不同凝固条件下Mg95.81Zn3.60Y0.59合金凝固过程及凝固组织Solidification process and solidified microstructure of Mg95.81Zn3.60Y0.59 alloy under different solidification conditions
李博,董允,樊志斌,徐高鹏,谢宏斌,周婷
摘要(Abstract):
采用Factsage热化学软件计算了平衡条件和Scheil条件下实验合金的凝固路径及相组成。在与之对比基础上研究了常规铸造(金属型)和4 GPa高压下凝固的实验合金凝固过程和相组成。结果表明:金属型铸造下,四相包共晶转变和随后的WMg_3Y_2Zn_3相分解不充分,室温下凝固组织由α-Mg基体,W-Mg_3Y_2Zn_3和I-Mg_3YZn_6相组成。4 GPa高压下凝固时,因液相线温度升高及单位面积α-Mg晶体形核率大幅增多,使α-Mg相所占体积分数增多,分布在枝晶间最后凝固的共晶液相发生偏析型离异共晶转变,生成面积尺寸很小的骨骼状共晶相半连续分布在枝晶间。4 GPa高压下凝固时,当熔体过热度很小时,初生晶α-Mg为规则的、分枝不发达的等轴晶(晶粒尺寸为20μm);随熔体过热度升高,不但晶粒尺寸增大,枝晶分叉、二次枝晶重熔、破碎等现象也逐渐显现;4 GPa高压下凝固组织由α-Mg+I-Mg_3YZn_6相组成。
关键词(KeyWords): Scheil凝固;高压凝固;凝固过程;离异共晶;晶粒尺寸
基金项目(Foundation): 国家自然科学基金(51675092);; 河北省自然科学基金(E2014501123)
作者(Author): 李博,董允,樊志斌,徐高鹏,谢宏斌,周婷
DOI: 10.13289/j.issn.1009-6264.2017.01.005
参考文献(References):
- [1]Somekawa H,Watanabe H,Mukai T.Damping properties in Mg-Zn-Y alloy with dispersion of quasicrystal phase particle[J].Materials Letters,2011,65(21):3251-3253.
- [2]Mabuchi M,Yamada Y,Shimojima K,et al.In:Kainer K eds.Magnesium Alloys and Their Applications[M].Weinheim:Wiley-VCH,2000.
- [3]王宏伟,朱冬冬,邹鹑鸣,等.高压凝固对Ti-48Al合金片层组织及其力学性能影响[J].稀有金属材料与工程,2012,41(1):42-44.WANG Hong-wei,ZHU Dong-dong,ZOU Chun-ming,et al.Effect of high pressure on the lamellar spacing and mechanical properties of Ti-48Al alloy[J].Rare Metal Materials and Engineering,2012,41(1):42-44.
- [4]Li R X,Li R D,Bai Y H et al.Effect of specific pressure on microstructure and mechanical properties of squeeze casting ZA27 alloy[J].Transactions of Nonferrous Metals Society of China,2010,20(1):59-63.
- [5]Yu X F,Zhang G Z,Wang X Y et al.Non-equilibrium microstructure of hyper-eutectic Al-Si alloy solidified under superhigh pressure[J].Journal of Materials Science,1999,34(17):4149-4152.
- [6]张国志,于溪凤,张雅静,等.Al-Si合金超高压凝固过饱和固溶体的时效组织与性能[J].材料与冶金学报,2006,5(1):61-63.ZHANG Guo-zhi,YU Xi-feng,ZHANG Ya-jing,et al.Precipitated structure and properties of Al-Si alloy extended solution solidified at high pressure[J].Journal of Materials and Metallurgy,2006,5(1):61-63.
- [7]Wang H W,Zhu D D,Zou C M et al.Evolution of the microstructure and nanohardness of Ti-48 at.%Al alloy solidified under high pressure[J].Materials and Design,2012,34:488-493.
- [8]Luo Z P,Zhang S Q,Tang A L.Quasicrystals in as-cast Mg-Zn-RE alloys[J].Scripta Mater,1993,28(12):1513-1518.
