一种高强耐热轴承钢的微观组织及力学性能Microstructure and mechanical properties of a high strength heat resistant bearing steel
信振飞,迟宏宵,于杰,周健,谷金波
摘要(Abstract):
利用光学显微镜(OM)、扫描电镜(SEM)、透射电镜(TEM)、X射线衍射仪(XRD)、拉伸试验和洛氏硬度计等研究了一种新型成分优化的超高强度轴承钢经不同工艺热处理后的微观组织及力学性能。结果表明,在1040~1080℃范围内,随着固溶温度的升高,试验钢的抗拉强度逐渐升高,屈服强度逐渐降低。试验钢经1060℃固溶1 h后油淬及两次(-73℃冷处理2 h+540℃回火2 h)处理后,抗拉强度达到1997 MPa,屈服强度达到1600 MPa,断后伸长率达到12%,断面收缩率为55%,具有优异的强韧性能;随固溶温度的升高,试验钢的原始奥氏体晶粒尺寸逐渐增大,从19μm增加到50.9μm,未溶碳化物含量明显减少,残留奥氏体含量逐渐增多,其中,残留奥氏体含量增多是导致屈服强度逐渐降低的主要原因;试验钢中大量存在M_6C和Laves两种不同种类的析出相,其中M_6C碳化物在固溶阶段起到细化晶粒作用,Laves相在回火过程弥散析出,是试验钢获得超高强度的主要强化机制。
关键词(KeyWords): 轴承钢;超高强度;板条马氏体;析出相;位错密度;M_6C碳化物
基金项目(Foundation): 国家科技重大专项经费资助(J2019-VI-0019-0134)
作者(Author): 信振飞,迟宏宵,于杰,周健,谷金波
DOI: 10.13289/j.issn.1009-6264.2022-0535
参考文献(References):
- [1] 李昭昆,雷建中,徐海峰,等.国内外轴承钢的现状与发展趋势[J].钢铁研究学报,2016,28(3):1-12.LI Zhao-kun,LEI Jian-zhong,XU Hai-feng,et al.Current status and development trend of bearing steel in China and abroad[J].Journal of Iron and Steel Research,2016,28(3):1-12.
- [2] 马芳,刘璐.航空轴承技术现状与发展[J].航空发动机,2018,44(1):85-90.MA Fang,LIU Lu.Present situation and development of aviation bearing technology[J].Aeroengine,2018,44(1):85-90.
- [3] Wang L,Snidle R W,Gu L,et al.Rolling contact silicon nitride bearing technology:A review of recent research[J].Wear,2000(1/2):246.
- [4] Maloney J L,Tomasello C M.Case carburized stainless steel alloy for high temperature applications:US,US5424028 A[P].1995.
- [5] Li S L,Liang Y L,Yu J B,et al.The high-cycle fatigue behavior of carburized M50NiL steel with high-energy modification and compound infiltration:A comparative study[J].Surface and Coatings Technology,2022,451(0257-8972):1290009.
- [6] 严晓红,俞峰,姚长贵,等.一种高强高韧耐蚀高温轴承齿轮钢及制备方法:中国,CN102226254[P].2013-03-20.YAN Xiao-hong,YU Feng,YAO Chang-gui,et al.The invention relates to a high strength and high toughness corrosion resistant high temperature bearing gear steel and a preparation method thereof:China,CN102226254[P].2013-03-20.
- [7] 李新宇,杨卯生,周晓龙,等.钴和钼对高钴铬钼轴承钢组织及力学性能影响[J].钢铁,2017,52(5):77-86.LI Xin-yu,YANG Mao-sheng,ZHOU Xiao-long,et al.Influence of Co and Mo on microstructure and mechanical properties of bearing steel with high content of cobalt,chromium and molybdenum[J].Iron and Steel,2017,52(5):77-89.
