氮元素对马氏体不锈钢组织和性能的影响Effect of nitrogen element on microstructure and properties of martensitic stainless steel
郑善举,杨卯生,张启富,郝晓东
摘要(Abstract):
研究了马氏体不锈轴承钢经添加氮元素及热处理后的微观组织和力学性能。结果表明,经过相同的热处理后,高氮马氏体不锈轴承钢比没有经过氮合金化处理的马氏体不锈钢具有更高的抗拉强度、屈服强度和硬度,分别提高了20%、26%和21%;同时冲击韧性没有明显降低。组织观察发现,经过氮合金化及热处理后,马氏体不锈轴承钢中的析出碳化物得到了细化。最大碳化物尺寸由25μm降低至5μm,碳化物平均尺寸由882 nm降低至592 nm,碳化物所占面积比例由16.0%降低至2.3%。氮元素的固溶强化和细小析出相的沉淀强化是造成高氮马氏体不锈轴承钢综合性能提高的原因。
关键词(KeyWords): 马氏体不锈钢;氮合金化;微观组织;力学性能
基金项目(Foundation):
作者(Author): 郑善举,杨卯生,张启富,郝晓东
DOI: 10.13289/j.issn.1009-6264.2017.01.017
参考文献(References):
- [1]徐茂德.热处理工艺对9Cr18不锈钢耐腐蚀性能的影响[J].机械工程材料,1985(3):46-51.XU Mao-de.The effect of heat treating process on corrosion resistance of 9Cr18 stainless steel[J].Materials for mechancial engineering,1985(3):46
- [2]张剑桥.9Cr18Mo马氏体不锈钢的平衡相热力学计算[J].特殊钢,2010,31(6):10-12.ZHANG Jian-qiao.Thermodynamic calculation on equilibrium precipitated phases in martensitic stainless steel 9Cr18Mo[J].Special Steel,2010,31(6):10-12.
- [3]郑善举,杨卯生,雷霆.含氮马氏体不锈轴承钢的腐蚀性能[J].金属热处理,2014,39(1):11-15.ZHENG Shan-ju,YANG Mao-sheng,LEI Ting.Corrosion resistance of nitrogen-containing martensitic stainless bearing steel[J].Heat Treatment of Metals,2014,39(1):11-15.
- [4]Lai J K L.A review of precipitation behavior in AISI type 316 stainless steel[J].Materials Science and Engineering,1983,61(2):101-109.
- [5]Prokoshkina V G,Kaputkina L M,Uluntcev D Y.Martensitic transformation and thermal stability of strengthening of nitrogen-containing chromiumnickel steels[J].Materialovedenie,1999,11(9):19-22.
- [6]Prokoshkina V G,Kaputkina L M,Svyazhin A G.A study of cast and thermomechanically hardened chromium-nickel nitrogen-bearing steel[J].Metall Tech.and Treatment of Met,2000,42(10):342-341.
- [7]Kostina M V,Bannykh O A,Blinov V M.Special features of steels alloyed with nitrogen[J].Metal Science and Heat Treatment,2000,44(11/12):459-462.
- [8]Prokoshkina V G,Kaputkina L M,Lozhnikov Y I.Thermomechanical treatment of nitrogen-containing corrosion resistant steels various structure classes[J].Mater Sci Forum,1999,426(2):969-974.
- [9]Hnninen H,Romu J,Ilola R,et al.Effect of processing and manufacturing of high nitrogen-containing stainless steels on their mechanical,corrosion and wear properties[J].Journal of Materials Processing Technology,2001,117(3):424-430.
- [10]马小平,王立军,王园园,等.氮对马氏体不锈钢00Cr13Ni4Mo组织和性能的影响[J].材料热处理学报,2012,33(4):77-84.MA Xiao-ping,WANG Xiao-ping,WANG Yuan-yuan,et al.Effect of nitrogen on microstructure and properties of martensitic stainless steel00Cr13Ni4Mo[J].Transactions of Materials and Heat Treatment,2012,33(4):77-84.
- [11]Heitkemper M,Bohne C,Pyzalla A,et al.Fatigue and fracture behavior of a laser surface heat treated martensitic high-nitrogen tool steel[J].International Journal of Fatigue,2003,25(2):101-106.
- [12]Stein G,Hucklenbroich I,Feichtinger H.Current and future applications of high nitrogen steels[J].Materials Science Forum,1999,318(1):151-160.
- [13]Toro A,Alonso-Falleiros N,Rodriguez D,et al.P/M Processing routes for high nitrogen martensitic stainless steels[J].Transactions of the Indian Institute of Metals,2002,55(5):481-487.
- [14]Garzon C M,Toro A,Tschiptschin A P.Microstructure and chemical characterization of high temperature nitride 12%Cr stainless steels[J].Transactions of the Indian Institute of Metals,2003,55(5):255-263.
- [15]王淑霞,贾伟,王毓麟.氮对0Cr13Ni4Mo马氏体不锈钢机械性能的影响[J].特殊钢,2001,22(5):23-25.WANG Shu-xia,JIA Wei,WANG Yu-lin.Effect of nitrogen on mechanical properties of martensitic stainless steel 0Cr13Ni4Mo[J].Special Steel,2001,22(5):23-25.
- [16]Marder J M,Marder A R.The morphology of iron-nickel massive martensite(Structural features of Fe-Ni massive martensite observed by light,electron and hot stage microscopies showing parallel block packet)[J].ASM Transactions Quarterly,1969,4(1):171-177.
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