Ag/Cu和Cu/Ni纳米金属多层膜强度软化的理论分析Theoretical analysis for the softening of Ag/Cu and Cu/Ni nanometer multilayer films
任凤章,陈洁,赵士阳,马战红,王宇飞,田保红
摘要(Abstract):
用电沉积法分别制备了具有不同调制波长的Ag/Cu和Cu/Ni金属多层膜,研究了多层膜的硬度与调制波长之间的关系。结果表明,当调制波长λ>300 nm时,两种多层膜的硬度与调制波长符合位错塞积机制的Hall-Petch关系,当λ<300 nm时,都偏离了Hall-Petch关系;Ag/Cu和Cu/Ni多层膜分别在λ=50 nm和100 nm处取得硬度峰值。基于Cheng等人的电子理论分别求出了Ag、Cu和Ni金属晶体的位错稳定的临界晶粒尺寸,进而定量地解释了Ag/Cu和Cu/Ni金属多层膜硬度峰值位置。
关键词(KeyWords): 多层膜;Hall-Petch关系;临界晶粒尺寸;电子理论
基金项目(Foundation): 国家自然科学基金资助项目(50771042);; 河南省基础与前沿技术研究计划资助项目(092300410064);; 河南省科技创新人才计划项目(104100510005);; 河南省高校科技创新人才支持计划资助项目(2009HASTIT023)
作者(Author): 任凤章,陈洁,赵士阳,马战红,王宇飞,田保红
DOI: 10.13289/j.issn.1009-6264.2010.12.002
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