- [8] 袁晓虹,郑善举,阴树标,等.回火时间对高温轴承钢组织和性能的影响[J].金属热处理,2014,39(10):28-31.YAN Xiao-hong,ZHENG Shan-ju,YIN Shu-biao,et al.Effect of tempering time on microstructure and properties of high temperature bearing steel[J].Heat Treatment of Metals,2014,39(10):28-31.
- [9] Yu X F,Shen X Y,Wang S S,et al.Effect of quenching and tempering treatment on microstructure and mechanical properties of CSS-42L bearing steel[J].Journal of Materials Engineering and Performance,2022,31(7):5458-5466.
- [10] 肖茂果,李东辉,吕新杨,等.热处理对高Cr-Co-Mo轴承钢组织与性能的影响[J].材料热处理学报,2018,39(8):75-81.XIAO Mao-guo,LI Dong-hui,Lü Xin-yang,et al.Effects of heat treatment on microstructure and properties of a high Cr-Co-Mo alloyed heat resistant bearing steel[J].Transactions of Materials and Heat Treatment,2018,39(8):75-81.
- [11] 张瑜,张志波,赵卫东.固溶温度对耐高温轴承钢组织与性能的影响[J].金属热处理,2015,40(3):151-154.ZHANG Yu,ZHANG Zhi-bo,ZHAO Wei-dong.Effects of solid solution temperature on microstructure and mechanical properties of high-temperature resistant bearing steel[J].Heat Treatment of Metals,2015,40(3):151-154.
- [12] 鲍俭,杨卯生,王华昆.热处理工艺对20Cr14Co12Mo5轴承钢力学性能的影响[J].钢铁,2010,45(1):91-95.BAO Jian,YANG Mao-sheng,WANG Hua-kun.Effect of heat treatment on mechanical properties of bearing steel 20Cr14Co12Mo5[J].Iron and Steel,2010,45(1):91-95.
- [13] Dyson D J,Keown S R J A M.A study of precipitation in a 12%Cr-Co-Mo steel[J].Acta Metallurgica,1969,17(8):1095-1107.
- [14] 郑善举,杨卯生,雷霆,等.冷处理对16Cr14Co12Mo5轴承钢组织和性能的影响[J].钢铁,2012,47(12):76-80.SHNEG Shan-ju,YANG Mao-sheng,LEI Ting,et al.Effect of cold treatment on microstructure and mechanical properties of 16Cr14Co2Mo5 bearing steel[J].Iron and Steel,2012,47(12):76-80.
- [15] Li S,Yuan X,Jiang W,et al.Effects of heat treatment influencing factors on microstructure and mechanical properties of a low-carbon martensitic stainless bearing steel[J].Materials Science and Engineering A,2014,605:229-235.
- [16] Yuan X H,Zheng S J,Yang M S,et al.Carbide precipitation and microstructure refinement of Cr-Co-Mo-Ni bearing steel during hot deformation[J].Journal of Central South University,2015,22(9):3265-3274.
- [17] 刘天祥.BG800轴承钢耐磨性能与疲劳行为的研究[D].昆明:昆明理工大学,2021.LIU Tian-xing.Study on wear resistance and fatigue behavior of BG800 bearing steel[D].Kunming:Kunming University of Science and Technology,2021.
- [18] 尹龙承.14Cr14Co13Mo4钢Ni缓冲层法渗碳及热处理工艺研究[D].哈尔滨:哈尔滨工业大学,2020.YIN Long-cheng.Ni buffer layer method for carburizing and heat treatment of 14Cr14Co13Mo4 steel[D].Harbin:Harbin Institute of Technology,2020.
- [19] Liu F,Chen K,Kang C,et al.Effects of V-Nb microalloying on the microstructure and properties of spring steel under different quenching-tempering times[J].Journal of Materials Research and Technology,2022,19:779-793.
- [20] Zhang D,Liu G,Zhang K,et al.Effect of Nb microalloying on microstructure evolution and mechanical properties in low carbon medium manganese steel[J].Materials Science and Engineering A,2021,824:141813.
