扩散处理对离子镀铝TiAl合金高温氧化性能的影响Effect of diffusion treatment on high temperature oxidation property of multi-arc ion plating aluminum coatings on TiAl alloy
吴向清,杨志成,谢发勤,田进
摘要(Abstract):
利用多弧离子镀技术在TiAl合金表面制备纯铝层,分别进行720℃×2 h、780℃×2 h和840℃×2 h高温扩散处理,采用SEM、EDS和XRD分析了扩散铝层的微观组织及其相组成,并测试了不同扩散热处理工艺对合金高温氧化性能的影响。结果表明:随着扩散温度升高,镀铝扩散层厚度不断增加,扩散层由表及里形成Al2O3/TiAl3/TiAl2的结构特征,且内部Al元素浓度呈梯度分布;镀铝经扩散处理后的TiAl合金在850℃空气中的氧化速度主要受扩散层元素与基体元素之间的热扩散过程控制。氧化动力学曲线呈对数变化规律。当扩散工艺为840℃×2 h时,镀铝扩散层具有优良的抗高温氧化性能。
关键词(KeyWords): TiAl合金;多弧离子镀铝;扩散处理;高温氧化
基金项目(Foundation): 国家基础研究发展计划项目(2007CB607603);; 陕西省科学技术研究发展计划项目(2006KG03)
作者(Author): 吴向清,杨志成,谢发勤,田进
DOI: 10.13289/j.issn.1009-6264.2013.06.024
参考文献(References):
- [1]李成功,傅恒志,于翘,等.航空航天材料[M].北京:国防工业出版社,2002:79-100.
- [2]Austin C M.Current status of gamma Ti aluminides for aerospace applications[J].Current Opinion in Solid State and Materials Science,1999,4(3):239-242.
- [3]Yoshihara M,Tsniguchi S,Zhu Y C.Effect of ion implantation on the oxidation resistance of TiAl[J].Metallurgical and Materials Transactions A,2003,34(10):2253-2261.
- [4]张宁,林均品,王艳丽,等.W,B,Y合金元素对高铌TiAl基合金高温长期抗氧化性能的影响[J].稀有金属材料与工程,2007,36(5):884-887.ZHANG Ning,LIN Jun-pin,WANG Yan-li,et al.Influence of W,B,and Y elements on antioxidation of high temperature and long term for TiAl basedalloys with high Nb content[J].Rare Metal Materials and Engineering,2007,36(5):884-887.
- [5]Taniguchi S,Uesaki K,Zhu Y C,et al.Influence of implantation of Al,Si,Cr or Mo ions on the oxidation behaviour of TiAl under thermal cycleconditions[J].Materials Science and Engineering A,1999,266(1-2):267-275.
- [6]Li X Y,Taniguchi S,Matsunaga Y,et al.Influence of siliconizing on the oxidation behavior of aγ-TiAl[J].Intermetallics,2003,11(2):143-150.
- [7]Takeshi Izumi,Takumi Nishimoto,Toshio Narta.Formation of nickel aluminide coating onγ-TiAl alloy[J].Intermetallics,2003,11(8):841-848.
- [8]LIU Xiu-bo,WANG Hua-ming.Modification of tribology and high-temperature behavior of Ti-48Al-2Cr-2Nb intermetallic alloy by laser cladding[J].Applied Surface Science,2006,252(16):5735-5744.
- [9]LIU Xiu-bo,Wang Hua-ming.Microstructure,wear and high-temperature oxidation resistance of laser clad Ti5Si3/γ/TiSi composite coatings onγ-TiAlintermetallic alloy[J].Surface and Coatings Technology,2006,200(14-15):4462-4470.
- [10]刘秀波,王华明.工艺参数对TiAl合金激光熔覆复合涂层的影响[J].激光技术,2006,30(1):67-69.LIU Xiu-bo,WANG Hua-ming.The influence of processing parameters on laser cladding composite coatings on TiA1 intermetallic alloy[J].LaserTechnology,2006,30(1):67-69.
- [11]Lee J K,Oh M H,Lee H K,et al.Plasma-sprayed Al-21Ti-23Cr coating for oxidation protection of TiAl alloys[J].Surface and Coatings Technology,2004,182(2-3):363-369.
- [12]吴向清,田进,谢发勤,等.多弧离子镀铝对TiAl合金高温抗氧化性能的影响[J].中国表面工程,2009,22(5):50-55.WU Xiang-qing,TIAN Jin,XIE Fa-qin,et al.Effect on the high temperature oxidation resistance of multi-arc ion plating aluminum films on TiAl alloy[J].China Surface Engineering,2009,22(5):50-55.
- [13]吴向清,谢发勤,胡宗纯,等.扩散铝涂层对TiAl合金高温摩擦磨损性能的影响[J].材料热处理学报,2010,31(6):113-117.WU Xiang-qing,XIE Fa-qin,HU Zong-chun,et al.Effect of diffusion treatment on high temperature friction and wear resistance of aluminium-platedTiAl alloy[J].Transactions of Materials and Heat Treatment,2010,31(6):113-117.
- [14]JIANG Hui-ren,WANG Zhong-lei,MA Wen-shuai,el at.Effects of Nb and Si on high temperature oxidation of TiAl[J].Transactions of NonferrousMetals Society of China,2008,18(3):512-517.
- [15]LU Wei,CHEN Chun-lin,HE Lian-long.Effect of niobium on oxidation behavior of TiAl[J].Journal of Materials Research,2007,22(6):1486-1490.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||