氨水浓度对38CrMoAl钢液相等离子体电解渗氮层显微组织及性能的影响Effect of ammonia concentration on microstructure and properties of liquid phase plasma electrolytic nitrided layer of 38CrMoAl steel
周浪,邹爱华,夏天成,顾晓晓
摘要(Abstract):
在不同氨水浓度的电解液中,采用液相等离子体渗透技术在38CrMoAl钢表面制备了渗氮层。采用光学显微镜(OM)、扫描电镜(SEM)和X射线衍射仪(XRD)等对渗氮层的显微组织、相组成进行了观察和分析,并采用Parstat2273电化学工作站测试了渗氮层的耐蚀性能,并对其显微硬度和耐磨性进行了测试,研究了氨水浓度对38CrMoAl钢液相等离子体渗氮显微组织与性能的影响。结果表明:随着氨水浓度的增大,渗氮层中的白亮层厚度呈增加趋势,分布着针状的氮化物和细小碳化物的扩散层厚度和渗氮层最大显微硬度值呈先增加后降低的趋势;当氨水浓度为60%时,渗氮层厚度达160μm,其中扩散层为112μm,渗氮层硬度最高为1023 HV0.1,约是基体硬度的3.5倍;渗氮层主要以Fe_2N、Fe_3N相等为主;渗氮层的耐磨性能和耐腐蚀优于基体。
关键词(KeyWords): 氨水浓度;38CrMoAl钢;液相等离子体;渗氮层;性能;显微组织
基金项目(Foundation): 国家自然科学基金(52027816)
作者(Author): 周浪,邹爱华,夏天成,顾晓晓
DOI: 10.13289/j.issn.1009-6264.2023-0054
参考文献(References):
- [1] 王彬,薛文斌,金小越,等.金属表面液相等离子体电解渗硼技术[J].表面技术,2019,48(7):37-48.WANG bin,XUE Wen-bin,JIN Xiao-yue,et al.Plasma electrolytic boriding technology on surface of metals[J].Surface Technology,2019,48(7):37-48.
- [2] Mukhacheva T L,Belkin P N,Burov S V,et al.Increasing wear resistance of austenitic stainless steel by anodic plasma electrolytic nitrocarburising[J].Journal of Physics:Conference Series,2020,1713(1):012031.
- [3] Tambovskiy I,Mukhacheva T,Gorokhov I,et al.Features of cathodic plasma electrolytic nitrocarburizing of low-carbon steel in an aqueous electrolyte of ammonium nitrate and glycerin[J].Metals,2022(12):1773-1789.
- [4] 王亚明,邹永纯,王树棋,等.金属微弧氧化功能陶瓷涂层设计制备与使役性能研究进展[J].中国表面工程,2018,31(4):20-45.WANG Ya-ming,ZOU Yong-chun,WANG Shu-qi,et al.Research progress on design preparation and service performance of metal micro arc oxidation functional ceramic coatings[J].China Surface Engineering,2018,31(4):20-45.
- [5] Kusmanov S A,Tambovskiy I V,Silkin S A,et al.The effect of plasma electrolytic polishing on the surface properties of nitrocarburised steel[J].Journal of Physics:Conference Series,2020,1713(1):012023.
- [6] 郭强.碳源对不锈钢表面渗碳层组织和性能的影响研究[D].哈尔滨:哈尔滨工程大学,2018.GUO Qiang.Effect of carbon source on microstructure and properties of carburized layer on stainless steel surface[D].Harbin:Harbin Engineering University,2018.
- [7] Simao J,Lee H G,Aspinwall D K,et al.Workpiece surface modification using electrical discharge machining[J].International Journal of Machine Tools and Manufacture,2003,43(2):121-128.
- [8] 金小越,吴杰,杨璇,等.槽电压对纯铁表面液相等离子体电解硼碳氮三元共渗层摩擦磨损性能的影响[J].材料工程,2017,45(4):58-64.JIN Xiao-yue,WU Jie,YANG Xuan,et al.Effect of cell voltage on friction and wear properties of liquid phase plasma electrolytic boron carbonitriding layer on pure iron[J].Journal of Materials Engineering,2017,45(4):58-64.
- [9] Wang B,Xue W B,Jin X Y,et al.Combined treatment plasma electrolytic carburizing and borocarburizing on Q235 low-carbon steel[J].Materials Chemistry and Physics,2019,221(1):232-238.
