煤种对高硅酸铁尾矿深度还原回收铁的影响Effects of coal types on iron recovery from iron ore tailings with high iron silicate by deep reduction process
王长龙,王爽,乔春雨,倪文,徐承焱,仇夏杰,平硕
摘要(Abstract):
以含铁14.51%(质量分数)的铁尾矿为研究对象,采用煤基深度还原—磁选方法回收铁,研究并分析了焙烧过程中不同煤还原剂、助熔剂、焙烧温度以及焙烧时间对铁还原的影响规律。结果表明:对于铁尾矿深度还原,固定碳含量高且含有少量挥发份的煤效果较好;以无烟煤为还原剂,CaO为助熔剂,1300℃焙烧180 min,磁选得到铁产品中铁品位90.12%,铁回收率为72.21%。通过X射线衍射(XRD)、扫描电镜(SEM)及能谱分析(EDS)分析了磁选铁产品中铁的存在形式,结果表明:铁尾矿深度还原过程中铁矿物大部分被还原成金属铁,仅有少部分矿物是金属铁被氧化的磁铁矿和石英,实现了铁尾矿中铁的还原和富集。
关键词(KeyWords): 铁尾矿;深度还原;无烟煤;铁
基金项目(Foundation): 国家高技术研究发展计划(“863”计划)资助项目(2012AA062405)
作者(Author): 王长龙,王爽,乔春雨,倪文,徐承焱,仇夏杰,平硕
DOI: 10.13289/j.issn.1009-6264.2014.09.004
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