30CrMnSiA结构钢表面多功能改性层的性能分析Performance analysis of multifunctional modified coatings on surface of 30CrMnSiA structural steel
刘泉利,王朝琳,刘瑞良,陈秋宇,米南,谢晓东,刘梓航
摘要(Abstract):
首先采用不同技术在30CrMnSiA钢表面制备了6种黑色多功能改性层,分别是采用电镀技术制备了纯Cr镀层、纯Ni镀层、纯Zn镀层和Zn-Ni复合镀层,采用低温渗氮+氧化(LTN+O)复合技术制备了LTN+O复合层,以及采用物理气相沉积(PVD)技术制备了PVD涂层,随后利用X射线衍射仪、扫描电镜等对黑色多功能改性层的组织结构进行表征,以及通过显微硬度仪、球-盘摩擦磨损试验机和电化学工作站对其力学性能和耐蚀性能进行测试。结果表明:采用电镀、低温渗氮+氧化复合以及PVD沉积等技术均可在30CrMnSiA钢表面成功制备黑色多功能改性层;在硬度方面,PVD涂层硬度最高,达到1610 HV0.05;在摩擦磨损性能方面,相比30CrMnSiA钢基体,黑色多功能改性层的摩擦系数均略有升高,除纯Ni镀层外,其他改性层的耐磨性能均优于30CrMnSiA钢基体;在结合力方面,PVD涂层和纯Ni镀层的结合力最好,压痕边缘位置无裂纹;在耐蚀性方面,相比30CrMnSiA钢基体,Zn-Ni复合镀层和LTN+O复合层耐蚀性有所提高,其他改性层的耐蚀性有所降低。
关键词(KeyWords): 30CrMnSiA钢;多功能改性层;组织结构;摩擦磨损性能;耐蚀性能
基金项目(Foundation): 黑龙江省自然科学基金(LH2023E060);; 国家自然科学基金(52371060);; 中央高校基本科研业务费专项基金(3072023WD1010)
作者(Author): 刘泉利,王朝琳,刘瑞良,陈秋宇,米南,谢晓东,刘梓航
DOI: 10.13289/j.issn.1009-6264.2023-0464
参考文献(References):
- [1] Kong Y,Liu Z D,Liu Q B.Effect of laser power on microstructure and properties of Ni-based alloy coatings on 30CrMnSiA steel[J].Journal of Thermal Spray Technology,2022,31(7):2136-2146.
- [2] 韩舒展,惠卫军,刘荣佩,等.回火温度对 30CrMnSiA 钢氢致延迟断裂行为的影响[J].[J].材料热处理学报,2014,35(7):114-119.HAN Shu-zhan,HUI Wei-jun,LIU Rong-pei,et al.Effect of tempering temperature on hydrogen-induced delayed fracture behavior of 30CrMnSiA steel[J].Transactions of Materials and Heat Treatment,2014,35(7):114-119.
- [3] 汤智慧,陆峰,张晓云,等.航空高强度结构钢及不锈钢防护研究与发展[J].航空材料学报,2003(S1):261-266.TANG Zhi-hui,LU Feng,ZHANG Xiao-yun,et al.Research and development of aviation high strength structural steel and stainless steel protection[J].Journal of Aeronautical Materials,2003(S1):261-266.
- [4] 宋春艳.300M飞机起落架外筒锻件生产过程中关键技术研究[D].秦皇岛:燕山大学,2014.SONG Chun-yan.Study on the key technology of producing for 300M aircraft landing gear outer cylinder forging[D].Qinhuangdao:Yanshan University,2014.
- [5] 梁益龙.高温淬火和回火对30CrMnSiA 钢组织和性能的影响[J].贵州工学院学报,1989(1):48-57.LIANG Yi-long.Effect of high temperature quenching and tempering on microstructure and properties of 30CrMnSiA steel[J].Journal of Guizhou University of Technology (Natural Science Edition),1989(1):48-57.
- [6] 颜鸣皋,吴学仁,朱知寿.航空材料技术的发展现状与展望[J].航空制造技术,2003(12):19-25.YAN Ming-gao,WU Xue-ren,ZHU Zhi-shou.Recent progress and prospects for aeronautical material technologies[J].Aeronautical Manufacturing Technology,2003(12):19-25.
- [7] Liu X C,Chen X J,Liang Z W,et al.The tribological properties of 30CrMnSiA bearing steels treated by the strengthening grinding process under lubrication wear[J].Materials,2022,15(20):7380.
- [8] 皮志超,闫江涛,肖鹏,等.30CrMnSiA表面有氰/无氰镀镉层的电化学性能对比研究[J].材料保护,2023,56(3):65-73.PI Zhi-chao,YAN Jiang-tao,XIAO Peng,et al.Comparative study of the electrochemical performance of cyanide/non-cyanide cadmium plating coating on 30CrMnSiA surface[J].Materials Protection,2023,56(3):65-73.
- [9] 唐丽娜.淬火态30CrMnSiA和42CrMo钢等离子体稀土氮碳共渗层组织与性能[D].哈尔滨:哈尔滨工业大学,2013.TANG Li-na.Microstructure and properties of surface layers of quenched 30CrMnSiA and 42CrMo steels plasma nitrocarburized with rare earths[D].Harbin:Harbin Institute of Technology,2013.
