Mg-Gd-Fe和Mg-Gd-Cu合金的微观组织、力学性能和腐蚀性能的对比Comparison of microstructure, mechanical properties and corrosion properties between Mg-Gd-Fe and Mg-Gd-Cu alloys
普恒,杨韬如,向敏,胡耀波
摘要(Abstract):
可降解的压裂工具是目前石油钻井领域用工具的研究热点。在Mg合金中加入Fe能够与Mg基体形成电偶腐蚀,使合金具备高速率的可降解性能。添加较少稀土元素制备镁合金,可使合金具有较高的塑性,以增强其抗冲击的能力,从而适用于更复杂的石油钻井工况。基于此,制备了Mg-Gd-Fe合金和Mg-Gd-Cu合金,并对比研究了两种挤压态合金的微观组织、力学性能和腐蚀性能。结果表明:Mg-Gd-Cu合金的屈服强度和抗拉强度均高于Mg-Gd-Fe合金,Mg-Gd-Cu合金强度较高可归因于第二相的体积分数较高、晶粒尺寸较细;Mg-Gd-Fe和Mg-Gd-Cu合金的断后伸长率分别为53.0%和23.3%,这是由于Cu元素削弱了稀土织构,且第二相的体积分数较高,从而降低了Mg-Gd-Cu合金的塑性;在25℃的3.0 mass%KCl溶液中,Mg-Gd-Fe和Mg-Gd-Cu合金均具有优异的降解性能,降解速率分别为380.9 mm/y和219.5 mm/y。
关键词(KeyWords): 可溶合金;高塑性;力学性能;腐蚀性能
基金项目(Foundation): 国家自然科学基金面上项目(52071037)
作者(Author): 普恒,杨韬如,向敏,胡耀波
DOI: 10.13289/j.issn.1009-6264.2024-0294
参考文献(References):
- [1] Prasad S V S,Prasad S B,Verma K,et al.The role and significance of Mg in modern day research:A review[J].Journal of Magnesium and Alloys,2022,10(1):1-61.
- [2] Esmaily M,Svensson J E,Fajardo S,et al.Fundamentals and advances in Mg alloy corrosion[J].Progress in Materials Science,2017,89:92-193.
- [3] Li S B,Yang X Y,Hou J T,et al.A review on thermal conductivity of Mg and its alloys[J].Journal of Magnesium and Alloys,2020,8(1):78-90.
- [4] Sekar P,Narendranath S,Desai V,et al.Recent progress in vivo studies and clinical applications of Mg based biodegradable implants-A review[J].Journal of Magnesium and Alloys,2021,9(4):1147-1163.
- [5] Tong F L,Wei S H,Chen X Z,et al.Mg alloys as anodes for neutral aqueous Mg-air batteries[J].Journal of Magnesium and Alloys,2021,9(6):1861-1883.
- [6] Sun J,Du W B,Fu J J,et al.A review on magnesium alloys for application of degradable fracturing tools[J].Journal of Magnesium and Alloys,2022,10:2649-2672.
- [7] Xie J S,Zhang J H,You Z H,et al.Towards developing Mg alloys with simultaneously improved strength and corrosion resistance via RE alloying[J].Journal of Magnesium and Alloys,2021,9(1):41-56.
- [8] Zhang J H,Liu S J,Wu R Z,et al.Recent developments in high-strength Mg-RE-based alloys:Focusing on Mg-Gd and Mg-Y systems[J].Journal of Magnesium and Alloys,2018,6(3):277-291.
- [9] Yang Y,Xiong X M,Chen J,et al.Research advances in Mg and Mg alloys worldwide in 2020[J].Journal of Magnesium and Alloys,2021,9(3):705-747.
- [10] Wan Y C,Tang B,Gao Y H,et al.Bulk nanocrystalline high-strength Mg alloys prepared via rotary swaging[J].Acta Materialia,2020,200:274-286.
- [11] Zhong S Y,Zhang D F,Chai S S,et al.Effect of Cu addition on the microstructure,mechanical properties and degradation rate of Mg-2Gd alloy[J].Journal of Materials Research and Technology,2021,15:477-487.
- [12] Liu B S,Dong G H,Ren X X,et al.Accelerated degradation rate of high-strength Mg-4Y-1Zn alloy by Cu addition for degradable bridge-plug applications[J].International Journal of Materials Research,2020,111(10):872-875.
