热处理对镍钛合金组织和相变特性的影响Effect of heat treatment on microstructure and phase transformation behavior of NiTi shape memory alloys
石世威,袁志山,王永辉,崔跃,李君涛,冯昭伟,尚再艳,朱明
摘要(Abstract):
通过差示扫描量热仪(DSC)、X射线衍射仪(XRD)、扫描电镜(SEM)和透射电镜(TEM)研究了固溶时效对Ti-50.8Ni和Ti-50.8Ni-0.3Cr合金显微组织及相变特性影响。结果表明,固溶后两种合金组织都由原始拉拔纤维组织转变为等轴晶粒,晶粒随固溶温度升高而长大,固溶后母相主要是B2(B19’)相,同时发现存在Ti Ni3粒子。两种合金的马氏体相变峰值温度Mp随着固溶温度升高及时间延长先降低再升高。500℃时效0.5 h时Ti-50.8Ni合金加热/冷却相变类型是A→R→M1→M2/M→Rr→A,Ti-50.8Ni-0.3%Cr合金相变类型是A→R→M1→M2/M→Rr1→Rr2→A;时效1 h时,两种合金加热/冷却相变类型是A→R→M/M→Rr→A,时效2 h后两种合金加热/冷却相变类型是A→R→M/M→A。
关键词(KeyWords): 形状记忆合金;固溶时效;显微组织;相变
基金项目(Foundation): 2015年工业转型升级强基项目(TC150B5C0-3)
作者(Author): 石世威,袁志山,王永辉,崔跃,李君涛,冯昭伟,尚再艳,朱明
DOI: 10.13289/j.issn.1009-6264.2017.02.008
参考文献(References):
- [1]Seyyed Aghamiri S M,Nili Ahmadabadi M,Raygan S,et al.The mechanical and thermal behaviors of heat treated Ni-rich Ni Ti orthodontic archwires[J].J Mater Eng Perform,2009,18(5/6):843-847.
- [2]Christian Sander,Franz Martin Sander,Franz Gunter Sander.The derotation of premolars and canines with Ni Ti elements[J].J Orofacial Orthopedics,2006,67:117-126.
- [3]Dolce M,Cardone D.Mechanical behaviour of shape memory alloys for seismic applications 2.Austenite Ni Ti wires subjected to tension[J].Inter J Mech Sci,2001,43(11):2657-2677.
- [4]Dong Y S,Xiong J L,Li A Q,et al.A passive damping device with Ti Ni shape memory alloy rings and its properties[J].Mater Sci Eng A,2006,416:92-97.
- [5]Li H J,Dunne D.New corrosion resistant iron-based shape memory alloys[J].ISLJ Int,1997,37(6):605-609.
- [6]Zhang C,Farhat Z N.Sliding wear of superelastic Ti Ni alloy[J].Wear,2009,267:394-400.
- [7]贺志荣,王芳,周敬恩.Ni含量和热处理对Ti-Ni形状记忆合金相变和形变行为的影响[J].金属热处理,2006,31(9):17-22.HE Zhi-rong,WANG Fang,ZHOU Jing-en.Effect of Ni content and heat treatment on phase transformation and deformation behavior of Ti-Ni shape memory alloys[J].Heat Treatment of Metals,2006,31(9):18-22.
- [8]Shima Y,Otsubo K,Yoneyama T,et al.Anisotropic orthodontic force from the hollow super-elastic Ti-Ni alloy wire by transforming the wire crosssection[J].J Mater Sci:Mater in Medicine,2002,13:169-176.
- [9]Kim J I,Miyazaki S.Comparison of shape memory characteristics of a Ti-50.9 at.pct Ni alloy aged at 473 and 673 K[J].Metall Mater Trans A,2005,36:3301-3310.
- [10]贺志荣,王芳,王永善,等.V和Cr对Ti-Ni超弹性合金相变和形变特性的影响[J].金属学报,2007,43(12):1293-1296.HE Zhi-rong,WANG Fang,WANG Yong-shan,et al.Effects of V,Cr on transformation and deformation characteristics of Ti-50.8Ni superelastic alloy[J].Acta Metallurgica Sinica,2007,43(12):1293-1296.
- [11]Liu A L,Sui J H,Lei Y C,et al.Effect of Y addition on microstructure and martensitic transformation of a Ni-rich Ti-Ni shape memory alloy[J].J Mater Sci,2007,42:5791-5794.
- [12]王启,贺志荣,邵大伟等.固溶-时效处理对Ti-Ni-Cr形状记忆合金拉伸性能和显微组织的影响[J].稀有金属材料与工程,2012,41(7):1191-1195.WANG Qi,HE Zhi-rong,SHAO Da-wei,et al.Effects of solution annealing and aging on tensile property and microstructure of Ti-Ni-Cr shape memory alloy[J].Rare Metal Materials and Engineering,2012,41(7):1191-1195.
- [13]朱康平,祝建雯,曲恒磊.国外生物医用钛合金的发展现状[J].稀有金属材料与工程,2012,41(11):2058-2063.ZHU Kang-ping,ZHU Jian-wen,QU Heng-lei.Development and application of biomedical Ti alloys abroad[J].Rare Metal Materails and Engineering,2012,41(11):2058~2063.
- [14]Huang X,Liu Y.Effect of annealing on the transformation behavior and superelasticity of Ni Ti shape memory alloy[J].Scripta Mater,2001,45(2):153-160.
- [15]Chrobk D,Stroz D.Two-stage R phase transformation in cold-rolled and annealed Ti-50.6 at percent Ni alloy[J].Scripta Mater,2005,24(8):40-41.
- [16]Takashi Fukuda,Toshio Saburi.Mechanism of B2-B19-B19'transformation in shape memory Ti-Ni-Cu alloys[J].Mater Trans,1995,36(10):1244-1248.
- [17]ZHANG Yan-qiu,JIANG Shu-yon,ZHAO Ya-nan,et al.Influence of cooling rate on phase transformation and microstructure of Ti-50.9%Ni shape memory alloy[J].Transactions of Nonferrous Metals Society of China,2012,22:2685-2690.
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