- [10] 杨西荣,田倩炆,刘晓燕,等.热处理对化学镀Ni-W-P镀层组织与性能的影响[J].材料热处理学报,2022,43(6):147-153.YANG Xi-rong,TIAN Qian-wen,LIU Xiao-yan,et al.Effect of heat treatment on microstructure and properties of electroless Ni-W-P coating[J].Transactions of Materials and Heat Treatment,2022,43(6):147-153.
- [11] Abraham S N,Hasegawa M M,Straka A S.Black molecular adsorber coatings for spaceflight applications[C]//SPIE Optical Engineering + Applications.International Society for Optics and Photonics,2014.
- [12] Zhurerova L,Rakhadilov B,Popova N,et al.Effect of the PEN/C surface layer modification on the microstructure,mechanical and tribological properties of the 30crmnsia mild-carbon steel[J].Journal of Materials Research and Technology,2020,9(1):291-300.
- [13] 包俊成,赵捷,王志奇,等.表面强化对30CrMnSiA钢疲劳性能的影响[J].机械工程材料,2010,34(6):71-73.BAO Jun-cheng,ZHAO Jie,WANG Zhi-qi,et al.Influence of surface strengthening on fatigue property of 30CrMnSiA steel[J].Materials for Mechanical Engineering,2010,34(6):71-73.
- [14] 皮志超,宋宜强,闫江涛,等.30CrMnSiA钢表面镉镀层化学转化膜的电化学特性[J].表面技术,2023,52(6):307-318.PI Zhi-chao,SONG Yi-qiang,YAN Jiang-tao,et al.Electrochemical characteristics of chemical conversion film of cadmium coating on 30CrMnSiA steel surface[J].Surface Technology,2023,52(6):307-318.
- [15] 辛童,白力静,董博轩,等.镁合金不同黑色防腐-吸光一体化涂层的性能研究[J].兵器材料科学与工程,2019,42(5):64-69.XIN Tong,BAI Li-jing,DONG Bo-xuan,et al.Properties of different black anticorrosion-absorption integrated coatings on magnesium alloy[J].Ordnance Material Science and Engineering,2019,42(5):64-69.
- [16] Reghuraj A R,Saju K K,Ritwik A,et al.Relative improvements in anti reflection property of black coating produced on stainless steel 310 using conversion coating techniques[J].Materials Today:Proceedings,2021,47(15):5079-5085.
- [17] Casademont C,Roche J,Arurault L.Alternative black coatings prepared on aluminium alloy 1050[J].Surface Engineering,2019,35(10):899-905.
- [18] Ding F J,Liu K,Lu J W.QPQ salt bath composite processing on microstructure and property of certain type aviation piston engine ring[J].IOP Conference Series:Materials Science and Engineering,2019,493(1):012119.
- [19] 白晶莹,李思振,郑大江,等.黑色微弧氧化膜的制备及其表征[J].物理化学学报,2016,32(9):2271-2279.BAI Jing-ying,LI Si-zhen,ZHENG Da-jiang,et al.Preparation and characterization of black micro-arc oxidation films[J].Acta Physico-Chimica Sinica,2016,32(9):2271-2279.
- [20] Hao Y T,Ye Z Y,Ye M H,et al.Construction and growth of black PEO coatings on aluminum alloys for enhanced wear and impact resistance[J].Ceramics International,2023,49(18):30782-30793.
- [21] Yao R,Li Y,Yao Z P,et al.Black PEO coating with enhanced thermal stability on titanium alloy and its thermal control properties[J].Surface & Coatings Technology,2022,429,127934.
- [22] 张海云.金属铜表面纳米涂层结构调控及其光热性能研究[D].重庆:重庆大学,2022.ZHANG Hai-yun.Study on tailoring nanostructured coatings on copper and their photothermal property[D].Chongqing:Chongqing University,2022.
- [23] 邱万奇,吴强,刘仲武,等.压痕法研究镶嵌结构界面金刚石膜粘附性能[J].稀有金属材料与工程,2014,43(2):381-385.QIU Wan-qi,WU Qiang,LIU Zhong-wu,et al.Study on adhesive properties of inlay structure diamond coatings by indentation test[J].Rare Metal Materials and Engineering,2014,43(2):381-385.
- [24] 肖娟,石志锋,刘佳,等.样品质量控制对X射线衍射测量结果的影响[J].应用化学,2023,40(5):720-729.XIAO Juan,SHI Zhi-feng,LIU Jia,et al.Effect of sample quality control on X-ray diffraction measurement results[J].Chinese Journal of Applied Chemistry,2023,40(5):720-729.
- [25] Fan Q H,Grácio J,Ali N,et al.Comparison of the adhesion of diamond films deposited on different materials[J].Diamond & Related Materials,2001,10(3):797-802.
- [26] Gerth J,Wiklund U.The influence of metallic interlayers on the adhesion of PVD TiN coatings on high-speed steel[J].Wear,2006,264(9):885-892.
- [27] Du H,Zhao H B,Xiong J,et al.Effect of interlayers on the structure and properties of tialn based coatings on WC-Co cemented carbide substrate[J].International Journal of Refractory Metals and Hard Materials,2013,37:60-66.
- [28] 卓城之.纳米颗粒对Ni基复合镀渗层的腐蚀磨损性能影响的研究[D].南京:南京航空航天大学,2011.ZHUO Cheng-zhi.Investigation on erosion-corrosion behaviours of nano-particles reinforced ni-based alloying layer[D].Nanjing:Nanjing University of Aeronautics And Astronautics,2011.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||