HRB500E微合金化钢筋中钒的化合物析出行为Precipitation behavior of vanadium compounds in HRB500E microalloyed steel bars
尤景田,黎志英,王劼,黄胜,曾泽芸,黎世旺,杨光凯,李长荣
摘要(Abstract):
分析了HRB500E微合金化高强度钢筋中钒的氮化物、碳化物和碳氮化物分别在液相、凝固过程、奥氏体以及铁素体相中的析出热力学条件,并研究了它们在实验钢连铸或热处理过程中的析出规律。结果表明:实验钢中,钒的碳化物和氮化物在钢液中不析出。碳氮化钒(VC_xN_(1-x))中的x值随温度降低而增大,即在高温平衡条件下析出富氮的碳氮化物,在全固溶温度1450 K下析出物为VC_(0.03)N_(0.97)。VN在1176~1448 K温度区间内在奥氏体相中析出,温度低于1176 K时,主要析出物为碳化钒或碳氮化钒。实验钢铁素体相中也观察到有钒的化合物析出,呈椭圆形,析出规律与热力学分析结果基本吻合。
关键词(KeyWords): 高强度钢筋;热力学;碳化钒;氮化钒;碳氮化钒
基金项目(Foundation): 国家自然科学基金(52074095);; 贵州省科技厅科技支撑项目[2022]053
作者(Author): 尤景田,黎志英,王劼,黄胜,曾泽芸,黎世旺,杨光凯,李长荣
DOI: 10.13289/j.issn.1009-6264.2022-0391
参考文献(References):
- [1] 杜杰杰,孙志林,张昕,等.氮对高强度钢筋用钒微合金化钢冲击韧度的影响[J].热处理,2018,33(4):18-23.DU Jie-jie,SUN Zhi-lin,ZHANG Xin,et al.Effect of nitrogen on impact toughness of vanadium microalloyed steel for high-strength bar[J].Heat Treatment,2018,33(4):18-23.
- [2] 王鹏辉,乔宏霞,冯琼,等.氯氧镁水泥混凝土中涂层钢筋的耐久性退化研究[J].建筑材料学报,2020,23(3):563-571.WANG Peng-hui,QIAO Hong-xia,FENG Qiong,et al.Study on durability degradation of coated steel bar in magnesium oxychloride cement concrete[J].Journal of Building Materials,2020,23(3):563-571.
- [3] 周煌,刘铖霖,曹建春,等.高强抗震钢筋原位拉伸的微观组织变形机理[J].钢铁研究学报,2018,30(10):822-829.ZHOU Huang,LIU Cheng-lin,CAO Jian-chun,et al.Microstructure deformation mechanism of in-situ tension of high-strength anti-seismic rebars[J].Journal of Iron and Steel Research,2018,30(10):822-829.
- [4] 刘鑫,冯光宏,张宏亮,等.方坯直轧工艺对钢筋组织和性能差异性的影响[J].钢铁,2018,53(12):92-99.LIU Xin,FENG Guang-hong,ZHANG Hong-liang,et al.Effect of billet direct rolling process on difference in microstructure and mechanical properties of rebar[J].Iron and Steel,2018,53(12):92-99.
- [5] 杨才福.钒钢的技术进展[J].钢铁,2013,48(4):1-11.YANG Cai-fu.Recent development of vanadium microalloying technology[J].Iron and Steel,2013,48(4):1-11.
- [6] 刘金源,邱伟明,李祥龙,等.25MnSiVN高强抗震钢筋组织相变探讨[J].物理测试,2018,36(1):16-21.LIU Jin-yuan,QIU Wei-ming,LI Xiang-long,et al.Discussion about the microstructure transformation of 25MnSiVN high strength reinforcement anti-seismic bars[J].Physics Examination and Testing,2018,36(1):16-21.
- [7] Xu G,Gan X,Ma G,et al.The development of Ti-alloyed high strength microalloy steel[J].Materials and Design,2010,31(6):2891-2896.
- [8] 潘红波,汪杨,阎军,等.Nb含量及工艺对HRB600钢筋组织与性能的影响[J].建筑材料学报,2017,20(3):392-398.PAN Hong-bo,WANG Yang,YAN Jun,et al.Effect of Nb content and process on the microstructure and mechanical properties of HRB600 steel rebar[J].Journal of Building Materials,2017,20(3):392-398.
- [9] 黎洁,谢贤,吕晋芳,等.铌矿资源概述及选矿技术研究进展[J].金属矿山,2021(2):120-126.LI Jie,XIE Xian,Lü Jin-fang,et al.Overview of niobium resources and research progress of mineral processing technology[J].Metal Mine,2021(2):120-126.
- [10] 彭科波,高利坤,饶兵,等.钒资源现状及有机磷类萃取剂萃钒的研究进展[J].工程科学学报,2021,43(5):603-611.PENG Ke-bo,GAO Li-kun,RAO Bing,et al.Current status of vanadium resources and research progress on vanadium extraction with organic phosphorus extractants[J].Chinese Journal of Engineering,2021,43(5):603-611.
- [11] Baker T N.Processes,microstructure and properties of vanadium microalloyed steels[J].Iron Steel Vanadium Titanium,2014,25(9):1083-1107.
- [12] Show B K,Veerababu R,Balamuralikrishnan R,et al.Effect of vanadium and titanium modification on the microstructure and mechanical properties of a microalloyed HSLA steel[J].Materials Science and Engineering A,2010,527(6):1595-1604.
- [13] Chen J,Chen X W,Tang S,et al.Effect of cooling paths on microstructure and mechanical properties of vanadium bearing microalloyed steel[C]//Chinese Materials Congress,Taiyuan,2013:243-249.