- [10] 谢越.钢铁表面阳极液相等离子体渗入改性理论及试验研究[D].哈尔滨:哈尔滨工程大学,2020.XIE Yue.Theoretical and experimental study on anode liquid phase plasma infiltration modification of steel surface[D].Harbin:Harbin Engineering University,2020.
- [11] 刘瑞良,宋天宇,边城鑫,等.等离子体电解渗入技术及其在不锈钢表面改性中的应用研究进展[J].材料热处理学报,2020,41(12):1-15.LIU Rui-liang,SONG Tian-yu,BIAN Cheng-xin,et al.Research progress of plasma electrolytic saturation technology and its application in surface modification of stainless steel[J].Transactions of Materials and Heat Treatment,2020,41(12):1-15.
- [12] 黄洁雯.钛合金阴极等离子电解沉积机制研究[D].南京:南京理工大学,2019.HUANG Jie-wen.Study on cathodic plasma electrodeposition mechanism of titanium alloy[D].Nanjing:Nanjing University of Technology,2019.
- [13] 张蓬予,朱新河,付景国,等.电压对低碳钢表面液相等离子体电解碳氮共渗层的摩擦学性能影响[J].科学技术与工程,2020,20(20):8107-8112.ZHANG Peng-yu,ZHU Xin-he,FU Jing-guo,et al.Effect of voltage on tribological properties of Plasma electrolytic carbonitriding layer on low carbon steel surface[J].Science Technology and Engineering,2020,20(20):8107-8112.
- [14] Tarakci M,Korkmaz K,Gencer Y,et al.Plasma electrolytic surface carburizing and hardening of pure iron[J].Surface Coating Technology,2005,199(23):205-212.
- [15] Nevyantseva R R,Gorbatkov S A,Parfenov E V,et al.The influence of vapor-gaseous envelope behavior on plasma electrolytic coating removal[J].Surface and Coatings Technology,2001,148(1):30-37.
- [16] Andrei V A,Malinovschi V,Radulescu C,et al.Applications of plasma electrolytic saturation technique in the field of nuclear materials[J].Journal of Science and Arts,2019,1(46):185-194.
- [17] Krivenko A G,Manzhos R A,Kotkin A S.Plasma-assisted electrochemical exfoliation of graphite in the pulsed mode[J].High Energy Chemistry,2018,52(3):272-273.
- [18] Krivenko A G,Manzhos R A,Kochergin V K,et al.Plasma electrochemical synthesis of few-layer graphene structures for modification of epoxy binder[J].High Energy Chemistry,2019,53(3):254-260.
- [19] Belkin V S,Belkin P N,Krit B L,et al.Increasing wear resistance of low-carbon steel by anodic plasma-electrolytic nitroboriding[J].Journal of Materials Engineering and Performance,2020,29(1):564-572.
- [20] Nie X,Wilson A,Leyland A,et al.Deposition of duplex Al2O3/DLC coating on Al alloys for tribological applications using a combined micro-arc oxidation and plasma-immersion ion implantation technique[J].Surface and Coating Technology,2000,131(1/3):506-513.
- [21] Yerokhin A,Mukaeva V R,Parfenov E V,et al.Charge transfer mechanisms underlying contact glowdischarge electrolysis[J].Electrochim Acta,2019,312(6):441-456.
- [22] Apelfeld A,Grigoriev S,Krit B,et al.Improving the stability of the coating properties for groupplasma electrolytic oxidation[J].Manufacturing Letters,2022,33(8):54-59.
- [23] Grigoriev S N,Vereschaka A A,Fyodorov S V,et al.Comparative analysis of cutting properties andnature of wear of carbide cutting tools with multi-layered nano-structured and gradient coatings produced by using of various deposition methods[J].The International Journal of Advanced Manufacturing Technology,2017,90(9/12):3421-3435.
- [24] Aliofkhazraei M,Sabour Rouhaghdam A,Gupta P.Nano-fabrication by cathodic plasma electrolysis[J].Critical Reviews in Solid State and Materials Sciences,2011,36(3):174-190.
- [25] 朱宗宁.活塞环表面液相等离子体电解渗氮及改性层性能研究[D].镇江:江苏大学,2020.ZHU Zong-ning.Study on the plasma electrolytic nitriding on the surface of piston ring in solution and perfromances of the modified layer[D].Zhenjiang:Jiangsu University,2020.
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