- [9]Chen B,Chen L,Lin D L et al.Effect of zirconium addition on microstructure and mechanical properties of Mg97Y2Zn1alloy[J].Transactions of Nonferrous Metals Society of China,2012,22(4):773-778.
- [10]Wang Z X,Lu J B,Xi Y J et al.Phase transitions of Cu-based alloys under high pressure[J].Journal of Alloys and Compounds,2010,492(1):529-531.
- [11]Wang D Q,Yang G C,Lin L et al.Equilibrium and non-equilibrium microstructures of Mg-Zn-Y quasicrystal alloy[J].Materials Letters,2008,62:1711-1714.
- [12]Wang S C,Chou C P.Effect of adding Sc and Zr on grain refinement and ductility of AZ31 magnesium alloy[J].Journal of Materials Processing Technology,2008,197(1/3):116-121.
- [13]Huang Y D,Kainer K U,Hort N.Mechanism of grain refinement of Mg-Al alloys by Si C inoculation[J].Scripta Materialia,2011,64(8):793-796.
- [14]Zhang A M,Hao H,Zhang X G.Grain refinement mechanism of Al-5C master alloy in AZ31 magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2013,23(11):3167-3172.
- [15]Zhang Q,Liu B,Niu Z Y et al.Grain refinement and mechanical properties of Mg-5Li-3Al alloy inoculated by Al-5Ti-1B master alloy[J].Materials Science and Engineering:A,2014,619:152-157.
- [16]Sun M,Hu X Y,Peng L M,et al.Effects of Sm on the grain refinement,microstructures and mechanical properties of AZ31 magnesium alloy[J].Materials Science and Engineering A,2014,620:89-94.
- [17]Liu S F,Chen Y,Han H.Mechanical and magnetic behavior of oligocrystalline Ni-Mn-Ga microwires[J].Journal of Alloys and Compounds,2015,624:226-233.
- [18]林小娉,董允,徐瑞,等.超高压凝固条件下Mg-6zn-3Y合金的晶体形态及相演变[J].金属学报,2011,47(12):1550.LIN Xiao-ping,DONG Yun,XU Rui,et al.Crystal morphologies and the phases in the Mg-6Zn-3Y alloy solidified under super-high pressure[J].Acta Metallurgica Sinica,2011,47(12):1550-1554.
- [19]林小娉,董允,徐瑞,等.GPa级超高压下Mg-6Zn-1Y合金晶体形态及凝固组织分析[J].稀有金属材料与工程,2013,42(11):2309-2314.LIN Xiao-ping,DONG Yun,XU Rui,et al.Solidification microstructures and crystalline morphologies of Mg-6Zn-Y alloy solidified under GPa level super-high pressure[J].Rare Metal Materials and Engineering,2013,42(11):2309-2314.
- [20]董允,林小娉,徐瑞,等.GPa级高压下Mg-Zn-Y合金凝固过程及准晶形成[J].稀有金属材料与工程,2013,43(5):1117-1122.DONG Yun,LIN Xiao-ping,XU Rui,et al.Solidification process and formation of quasi-crystal phase in Mg-6Zn-1Y alloy under pressure in the order of GPa[J].Rare Metal Materials and Engineering,2013,43(5):1117-1122.
- [21]董允,林小娉,徐瑞,等.超高压凝固Mg82.13Zn13.85Y4.02合金的组织及室温压缩性能[J].金属学报,2014,50(5):594-600.DONG Yun,LIN Xiao-ping,XU Rui,et al.Microstructure and room temperature compression properties of Mg82.13Zn13.85Y4.02alloy solidified under super-high pressure[J].Acta Metallurgica Sinica,2014,50(5):594-600.
- [22]张士佼,边秀房,景元高,等.压铸铝铁合金的组织与性能[J].特种铸造及有色合金,2007,27(9):698-701.ZHANG Shi-jiao,BIAN Xiu-fang,JING Yuan-gao,et al.Microstructure and properties of Al-Fe die casting alloy[J].Special Casting and Nonferrous Alloys,2007,27(9):698-701.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||