于万秋,田博,刘尧棣

• 1:吉林师范大学物理学院
• 2:吉林师范大学创新创业教育培训中心

摘要(Abstract)：

采用单辊快淬法制备了Fe_(76)Zr_(12)B_(12)和Fe_(75)Zr_(12)B_(12)Cu_1两种非晶合金，对两种非晶合金进行不同温度的等温热处理。利用差示扫描量热仪(DSC)、X射线衍射仪(XRD)和振动样品磁强计(VSM)等分析了两种合金的晶化曲线、晶化相及磁性，研究Cu添加对Fe_(76)Zr_(12)B_(12)合金热稳定性、晶化过程和磁性能的影响。结果表明：Cu的添加增加了Fe_(76)Zr_(12)B_(12)非晶合金的晶化激活能，提高了该非晶合金的热稳定性。两种合金在晶化初期，除了α-Fe相析出，均有ZrB等其他晶化产物析出；高温热处理后，含Cu合金中析出化合物的含量明显高于未添加Cu的合金。Cu的添加没有起到简化Fe_(76)Zr_(12)B_(12)非晶合金晶化过程的作用，但Cu的添加减小了合金中α-Fe相的平均晶粒尺寸。当两种非晶合金的热处理温度高于823 K时，矫顽力(H_c)均明显增大。

关键词(KeyWords)： Fe_(76)Zr_(12)B_(12)非晶合金;Cu添加;热稳定性;晶化过程

Abstract:

Keywords:

基金项目(Foundation): 吉林省教育厅科学技术研究规划项目(JJKH20210451KJ);; 吉林师范大学博士科研启动项目2021

作者(Author): 于万秋,田博,刘尧棣

DOI: 10.13289/j.issn.1009-6264.2022-0107

参考文献(References)：

• [1] He A N,Li J W,Wang M K,et al.Microstructure,magnetic domain and dynamic loss of surface-textured Fe-based nanocrystalline alloy[J].Journal of Materials Science & Technology,2022,120:1-7.
• [2] Parsons R,Zang B,Onodera K,et al.Core loss of ultra-rapidly annealed Fe-rich nanocrystalline soft magnetic alloys[J].Journal of Magnetism and Magnetic Materials,2019,476:142-148.
• [3] Liu T,Li F,Wang A,et al.High performance Fe-based nanocrystalline alloys with excellent thermal stability[J].Journal of Alloys and Compounds,2019,776:606-613.
• [4] 姚可夫，施凌翔，陈双琴，等.铁基软磁非晶/纳米晶合金研究进展及应用前景[J].物理学报，2018,67(1):016101.YAO Ke-fu,SHI Ling-xiang,CHEN Shuang-qin,et al.Research progress and application prospect of Fe-based soft magnetic amorphous/nanocrystalline alloys[J].Acta Physica Sinica,2018,67(1):016101.
• [5] Lashgari H R,Chu D,Xie S,et al.Composition dependence of the microstructure and soft magnetic properties of Fe-based amorphous/nanocrystalline alloys:A review study[J].Journal of Non-Crystalline Solids,2014,391(26):61-82.
• [6] 潘贇，刘天成，陈非非，等.退火温度对FeCuNbSiB纳米晶合金磁性能的影响[J].材料热处理学报，2020,41(3):89-95.PAN Yun,LIU Tian-cheng,CHEN Fei-fei,et al.Effect of annealing temperature on magnetic properties of FeCuNbSiB nanocrystalline alloys[J].Transactions of Materials and Heat Treatment,2020,41(3):89-95.
• [7] Li Y L,Shen N N,Wu Y D,et al.High Bs Fe-B-P-C-Cu nanocrystalline alloy with longtime annealing stability and low heating rate sensitivity[J].Journal of Magnetism and Magnetic Materials,2022,543:168623.
• [8] Ilin N V,Komogortsev S V,Kraynova G S,et al.Magnetic correlations peculiarities in amorphous Fe-Cu-Nb-Si-B alloy ribbons[J].Journal of Magnetism and Magnetic Materials,2022,541:168525.
• [9] Peng K,Tang L,Wu Y.Evolution of microstructure and magnetic properties of Fe73.5Si13.5B9Nb3Cu1 amorphous alloy during ion bombardment process[J].Journal of Magnetism and Magnetic Materials,2018,460:297-301.
• [10] Da N Z,Zhang Y,Takeuchi A,et al.Effect of substitution of Cu by Au and Ag on nanocrystallization behavior of Fe83.3Si4B8P4Cu0.7 soft magnetic alloy[J].Journal of Alloys & Compounds,2016,683:263-270.
• [11] Tang L,Peng K,Wu Y,et al.Effect of ion bombardment on the crystallization kinetics of FeSiNbBCu amorphous alloys[J].Journal of Alloys & Compounds,2017,695:2136-2141.
• [12] Shen B,Inoue A.Soft magnetic properties of bulk nanocrystalline Fe-Co-B-Si-Nb-Cu alloy with high saturated magnetization of 1.35 T[J].Journal of Materials Research,2004,19(9):2549-2552.
• [13] Yu W Q,Lin H,Lu L P,et al.Effect of chemical composition and Cu addition on crystallization and magnetic characteristics of FeZrB alloys[J].Physics Letters A,2020,384(26):126640.
• [14] Yu W Q,Zhou Q L,Liu Z S,et al.Effect of Cu and Mo additions on the crystallization behavior and magnetic properties of Fe80Zr10B10 alloy[J].Journal of Materials Engineering and Performance,2017,26(5):1-6.
• [15] Ma X,Fan S,Luan C,et al.Effect of Cu addition on the braking performance of Fe-Si alloy-modified C/C-SiC brake materials[J].Wear,2021,477:203851.
• [16] Hono K,Ping D H,Ohnuma M,et al.Cu clustering and Si partitioning in the early crystallization stage of an Fe73.5Si13.5B9Nb3Cu1 amorphous alloy[J].Acta Materialia 1999,47(3):997-1006.
• [17] Ayers J D,Sprague V G,Elam W T,et al.On the formation of nanocrystals in the soft magnetic alloy Fe73.5Nb3Cu1Si13.5B9[J].Acta Materialia,1998,46(6):1861-1867.
• [18] Xiong X Y,Muddle B C,Finlayson T R.The effect of Cu addition on the microstructure and low-temperature magnetization of nanocrystalline Fe87-xZr7B6Cux and Fe81-xZr7B12Cux alloys[J].Journal of Physics D:Applied Physics,2003,36(3):223-228.
• [19] Pang L L,Inoue A,Zanaeva E N,et al.Nanocrystallization,good soft magnetic properties and ultrahigh mechanical strength for Fe82-85B13-16Si1Cu1 amorphous alloys[J].Journal of Alloys and Compounds,2019,785:25-37.
• [20] Ohkubo T,Kai H,Ping D H,et al.Mechanism of heterogeneous nucleation of α-Fe nanocrystals from Fe89Zr7B3Cu1 amorphous alloy[J].Scripta Materialia,2001,44(6):971-976.
• [21] Jha R,Diercks D R,Chakraborti N,et al.Interfacial energy of copper clusters in Fe-Si-B-Nb-Cu alloys[J].Scripta Materialia,2019,162:331-334.
• [22] Lashgaria H R,Chu D,Xie S S,et al.Composition dependence of the microstructure and soft magnetic properties of Fe-based amorphous/nanocrystalline alloys:A review study[J].Journal of Non Crystalline Solids,2014,391(26):61-82.
• [23] Herzer G.Chapter 3 Nanocrystalline soft magnetic alloys[J].Handbook of Magnetic Materials,1997,10:415-462.
• [24] Kong F,Wang A,Fan X,et al.High Bs Fe84-xSi4B8P4Cux (x=0-1.5) nanocrystalline alloys with excellent magnetic softness[J].Journal of Applied Physics,2011,109(7):07A303.
• [25] Yu W Q,Lu L P,Zuo B.Primary crystallization phases and magnetic property of FeZrB alloys[J].Rare Metal Materials and Engineering,2020,49(5):1561-1566.
• [26] Kissinger H E.Variation of peak temperature with heating rate in differential thermal analysis[J].Journal of Research of the National Bureau of Standards,1956,57(4):217-221.
• [27] Cui L,Men H,Makino A,et al.Effect of Cu and P on the crystallization behavior of Fe-rich hetero-amorphous FeSiB alloy[J].Materials Transactions,2009,50(11):2515-2520.
• [28] 孙亚明，于万秋，张勇，等.Ag、Cu添加对Fe40Co40Zr6Mo4B10合金热稳定性和磁性能的影响[J].材料导报，2016,30(6):86-88.SUN Ya-ming,YU Wan-qiu,ZHANG Yong,et al.Effects of Ag and Cu on thermal stability and magnetic property of Fe40Co40Zr6Mo4B10 alloy[J].Materials Review,2016,30(6):86-88.
• [29] 高敬恩，李宏祥，陈子潘，等.纳米晶的形成对FeCSiBPCu非晶合金软磁性能的影响[J].功能材料，2013,44(13):1920-1923.GAO Jing-en,LI Hong-xiang,CHEN Zi-pan,et al.Enhancing soft magnetic properties of FeCSiBPCu amorphous alloys by nanocrystallization[J].Jorunal of Functional Materials,2013,44(13):1920-1923.
• [30] Jung H Y,Stoica M,Yi S,et al.Crystallization kinetics of Fe76.5-xC6.0Si3.3B5.5P8.7Cux (x=0,0.5,and 1 at.pct) bulk amorphous alloy[J].Metallurgical & Materials Transactions A,2015,46(6):2415-2421.

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