- [14] Chun X,Sun Q,Chen X.Research on transformation mechanism and microstructure evolution rule of vanadium-nitrogen microalloyed steels[J].Materials & Design,2007,28(9):2523-2527.
- [15] Shi Z,Yang C,Wang R,et al.Effect of nitrogen on the microstructures and mechanical properties in simulated CGHAZ of vanadium microalloyed steel varied with different heat inputs[J].Materials Science and Engineering A,2016,649:270-281.
- [16] 陈恩普.铁基、镍基、钴基合金熔点计算方法和经验公式[J].特殊钢,1992,13(2):28-30.CHEN En-pu.Calculation method and empirical formula for melting point of iron-based,nickel-based and cobalt-based alloys[J].Special Steel,1992,13(2):28-30.
- [17] Choudhary S K,Ghosh A.Mathematical model for prediction of composition of inclusions formed during solidification of liquid steel[J].ISIJ International.2009,49(12):1819-1827.
- [18] 雍岐龙.钢铁材料中的第二相[M].北京:冶金工业出版社,2006.
- [19] 杨才福,张永权,王瑞珍.钒钢冶金原理与应用[M].北京:冶金工业出版社,2012.
- [20] 王家,黄积荣,林建生.金属的凝固及其控制[M].北京:机械工业出版社,1983.
- [21] 王明林.低碳钢凝固过程含钛析出物的析出行为及其对凝固组织影响的机理研究[D].北京:钢铁研究总院,2003.WANG Ming-lin.Study on the precipitation behavior of titanium-containing precipitates during the solidification process of low carbon steel and the mechanism of its effect on the solidification structure[D].Beijing:Central Iron and Steel Research Institute,2003.
- [22] 陈家祥.连续铸钢手册[M].北京:冶金工业出版社,1991.
- [23] Narita K.Physical chemistry of the groups Va (Ti,Zr),Va (V,Nb,Ta) and the rare earth elements in steel[J].Transactions of the Iron and Steel Institute of Japan,1975,15(3):145-152.
- [24] Zhang K,Sun X,Li Z,et al.Effect of Ti/V ratio on thermodynamics and kinetics of MC in γ/α matrices of Ti-V microalloyed steels[J].Journal of Iron and Steel Research International,2021,28(8):1019-1029.
- [25] 雍岐龙,吴宝榕,孙珍宝,等.二元微合金碳氮化物的化学组成及固溶度的理论计算[J].钢铁研究学报,1989(4):47-52.YONG Qi-long,WU Bao-rong,SUN Zhen-bao,et al.Thermodynamic calculation for composition and solubility of two-constituent microalloy carbonitride[J].Journal of Iron and Steel Research,1989(4):47-52.
- [26] 曾泽芸,李长荣,黎志英,等.HRB500E抗震钢筋中钛化物析出热力学分析[J].钢铁,2020,55(5):50-56.ZENG Ze-yun,LI Chang-rong,LI Zhi-ying,et al.Thermodynamic analysis of titanium compound precipitation in HRB500E seismic steel[J].Iron and Steel,2020,55(5):50-56.
- [27] 杨才福.钒微合金化钢的技术进展与应用[J].钢铁研究学报,2020,32(12):13-27.YANG Cai-fu.Recent development progress and application of vanadium microalloying technology[J].Chinese Journal of Iron and Steel Research,2020,32(12):13-27.
- [28] Todd J A,Li P.Microstructure-mechanical property relationships in isothermally transformed vanadium steels[J].Metallurgical and Materials Transactions A,1986,17(7):1191-1202.
- [29] 柳书平,杨才福,张永权.氮对钒钢性能及析出相的影响[J].金属热处理,2001,26(10):7-9.LIU Shu-ping,YANG Cai-fu,ZHANG Yong-quan.Effect of nitrogen on the property and precipitation phase in vanadium steel[J].Heat Treatment of Metals,2001,26(10):7-9.
- [30] 王安东,王骏宇,田林茂.V(C,N)在含钒微合金钢奥氏体中的析出规律[J].机械工程材料,2016,40(8):23-26.WANG An-dong,WANG Jun-yu,TIAN Lin-mao.Precipitation law of V(C,N) in austenite of vanadium microalloyed steel[J].Materials for Mechanical Engineering,2016,40(8):23-26.
- [31] 陈龙海,李长荣,黎志英,等.HRB500E钢中第二相VC的异质形核分析与晶粒细化[J].材料导报,2020,34(S1):436-439.CHEN Long-hai,LI Chang-rong,LI Zhi-ying,et al.Heterogeneous nucleation analysis and grain refinement of the second phase VC in HRB500E steel[J].Materials Reports,2020,34(S1):436-439.
- [32] 王安仁,王锦楠,李曌亮,等.HRB500E钢中钒的析出行为研究[J].钢铁钒钛,2018,39(5):122-129.WANG An-ren,WANG Jin-nan,LI Zhao-liang,et al.Precipitation behavior of vanadium in HRB500E steel[J].Iron Steel Vanadium Titanium,2018,39(5):122-129.
- [33] 曾泽芸,李长荣,黎志英,等.Nb/V复合强化对高强度钢筋显微组织和性能的影响[J].建筑材料学报,2022,25(8):869-876.ZENG Ze-yun,LI Chang-rong,LI Zhi-ying,et al.Effect of Nb/V composite strengthening on the microstructure and properties of high-strength rebars[J].Journal of Building Materials,2022,25(8):869-876.
- [34] Yang Y,Jia X,Ma Y,et al.Effect of Nb on inclusions and phase transformation in simulated high heat input coarse-grain HAZ of Nb/Ti low carbon microalloyed steel[J].Materials Characterization,2022,189:111966.
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