CoFe/Ni(OH)2/NF电极的制备及性能Preparation and properties of CoFe/Ni(OH)2/NF electrode
卫学玲,包维维,邹祥宇,艾桃桃,李文虎,蒋鹏
摘要(Abstract):
采用两步水热法制备了CoFe/Ni(OH)_2/NF催化电极。利用X射线衍射仪(XRD)、X光电子能谱仪(XPS)、扫描电镜(SEM)和透射电镜(TEM)对CoFe/Ni(OH)_2/NF催化电极的物相、组成和形貌进行表征。在1 mol/L KOH电解液中对电极的电催化析氧反应(OER)、析氢反应(HER)和全解水性能进行了测试。结果表明:CoFe/Ni(OH)_2/NF电极为三维核壳结构,在OER和HER测试过程中驱动10 mA/cm~2的电流密度分别需要147 mV和98 mV的过电势,表现出稳定的催化活性和循环稳定性。以CoFe/Ni(OH)_2/NF催化电极为阴阳极的全解水池在1.6 V工作电压下即可产生20 mA/cm~2的水分解电流密度,并具有100 h的耐久性,表现出高效的碱性全解水性能。
关键词(KeyWords): 催化电极;析氧反应;析氢反应;全解水
基金项目(Foundation): 国家自然科学基金青年基金(51504147);; 陕西理工大学校级科研基金(SLGQD13(2)-18)
作者(Author): 卫学玲,包维维,邹祥宇,艾桃桃,李文虎,蒋鹏
DOI: 10.13289/j.issn.1009-6264.2022-0315
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