SPS烧结双主相Sm2Co17-Ce2Co17复合永磁体的微观组织Microstructure of dual main phase Sm2Co17-Ce2Co17 composite permanent magnets sintered by SPS
徐成福,傅森杨,马冬冬,顾正飞,马垒,阳永泉,高新强,刘荣进
摘要(Abstract):
研究了放电等离子烧结(SPS)工艺和退火温度对双主相Sm_2Co_(17)-Ce_2Co_(17)复合永磁体微观组织的影响。结果表明:制备双主相Sm_2Co_(17)-Ce_2Co_(17)复合永磁体的最佳SPS工艺为:烧结温度750℃、压强64 MPa、烧结时间10 min,这样有利于减少稀土元素之间的扩散。退火可使烧结后磁体中存在的非晶相晶化。退火温度越高,双主相磁体中的稀土元素之间越容易相互扩散,Ce原子易扩散到Sm_2Co_(17)相中取代Sm原子,而Sm原子扩散到Ce_2Co_(17)相中取代Ce原子的机会就相对较少些,且在Sm_2Co_(17)相与Ce_2Co_(17)相的边界处形成一个过渡的富稀土区。
关键词(KeyWords): 双主相Sm_2Co_(17)-Ce_2Co_(17)复合永磁体;放电等离子烧结(SPS);退火温度;微观组织
基金项目(Foundation): 广西自然科学基金(2021GXNSFAA220081);; 国家自然科学基金(52361004,52171054);; 广西信息材料重点实验室开放研究基金(221021-K)
作者(Author): 徐成福,傅森杨,马冬冬,顾正飞,马垒,阳永泉,高新强,刘荣进
DOI: 10.13289/j.issn.1009-6264.2023-0396
参考文献(References):
- [1] Wang C,Yu N J,Zhu M G,et al.High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet[J].AIP Advances,2019,9(12):125237.
- [2] Cui C X,Yang W,Ding J H,et al.Interface microstructure and magnetic properties of α-Sm2Co17/β-Sm2Co17 dual phase nanowire magnetic composite[J].Intermetallics,2019,111:106494.
- [3] Chen H Y,Song X,Zhou X L,et al.Identification of 2∶ 17R′ cell edge phase in Sm2Co17-type permanent magnets by transmission electron microscopy[J].Acta Metallurgica Sinica,2021,57(12):1637-1644.
- [4] Wang S,Fang Y K,Song K K,et al.Optimization of both coercivity and knee-point magnetic field of Sm2Co17-type magnets via solid solution process[J].Journal of Rare Earths,2020,38(11):1224-1230.
- [5] Wang S,Fang Y K,Wang C,et al.Dependence of macromagnetic properties on the microstructure in high-performance Sm2Co17-type permanent magnets[J].Journal of Magnetism and Magnetic Materials,2020,510:166942.
- [6] Zhou B,Ding Y,Liu L,et al.Study on the grain growth and the evolution of defects around grain boundaries during heat treatment process in Sm2Co17 permanent magnets[J].Journal of Alloys and Compounds,2023,969:172444.
- [7] Zhu S Z,Ge Y C,Li L Y,et al.Chemical segregation mechanism and magnetic properties of Sm2Co17-based permanent magnets:Experimental investigation and first-principles calculations[J].Journal of Alloys and Compounds,2023,960:170899.
- [8] Zhang Y,Wu P F,Lu Y,et al.Unveiling the anomalous atomic stacking and formation mechanism of 1:3R Z-plates in Sm2Co17-type magnets[J].Journal of Alloys and Compounds,2023,934:167890.
- [9] Bulyk I I,Kononiuk O P,Bovda V O.Influence of milling conditions on the structural state of powders of melt-spinned alloy based on Sm2Co17[J].Materials Science,2022,57:702-710.
- [10] Zhang Y,Tan H T,Cao X,et al.Atomic-scale oxidation of a Sm2Co17-type magnet[J].Acta Materialia,2021,220:117343.
