机械合金化对CrW合金烧结及电烧蚀的影响Effect of mechanical alloying on sintering and electric ablation behavior of CrW alloy
曹伟产,梁淑华,张晓,范志康
摘要(Abstract):
以机械合金化CrW粉末为原料,采用真空烧结制备CrW合金进行电烧蚀实验,并利用第一性原理计算了CrW固溶体电子态密度,探讨固溶对电烧蚀性能的影响规律。实验结果表明:球磨时间越长,烧结体CrW的固溶程度越高、平均耐电压强度越高,烧蚀面积越少;计算结果表明,随W固溶度的增大,CrW合金费米能级处电子密度下降,合金稳定性提高。
关键词(KeyWords): 机械合金化;CrW合金;固溶体;第一性原理;电烧蚀
基金项目(Foundation): 国家自然科学基金重点项目(50834003),国家自然科学基金(50871085);; 863计划(2009AA03Z522)
作者(Author): 曹伟产,梁淑华,张晓,范志康
DOI: 10.13289/j.issn.1009-6264.2010.09.031
参考文献(References):
- [1]王亚平,张丽娜,丁秉钧,等.选择性相强化对CuCr触头材料在真空小间隙中耐电压强度的影响[J].中国电机工程学报,1999,19(3):46-49.WANG Ya-ping,ZHANG Li-na,DING Bing-jun,et al.Effect of selective strengthening of CuCr contact materials on the dielectric strength in a short vacuum gap[J].Proceedings of the CSEE,1999,19(3):46-49.
- [2]YANG Zhi-mao,ZHANG Qi-uli,ZHANG Cheng-yu,et al.Influence of microstructure of CuCr25cathode on the motion of vacuum arc spots[J].Physics Letters A,2006,353(1):98-100.
- [3]Zhang C Y,Wang Y P,Yang,Z M,et al.Microstructure and properties of CuCr25alloys with different Ni content[J].Acta Metallurgica Sinica,2003,16:151-154.
- [4]ZHANG Chengyu,WANG Jiang,ZHANG Hui,et al.Deoxidization of CuCr25alloys prepared by vacuum induction melting[J].Transactions of Nonferrous Metals Society of China,2001,11(3):337-339.
- [5]Yang Z M,Zhang Q L,Zhang C Y,et al.Influence of microstructure of CuCr25cathode on the motion of vacuum arc spots[J].Physics Letters A,2006,353(1):98-100.
- [6]王立彬,张程煜,丁秉钧.W或C添加剂对优化CuCr25合金显微组织的作用[J].稀有金属材料与工程,2003,32(1):41-44.Wang Libing,Zhang Chengyu,Ding Bingjun.Influence of W or C adding on the microstructure of CuCr25alloys[J].Rare Metal Materials and Engineering,2003,32(1):41-44.
- [7]Zhang C Y,Ding B J.Effects of additives W and Ni on microstructure and properties of CuCr25materials[J].International Journal of Materials&Product Technology,2004,20(4):292-299.
- [8]Yang Zhimao,Zhang Qiuli,Zhang Chengyu,et al.Influence of microstructure of CuCr25cathode on the motion of vacuum arc spots[J].Physics Letters A,2006,353(1):98-100.
- [9]姚强,邢辉,孟丽君,等.Ti-Mo合金β结构稳定性和弹性性质的第一性原理研究[J].金属学报,2008,44(1):19-22.YAO Qiang,XING Hui,MENG Li-jun,et al.First-principles investigation ofβphase stability and elastic property of Ti-Mo alloys[J].Acta Metallurgica Sinica,2008,44(1):19-22.
- [10]Tashi Nautiyal,Suk Joo Youn,Kwang S Kim.Effect of dimensionality on the electronic structure of Cu,Ag,and Au[J].Physical review B,2003,68:033407.
- [11]Krger J,Limot L,Jensen H,et al.Stark effect in Au(111)and Cu(111)sueface states[J].Physical review B,2004,70:033401.
- [12]帅歌旺,方平,郭正华.机械合金化制备Cu-Fe过饱和固溶体及其时效分解[J].材料工程,2008,12:51-54.SHUAI Ge-wang,FANG Ping,GUO Zheng-hua.Aging treatment of Cu-Fe supersaturated solid solution prepared by mechanical alloying[J].Journal of Materials Engineering,2008,12:51-54.
- [13]拉弗蒂.真空电弧理论与应用[M].程积高,译.北京:机械工业出版社,1985.
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