- [21] 李强锋,赵鸿金,杨延丽,等.Ni和Nb元素对Fe-Cr-Mo合金力学和阻尼性能的影响[J].钢铁研究学报,2019,31(7):668-675.LI Qiang-feng,ZHAO Hong-jin,YANG Yan-li,et al.Effect of Ni and Nb on mechanical properties and damping capacity of Fe-Cr-Mo alloy[J].Journal of Iron and Steel Research,2019,31(7):668-675.
- [22] 赵振业,李志,刘天琦,等.探索新强韧化机制开拓超高强度钢新领域[J].中国工程科学,2003(9):39-42.ZHAO Zhen-ye,LI Zhi,LIU Tian-qi,et al.Studying the new strength-toughen mechanisms,developing a new field of ultra-high steel[J].Engineering Science,2003(9):39-42.
- [23] 王梦丹,杜三明,贺甜甜,等.回火温度对M50 钢组织及摩擦磨损性能影响[J].材料热处理学报,2021,42(12):117-123.WANG Meng-dan,DU San-ming,HE Tian-tian,et al.Effect of tempering temperature on microstructure and friction and wear properties of M50 steel[J].Transactions of Materials and Heat Treatment,2021,42(12):117-123.
- [24] 赵振业,李春志,李志,等.一种超高强度不锈钢超细化组织TEM研究[J].航空材料学报,2005(2):1-5.ZHAO Zhen-ye,LI Chun-zhi,LI Zhi,et al.Observation of the microstructure in an ultra-high strength and high toughness stainless steel[J].Journal of Aeronautical Materials,2005(2):1-5.
- [25] 雍岐龙,孙新军,郑磊,等.钢铁材料中第二相的作用[J].科技创新导报,2009(8):2-3.YONG Qi-long,SUN Xin-jin,ZHENG Lei,et al.The role of the second phase in iron and steel materials[J].Science and Technology Innovation Herald,2009(8):2-3.
- [26] 赵振业,李春志,李志,等.一种超高强度不锈齿轮钢强化相研究[J].航空材料学报,2003(1):1-6.ZHAO Zhen-ye,LI Chun-zhi,LI Zhi,et al.Study on the strengthening phase in a ultra-high strength stainless gear steel[J].Journal of Aeronautical Materials,2003(1):1-6.
- [27] 刘振宝,梁剑雄,杨志勇.Mo在马氏体沉淀硬化不锈钢中的作用与应用[J].连铸,2015,40(3):44-48.LIU Zhen-bao,LIANG Jian-xiong,YANG Zhi-yong.Effect and application of Mo in martensitic precipitationhardening stainless steel[J].Continuous Casting,2015,40(3):44-48.
- [28] 王康,杨卯生,樊刚,等.16Cr14Co12Mo5耐热耐蚀轴承钢强韧化机制的研究[J].钢铁,2011,46(10):75-79.WANG Kang,YANG Mao-sheng,FAN Gang,et al.Investigation on mechanism of strength-toughening of heat and corrosion resistant bearing steel 16Cr14Co12Mo5[J].Iron and Steel,2011,46(10):75-79.
- [29] Schnitzer R,Zickler G A,Lach E,et al.Influence of reverted austenite on static and dynamic mechanical properties of a PH 13-8 Mo maraging steel[J].Materials Science and Engineering A,2010,527(7/8):2065-2070.
- [30] 魏恒,郑少波,王淼,等.影响低碳钢屈强比的显微因素[J].上海金属,2012,34(2):19-22.WEI Heng,ZHENG Shao-bo,WANG Miao,et al.Effect of microstructues factor on yield ratio of low carbon steel[J].Shanghai Metals,2012,34(2):19-22.
- [31] Tl A,Zc B,Hui W C,et al.A new 2.4 GPa extra-high strength steel with good ductility and high toughness designed by synergistic strengthening of nano-particles and high-density dislocations[J].Scripta Materialia,2020,178:285-289.
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