- [13] Wang J F,Gao S Q,Liu X Y,et al.Enhanced mechanical properties and degradation rate of Mg-Ni-Y alloy by introducing LPSO phase for degradable fracturing ball applications[J].Journal of Magnesium and Alloys,2020,8(1):127-133.
- [14] Wang Y Q,Zhang D F,Zhong S Y,et al.Effect of minor Ni addition on the microstructure,mechanical properties and corrosion behavior of Mg-2Gd alloy[J].Journal of Materials Research and Technology,2022,20:3735-3749.
- [15] Zhong S Y,Zhang D F,Wang Y Q,et al.Microstructures,mechanical properties and degradability of Mg-2Gd-0.5(Cu/Ni) alloys:A comparison study[J].Journal of Materials Science & Technology,2022,128:44-58.
- [16] Dai C N,Wang J F,Pan Y L,et al.Achieving exceptionally high strength and rapid degradation rate of Mg-Er-Ni alloy by strengthening with lamellar γ′ and bulk LPSO phases[J].Journal of Materials Science & Technology,2024,168:88-102.
- [17] Esmaily M,Svensson J E,Fajardo S,et al.Fundamentals and advances in magnesium alloy corrosion[J].Progress in Materials Science,2017,89:92-193.
- [18] Zhang C,Wu L,Huang G S,et al.Effects of Fe concentration on microstructure and corrosion of Mg-6Al-1Zn-xFe alloys for fracturing balls applications[J].Journal of Materials Science & Technology,2019,35:2086-2098.
- [19] Su C,Wang J F,Li H Y,et al.High strength and rapid solution Mg alloy by adding Fe element fabricated by binder jetting additive manufacturing[J].Journal of Manufacturing Processes,2022,84:652-659.
- [20] Zheng C,Liu H Y,Wang H X,et al.Finite element analysis and experimental study on the deformation characteristics of an aluminum alloy fracturing ball[J].Journal of Natural Gas Science and Engineering,2016,35:203-210.
- [21] Jiang M G,Xu C,Yan H,et al.Unveiling the formation of basal texture variations based on twinning and dynamic recrystallization in AZ31 Mg alloy during extrusion[J].Acta Materialia,2018,157:53-71.
- [22] Chen H,Wang J Q,Han E H,et al.AC impedance spectroscopy study of the corrosion behavior of an AZ91 Mg alloy in 0.1M sodium sulfate solution[J]].Electrochimica Acta,2007,9:3299-3309.
- [23] Ascencio M,Pekguleryuz M,Omanovic S.An investigation of the corrosion mechanisms of WE43 Mg alloy in a modified simulated body fluid solution:the influence of immersion time[J].Corrosion Science,2014,87:489-503.
- [24] Ascencio M,Pekguleryuz M,Omanovic S.An investigation of the corrosion mechanisms of WE43 Mg alloy in a modified simulated body fluid solution:The effect of electrolyte renewal[J].Corrosion Science,2015:91:297-310.
- [25] King A D,Birbilis N,Scully J R.Accurate electrochemical measurement of Mg corrosion rates;a combined impedance,mass-loss and hydrogen collection study[J].Electrochimica Acta,2014,121:394-406.
- [26] Huang J,Song G L,Atrens A,et al.What activates the Mg surface-a comparison of Mg dissolution mechanisms[J].Journal of Materials Science & Technology,2020,57:204-220.
- [27] Chen J,Tan L,Yu X,Yang K.Effect of minor content of Gd on the mechanical and degradable properties of as-cast Mg-2Zn-xGd-0.5Zr alloys[J].Journal of Materials Science & Technology,2019,35(4):503-511.
- [28] Xie J,Zhang J,Zhang Z,et al.Corrosion mechanism of Mg alloys involving elongated long-period stacking ordered phase and intragranular lamellar structure[J].Journal of Materials Science & Technology,2023,151:190-203.
- [29] Jeong Y S,Kim W J.Enhancement of mechanical properties and corrosion resistance of Mg-Ca alloys through microstructural refinement by indirect extrusion[J].Corrosion Science,2014,82:392-403.
- [30] Li J R,Jiang Q T,Sun H Y,et al.Effect of heat treatment on corrosion behavior of AZ63 Mg alloy in 3.5wt.% sodium chloride solution[J].Corrosion Science,2016,111:288-301.