- [11] Zhang Y,Cao X,Tan H T,et al.Decomposition behavior in the early-stage oxidation of Sm2Co17-type magnets[J].Scripta Materialia,2021,200:113911.
- [12] Park J H,Kwon H J,Park J H,et al.Synthesis and characterization of Sm2Co17 using electrodeposition and reduction-diffusion process[J].Journal of Alloys and Compounds,2022,901:163669.
- [13] Chen B H,Li L Y,Zhu S Z,et al.Excellent magnetic and mechanical properties of the Sm2Co17-based magnets fabricated via microwave processing[J].Journal of Alloys and Compounds,2021,868:159071.
- [14] Jones N.The pull of stronger magnets[J].Nature,2011,472(7341):22-23.
- [15] Gut?eisch O,Willard M A,Bruck E,et al.Magnetic materials and devices for the 21st century:Stronger,lighter,and more energy efficient[J].Advanced Materials,2011,23(7):821-842.
- [16] Coey J M D.Hard magnetic materials:A perspective[J].IEEE Transactions on Magnetics,2011,47(12):4671-4681.
- [17] Poudyal N,Liu J P.Advances in nanostructured permanent magnets research[J].Journal of Physics D:Applied Physics,2013,46(4):1-23.
- [18] Li H L,Li X H,Guo D F,et al.Three-dimensional self-assembly of core/shell-like nanostructures for high-performance nanocomposite permanent magnets[J].Nano Letter,2016,16(9):5631-5638.
- [19] Yu N J,Gao W Y,Pan M X,et al.Influence mechanism of Fe content on the magnetic properties of Sm2Co17-type sintered magnets:Microstructure and microchemistry[J].Journal of Alloys and Compounds,2020,818:152908.
- [20] Xu C,Wang H,Liu B J,et al.Correlation between ordered solid solution and cellular structure of Sm2Co17 type magnets with high iron content[J].Journal of Magnetism and Magnetic Materials,2021,519:167477.
- [21] Wang S,Chen H S,Fang Y K,et al.Identification of optimal solid solution temperature for Sm2Co17-type permanent magnets with different Fe contents[J].Rare Metals,2021,40:3567-3574.
- [22] Wang C,Shen P,Fang Y K,et al.Cellular microstructure modification and high temperature performance enhancement for Sm2Co17-based magnets with different Zr contents[J].Journal of Materials Science & Technology,2022,120:8-14.
- [23] Wu H C,Liu Z,Zhang C Y,et al.Twinning,phase boundary structure and development of high coercivity in Fe-rich Sm2Co17-type magnets[J].Journal of Rare Earths,2022,40(1):102-111.
- [24] Liu J F,Ding Y,Hadjipanayis G C.Effect of iron on the high temperature magnetic properties and microstructure of Sm(CoFeCuZr)z permanent magnets[J].Journal of Applied Physics,1999,85(3):1670-1674.
- [25] 周寿增.稀土永磁材料及其应用[M].北京:冶金工业出版社,1995.
- [26] Goll D,Kleinschroth I,Sigle W,et al.Melt-spun precipitation-hardened Sm2(Co,Cu,Fe,Zr)17 magnets with abnormal temperature dependence of coercivity[J].Applied Physics Letters,2000,76(76):1054-1056.
- [27] 徐文第,曾令俊,刘庭臣.Cu在高Hcj 2∶ 17型SmCoCuFeZr系永磁体中的作用研究[J].金属材料研究,1985,11(1):17-19.XU Wen-di,ZENG Ling-jun,LIU Ting-chen.The role of Cu in the permanent magnet of high Hcj 2∶ 17 type SmCoCuFeZr system[J].Research on Metallic Materials,1985,11(1):17-19.
- [28] Lu N D,Song X Y,Liu X M,et al.Preparation and magnetic properties of amorphous and nanocrystalline Sm2Co17 alloys[J].Intermetallics,2010,18(6):1180-1184.
- [29] Xu C F,Gu Z F,Yang Y Q,et al.Phase relations of the Ce2Co17-Sm2Co17 pseudo-binary system[J].International Journal of Materials Research,2020,111(5):373-378.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||