电流密度对5083铝合金微弧氧化过程与电化学腐蚀性能的影响Effect of current density on formation and electrochemical corrosion resistance of micro-arc oxidization coatings on 5083 aluminum alloy
王红美,尹艳丽,帅刚,邱骥,马世宁
摘要(Abstract):
在含有磷酸钠和钼酸钠的电解液中采用恒流模式对5083铝合金进行微弧氧化。研究了电流密度对氧化电压、膜层生长速率的影响;采用扫描电镜和能谱对氧化膜的表面形貌和成分进行了分析;采用电化学极化曲线测试了氧化膜的耐腐蚀性能。结果表明:在恒电流微弧氧化过程中,氧化电压出现直线快速增长和平稳增长两个阶段,且随着电流密度的增加电压逐渐增大;随着电流密度的增大,氧化膜厚度增加,其表面微弧放电产生的微孔数量逐渐减少,而"火山堆积"状形貌特征越来越明显,电流密度过大氧化膜出现局部剥落,其对氧化膜成分影响不明显;微弧氧化陶瓷膜提高了铝合金基体的耐腐蚀性能,当电流密度为7.5 A/dm2时,微弧氧化膜的自腐蚀电流为1.9×10-8A/cm2,比铝合金基体降低了1个数量级,表现出良好的耐腐蚀性能。
关键词(KeyWords): 5083铝合金;微弧氧化;陶瓷膜;电流密度
基金项目(Foundation): 北京自然科学基金(3132024);; “十二五”装备预研基金(51327040101)
作者(Author): 王红美,尹艳丽,帅刚,邱骥,马世宁
DOI: 10.13289/j.issn.1009-6264.2016.03.028
参考文献(References):
- [1]Gordienko P S,Skorobogatova T M,Khrisanfova O A,et al.Protection from bimetal corrosion in a steel titanium pair by microarc oxidation[J].Prot Metals,1992,28:92-96.
- [2]葛延峰,蒋百灵,时惠英.电流脉冲宽度对铝合金微弧氧化过程的影响[J].材料热处理学报,2013,34(10):165-169.GE Yan-feng,JIANG Bai-ling,SHI Hui-ying.Effect of current pulse width on micro-arc oxidation process for aluminum alloy[J].Transactions of Materials and Heat Treatment,2013,34(10):165-169.
- [3]WEN Lei,WANG Ya-ming,ZHOU Yu,et al.Corrosion evaluation of microarc oxidation coatings formed on 2024 aluminium alloy[J].Corrosion Science,2010,52:2687-2696.
- [4]DING Hong-yan,DAI Zhen-dong,Suresh C S,et al.Corrosion wear behaviors of micro-arc oxidation coating of Al2O3on 2024Al in different aqueous environments at fretting contact[J].Tribology International,2010,43:868-875.
- [5]赵坚,宋仁国,李红霞,等.Na2Si O3浓度对6063铝合金微弧氧化层组织与性能的影响[J].材料热处理学报,2010,31(1):146-149.ZHAO Jian,SONG Ren-guo,LI Hong-xia,et al.Effect of Na2Si O3concentration on structure and performance of ceramic coatings prepared by microarc oxidation on 6063 aluminum alloy[J].Transactions of Materials and Heat Treatment,2010,31(1):146-149.
- [6]Li H X,Rudnev V S,Zheng X H,et al.Characterization of Al2O3ceramic coatings on 6063 aluminium alloy prepared in borate electrolytes by microarc oxidation[J].Journal of Alloys and Compounds,2008,462:99-102.
- [7]翟文杰,朱宝全,刘莲芳.典型介质中7A04微弧氧化膜的摩擦电化学行为[J].材料科学与工艺,2010,18(3):373-377.ZHAI Wen-jie,ZHU Bao-quan,LIU Lian-fang.Tribo-eletrochemical characteristics of 7A04 micro-arc oxidation films in typical solutions[J].Materials Science&Technology,2010,18(3):373-377.
- [8]国春艳,刘向东,张雅萍,等.电解液中Ce(NO3)3含量对ZAl Si12合金微弧氧化层特性的影响[J].材料热处理学报,2010,31(3):132-136.GUO Chun-yan,LIU Xiang-dong,ZHANG Ya-ping,et al.Effect of content of Ce(NO3)3in electrolyte on characteristics of ceramic coating formed by microarc process on ZAl Si12 alloy[J].Transactions of Materials and Heat Treatment,2010,31(3):132-136.
- [9]GUO Qiao-qin,JIANG Bai-ling,LI Jian-ping,et al.Corrosion resistance of micro-arc oxidized ceramic coating on cast hypereutectic alloy[J].Transactions of Nonferrous Metals Society of China,2010,20:2204-2207.
- [10]王平,郭小阳,王春华,等.电流密度对ZL108铝合金微弧氧化膜性能的影响[J].稀有金属材料与工程,2012,41(S2):174-177.WANG Ping,GUO Xiao-yang,WANG Chun-hua,et al.Effect of current density on properties of the ceramic coating formed on ZL108 alloy[J].Rare Metal Materials and Engineering,2012,41(S2):174-177.
- [11]Cai J S,Cao F C,Chang L R,et al.The preparation and corrosion behavious of MAO coating on AZ91D with rare earth conversion precursor film[J].Applied Surface Science,2011,257:3804-3811.
- [12]Salih D,Aylin A,Metin U.Characterization and corrosion behavior of ceramic coating on magnesium by micro-arc oxidation[J].Journal of Alloy and Compounds,2011,509:8601-8606.
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