- [31] Pan H,Pang K,Cui F Z,et al.Effect of alloyed Sr on the microstructure and corrosion behavior of biodegradable Mg-Zn-Mn alloy in Hanks’ solution[J].Corrosion Science,2019,157:420-437.
- [32] Yin S Q,Duan W C,Liu W H,et al.Influence of specific second phases on corrosion behaviors of Mg-Zn-Gd-Zr alloys[J].Corrosion Science,2020,166:108419.
- [33] Lu Y,Bradshaw A R,Chiu Y L,et al.Effects of secondary phase and grain size on the corrosion of biodegradable Mg-Zn-Ca alloys[J].Materials Science and Engineering C,2015,48:480-486.
- [34] Atrens A,Song G L,Liu M,et al.Review of recent developments in the field of Mg corrosion[J].Advanced Engineering Materials,2015,17(4):400-453.
- [35] Wang Y J,Peng J,Zhong L P.On the microstructure and mechanical property of as-extruded Mg-Sn-Zn alloy with Cu addition[J].Journal of Alloys and Compounds,2018,744:234-242.
- [36] Aqil Z,Hamed M,Reza M,et al.Unraveling the effect of deformation temperature on the mechanical behavior and transformation-induced plasticity of the SUS304L stainless steel[J].Steel Research International,2020,91:246-257.
- [37] Stanford N,Barnett M R.The origin of “rare earth” texture development in extruded Mg based alloys and its effect on tensile ductility[J].Materials Science and Engineering A,2008,496(1/2):399-408.
- [38] Hadorn J P,Sasaki T T,Nakata T,et al.Solute clustering and grain boundary segregation in extruded dilute Mg-Gd alloys[J].Scripta Materialia,2014,93:28-31.
- [39] Dai C N,Zhang S L,Wang Y,et al.Elucidation of the corrosion rate enhancement mechanism in Mg-Er-Gd-Ni alloys with high volume fraction of LPSO phase and different Gd contents after extrusion[J].Journal of Materials Research and Technology,2023,27:522-541.
- [40] Wang L S,Jiang J H,Liu H,et al.Microstructure characterization and corrosion behavior of Mg-Y-Zn alloys with different long period stacking ordered structures[J].Journal of Magnesium and Alloys,2020,8(4):1208-1220.
- [41] Yang H B,Wu L,Jiang B,et al.Enhancement of corrosion resistance and discharge performance of Mg-5Li-3Al-1Zn sheet for Mg-air battery via rolling[J].Journal of the Electrochemical Society,2020,167(11):110529.
- [42] Shi Z M,Cao F Y,Song G L,et al.Corrosion behaviour in salt spray and in 3.5% NaCl solution saturated with Mg(OH)2 of as-cast and solution heat-treated binary Mg RE alloys:RE=Ce,La,Nd,Y,Gd[J].Corrosion Science,2013,76:98-118.
- [43] Cao F Y,Shi Z M,Hofstetter J,et al.Corrosion of ultra-high-purity Mg in 3.5% NaCl solution saturated with Mg(OH)2[J].Corrosion Science,2013,75:78-99.
- [44] Atrens A,Shi Z M,Mehreen S U,et al.Review of Mg alloy corrosion rates[J].Journal of Magnesium and Alloys,2020,8(4):989-998.
- [45] Fu B Q,Liu W,Li Z L.Calculation of the surface energy of hcp-metals with the empirical electron theory[J].Applied Surface Science,2009,255(23):9348-9357.
- [46] Song G L,Mishra R,Xu Z Q.Crystallographic orientation and electrochemical activity of AZ31 Mg alloy[J].Electrochemistry Communications,2010,12(8):1009-1012.
- [47] Song G L,Xu Z Q.Crystal orientation and electrochemical corrosion of polycrystalline Mg[J].Corrosion Science,2012,63:100-112.
- [48] Xiang Q,Jiang B,Zhang Y X,et al.Effect of rolling-induced microstructure on corrosion behaviour of an as-extruded MgV5Li-1Al alloy sheet[J].Corrosion Science,2017,119:14-22.
- [49] Hagihara K,Okubo M,Yamasaki M,et al.Crystal orientation dependent corrosion behaviour of single crystals of a pure Mg and Mg-Al and Mg-Cu solid solutions[J].Corrosion Science,2016,109:68-85.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||