张勤,李玉海,刘馨

• 1:沈阳理工大学材料科学与工程学院

摘要(Abstract)：

采用微弧氧化技术在TC4钛合金表面制备复合陶瓷膜,研究了在Na2SiO3-NaH2PO4体系电解液中分别添加K2ZrF6和氧化锆粉对膜层组织结构和性能的影响。利用扫描电镜(SEM)和X射线衍射仪(XRD)分析膜层的微观组织和相组成。用MMW-1A万能摩擦磨损试验机对复合陶瓷膜进行了耐磨性能测试。结果表明,当溶液中分别添加了K2ZrF6和氧化锆粉后,都会使陶瓷膜的厚度增加,膜层表面粗糙度降低,且膜层中大尺寸缺陷减少。添加K2ZrF6和氧化锆粉所制备的膜层中主要由金红石型TiO2和ZrO2相组成,且添加氧化锆粉制备的陶瓷膜中的ZrO2含量比添加K2ZrF6制备的膜中含量要多。添加K2ZrF6和氧化锆粉所制备的陶瓷膜的耐磨性能得到提高。

关键词(KeyWords)： TC4;微弧氧化;复合陶瓷膜;耐磨性能

Abstract:

Keywords:

基金项目(Foundation): 沈阳市科技计划项目(F1226840)

作者(Author): 张勤,李玉海,刘馨

DOI: 10.13289/j.issn.1009-6264.2014.09.039

参考文献(References)：

• [1]薛文斌,邓志威,陈如意,等.钛合金在硅酸盐溶液中微弧氧化陶瓷膜的组织结构[J].金属热处理,2000(2):5-6.XUE Wen-bin,DENG Zhi-wei,CHEN Ru-yi,et al.Microstructure of ceramic coating formed by microarc oxidation in silicate solution on Ti6Al4V alloy[J].Heat Treatment of Metals,2000(2):5-6.
• [2]高广睿,李争显,杜继红.TC4合金表面微弧氧化膜层耐蚀及摩擦性能研究[J].稀有金属材料与工程,2008,37(S4):602-605.GAO Guang-rui,LI Zheng-xian,DU Ji-hong.Wear and corrosion resistance properties of TC4 alloy micro-arc oxidized coating[J].Rare Metal Materials and Engineering,2008,37(S4):602-605
• [3]Gnedenkov S V,Sinebryukhov S L,Skorobogatova T M,et al.Properties of coatings formed on titanium by micro-arc oxidation in hypophosphitealuminate electrolytes[J].Russian Journal of Electrochemistry.1998,34(9):940-945.
• [4]邓志威,薛文斌,汪新福,等.铝合金表面微弧氧化技术[J].材料保护,1996,29(2):15-16.
• [5]蒋百灵,吴国建,张淑芬,等.镁合金微弧氧化陶瓷层生长过程及微观结构的研究[J].材料热处理学报,2002,23(1):5-7.JIANG Bai-ling,WU Guo-jian,ZHANG Shu-fen,et al.Research on micromechanism and growth procedure of ceramic coating formed by micro-arc oxidation on magnesium alloys[J].Transactions of Materials and Heat Treatment,2002,23(1):5-7.
• [6]付伟,郭琳琳,陈明华,等.复合陶瓷膜的研究现状及发展前景[J].陶瓷,2006(12):5-7.FU Wei,GUO Lin-lin,CHEN Ming-hua,et al.Current status and developing prospect of composite ceramic membranes[J].Ceramics,2006(12):5-7.
• [7]MU W Y,Han Y.Characterization and properties of the MgF2/ZrO2composite coatings on magnesium prepared by micro-arc oxidation[J].Surface&Coatings Technology,2008,202:4278-4284.
• [8]辛世刚,赵荣根,都徽,等.铝合金表面氧化锆等离子体电解氧化涂层的制备及形成机理研究[J].无机材料学报,2009,24(1):107-110.XIN Shi-gang,ZHAO Rong-gen,DU Hui,et al.Prepare and formation mechanism of the zirconia coating on aluminium alloy by plasma electrolytic oxidation[J].Journal of Inorganic Meterials,2009,24(1):107-110.
• [9]夏伶勤,韩建民,李卫京,等.添加K2ZrF6对钛合金微弧氧化膜层组织结构的影响[J].北京交通大学学报,2013,37(2):114-118.XIA Ling-qin,HAN Jian-min,LIN Wei-jing,et al.Effects of K2ZrF6additive on microstructure of micro-arc coatings fabricated on TA15 alloy[J].Journal of Beijing Jiaotong University,2013,37(2):114-118.
• [10]张欣盟,陈东方,巩春志,等.添加K2ZrF6对LY12铝合金微弧氧化膜层结构调制及隔热性能影响[J].无机材料学报,2010,25(8):865-870.ZHANG Xin-meng,CHEN Dong-fang,GONG Chun-zhi,et al.Modulation effects of K2ZrF6addition on microstructure and heat resistance of micro-arc oxide coatings fabricated on LY12 aluminum alloy[J].Journal of Inorganic Materials,2010,25(8):865-870.
• [11]李玉海,赵艳,赵晖,等.Na2WO4和SiCp对2A12铝合金微弧氧化膜的影响[J].特种铸造及有色合金,2011,31(2):187-190.LI Yu-hai,ZHAO Yan,ZHAO Hui,et al.Effects of Na2WO4and SiCpon micro-arc oxidation coatings on 2A12 aluminum alloy[J].Special Casting&Nonferrous alloys,2011,31(2):187-191.
• [12]王亚明,雷廷权,蒋百灵,等.Na2SiO3-KOH-(NaPO3)6溶液中Ti6Al4V微弧氧化陶瓷膜研究[J].稀有金属材料与工程,2003,32(12):1041-1044.WANG Ya-ming,JIANG Bai-ling,LEI Ting-quan,et al.Ceramic coatings formed on Ti6Al4V alloy by micro-arc oxidation in Na2SiO3-KOH-(NaPO3)6solution[J].Rare Metal Materials and Engineering,2003,32(12):1041-1044.
• [13]王亚明,蒋百灵,雷廷权,等.Na2SiO4系溶液中Ti6Al4V微弧氧化陶瓷膜的结构与力学性能[J].稀有金属材料与工程,2004,33(5):502-506.WANG Ya-ming,JIANG Bai-ling,LEI Ting-quan,et al.Microstructure and mechanical properties of ceramic coatings produced on Ti6Al4V by microarc oxidation in Na2SiO4solution[J].Rare Metal Materials and Engineering,2004,33(5):502-506.
• [14]赵晖,朱其柱,万智来,等.脉冲占空比对钛合金微弧氧化膜及电流密度的影响[J].电镀与精饰,2011,33(2):34-36.ZHAO Hui,ZHU Qi-zhu,WAN Zhi-lai,et al.Effect of duty cycle on film and current density of pluse mico-arc oxidation on titanium alloy[J].Plating and Finishing,2011,33(2):34-36.

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