Sn元素对Mg-1Zn-0.3Zr-1Y生物镁合金组织和性能的影响Effect of Sn on microstructure and properties of Mg-1Zn-0.3Zr-1Y biological magnesium alloy
龚圆,贺俊光,文九巴,田培梧
摘要(Abstract):
通过光学显微镜(OM)、扫描电镜(SEM)、浸泡试验、析氢试验、电化学试验和拉伸试验等研究了Sn元素对Mg-1Zn-0.3Zr-1Y-xSn(x=0、0.5、1、1.5、2、2.5、3)生物镁合金组织、耐蚀性能和力学性能的影响。结果表明:添加Sn元素后,合金的耐蚀性和综合力学性能都有一定的提升。当Sn含量为2 mass%时,合金的耐蚀性和综合力学性能最好,合金在模拟体液中浸泡120 h后的平均腐蚀速率由未添加Sn元素的2.010 mm/y降至1.201 mm/y,自腐蚀电位正移为-1.433 V,自腐蚀电流密度降为2.208μA/cm~2,屈服强度、抗拉强度和伸长率分别为153.6 MPa、210.9 MPa和19.1%。
关键词(KeyWords): 生物镁合金;耐蚀性能;力学性能;Sn
基金项目(Foundation): 河南省高等学校重点科研项目(20A430010)
作者(Author): 龚圆,贺俊光,文九巴,田培梧
DOI: 10.13289/j.issn.1009-6264.2021-0309
参考文献(References):
- [1] 曾荣昌,柯伟,徐永波,等.Mg合金的最新发展及应用前景[J].金属学报,2001,37(7):673-685.ZENG Rong-chang,KE Wei,XU Yong-bo,et al.Recent development and application of magnesium alloys[J].Acta Metallurgica Sinica,2001,37(7):673-685.
- [2] Zheng Y F,Gu X N,Witte F.Biodegradable metals[J].Material Science and Engineering,2014,77:1-34.
- [3] 张小农,左敏超,张绍翔,等.医用可降解血管支架临床研究进展[J].金属学报,2017,53(10):1215-1266.ZHANG Xiao-nong,ZUO Min-chao,ZHANG Shao-xiang,et al.Advances in clinical research of biodegradable stents[J].Acta Metallurgica Sinica,2017,53(10):1215-1266.
- [4] 郑玉峰,杨宏韬.血管支架用可降解金属研究进展[J].金属学报,2017,53(10):1227-1237.ZHENG Yu-feng,YANG Hong-tao.Research progress in biodegradable metals for stent application[J].Acta Metallurgica Sinica,2017,53(10):1227-1237.
- [5] 罗延龄.新型生物医用高分子材料的合成、结构表征与性能研究[D].西安:陕西师范大学,2012.LUO Yan-ling.Synthesis,characterization and properties of novel biomedical polymer materials[D].Xi'an:Shanxi Normal University,2012.
- [6] 黎文献,田荣璋.镁及镁合金[M].长沙:中南大学出版社,2005:83.
- [7] 李德辉,董杰,曾小勤,等.高性能稀土镁合金研究进展[J].材料导报,2005,19(8):277-288.LI De-hui,DONG Jie,ZENG Xiao-qin,et al.Research progress of high-performance magnesium rare-earth alloys[J].Materials Review,2005,19(8):277-288.
- [8] 彭建,吕滨江,潘复生,等.高塑性Mg-Zn系稀土镁合金的研究进展[J].热加工工艺,2010,39(18):15-19.PENG Jian,Lü Bin-jiang,PAN Fu-sheng,et al.Research progress of rare-earth Mg-Zn alloy with high plasticity[J].Hot Working Technology,2010,39(18):15-19.
- [9] 唐恒,常丽丽.Mg-Sn-Zn-Ca合金的微观组织与力学行为研究[D].济南:山东大学,2016.TANG Heng,CHANG Li-li.Investigations of microstructure and mechanical behaviors of Mg-Sn-Zn-Ca alloys[D].Jinan:Shandong University,2016.
- [10] 陆星,赵国群,张昊天,等.Mg-Zn-Sn基变形镁合金的制备及其挤压成形的性能的研究[D].济南:山东大学,2018.LU Xing,ZHAO Guo-qun,ZHANG Hao-tian,et al.Fabrication of Mg-Zn-Sn based wrought magnesium alloys and study on their extrusion deformation performance[D].Jinan:Shandong University,2018.
- [11] 孙善扬,翁坤忠,袁广银.Sn对镁合金显微组织和力学性能的影响[J].中国有色金属学报,1999,9(1):55-58.SUN Shan-yang,WENG Kun-zhong,YUAN Guang-ying.Effects of Sn addition microstructure and mechanical properties of magnesium alloys[J].The Chinese Journal of Nonferrous Metals,1999,9(1):55-58.
- [12] Zhang X,Yuan G,Mao L,et al.Effects of extrusion and heat treatment on the mechanical properties and biocorrosion behaviors of a Mg-Nd-Zn-Zr alloy[J].Journal of the Mechanical Behavior of Biomedical Materials,2012,7(1):77-86.
- [13] Wang C M,Chen Y G,Xiao S F,et al.Thermal conductivity and mechanical properties of as-cast Mg-3Zn-(0.5-3.5)Sn alloy[J].Rare Metal Materials and Engineering,2013,42(10):2019-2022.
- [14] 宋长江.ZM61Ca0.5微观组织与仿生耐蚀性能关系的研究[D].重庆:重庆大学,2013.SONG Chang-jiang.The relationship between microstructure and bio-corrosion resistance property of ZM61Ca0.5 alloy[D].Chongqing:Chongqing University,2013.
- [15] 师慧娜,贺俊光,文九巴,等.稀土元素Dy对Mg-2Zn-0.5Zr生物镁合金组织与性能的影响[J].材料热处理学报,2020,41(1):12-18.SHI Hui-na,HE Jun-guang,WEN Jiu-ba,et al.Effect of rare earth element Dy on microstructure and properties of Mg-2Zn-0.5Zr bio-magnesium alloy[J].Transactions of Materials and Heat Treatment,2020,41(1):12-18.
- [16] 朗海洋,欧俊.生物医用可降解Zn-Sn系和Zn-Mg-Sn系合金的制备、组织及性能研究[D].广西:桂林理工大学,2019.LANG Hai-yang,OU Jun.Preparation,microstructure and properties of biomedical degradable Zn-Sn and Zn-Mg-Sn alloys[D].Guangxi:Guilin University of Technology,2019.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||