许可,杨贵荣,宋文明,马颖

• 1:兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室
• 2:机械工业上海蓝亚石化设备检测所有限公司

摘要(Abstract)：

随着对材料摩擦、润滑、粘结、吸附等表面现象研究的深入，各种新型复合涂层材料快速发展并开始逐渐取代传统材料。各种表面工程技术目的是为了制造高硬度及耐磨性优异的复合涂层，通过不同技术获得的涂层仍存在不同程度的孔隙率、结合强度低、断裂韧性低等缺陷，大量研究表明稀土及其氧化物对于改善涂层组织及性能起到了重要作用。本文综述了稀土及其氧化物对涂层微观组织及晶粒的影响及其对力学性能、摩擦学性能的改善效果，并分析了稀土的影响作用机制。在此基础上，探讨了稀土改性涂层的发展前景。

关键词(KeyWords)： 稀土;复合涂层;微观结构;性能

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(51765035,51205178);; 先进反应堆工程与安全教育部重点实验室开放基金课题(ARES-2022-02)

作者(Author): 许可,杨贵荣,宋文明,马颖

DOI: 10.13289/j.issn.1009-6264.2023-0210

参考文献(References)：

• ■,et al.Surface modification of titanium by plasma assisted chemical vapor deposition (PACVD) methods[J].Solid State Phenomena,2013,199:561-566.
• [2] Barshilia H C.Surface modification technologies for aerospace and engineering applications:Current trends,challenges and future prospects[J].Transactions of the Indian National Academy of Engineering,2021,6(2):1-16.
• [3] Pruncu C I,Aherwar A,Gorb S.Tribology and Surface Engineering for Industrial Applications[M].Boca Raton:CRC Press,2021.
• [4] Litvinov A E,Buz’ko V Y,Ivanin S N.Nanostructured wear-resistant coating for the composite turning inserts[J].Journal of Physics:Conference Series,2021,1967(1):012035.
• [5] Nayak S R,Mohana K N S.Corrosion protection performance of functionalized graphene oxide nanocomposite coating on mild steel[J].Surfaces and Interfaces,2018,11:63-73.
• [6] Li M Y,Han B,Qi C H,et al.Investigation on nano-self-lubricant coating synthesized by laser cladding and ion sulfurization[J].Journal of Nanomaterials,2015,16(1):1-8.
• [7] Sadabadi H,Allahkaram S R,Kordijazi A,et al.Self-healing coatings loaded by nano/microcapsules:A review[J].Protection of Metals and Physical Chemistry of Surfaces,2022,58(2):287-307.
• [8] Mondal K,Nu■ez III L,Downey C M,et al.Thermal barrier coatings overview:Design,manufacturing,and applications in high-temperature industries[J].Industrial & Engineering Chemistry Research,2021,60(17):6061-6077.
• [9] Dobuzhskaya A B,Galitsyn G A,Yunin G N,et al.Effect of chemical composition,microstructure and mechanical properties on the wear resistance of rail steel[J].Steel in Translation,2020,50(12):906-910.
• [10] He X,Song R G,Kong D J.Effects of TiC on the microstructure and properties of TiC/TiAl composite coating prepared by laser cladding[J].Optics & Laser Technology,2019,112:339-348.
• [11] Wang D,Ran S,Shen L,et al.Fast synthesis of B4C-TiB2 composite powders by pulsed electric current heating TiC-B mixture[J].Journal of the European Ceramic Society,2015,35(3):1107-1112.
• [12] Yang C,Zhang B,Zhao D,et al.In-situ synthesis of AlN/Mg-Al composites with high strength and high plasticity[J].Journal of Alloys and Compounds,2017,699:627-632.
• [13] Zhou S,Zeng X,Hu Q,et al.Analysis of crack behavior for Ni-based WC composite coatings by laser cladding and crack-free realization[J].Applied Surface Science,2008,255(5):1646-1653.
• [14] Quazi M,Fazal M A,Haseeb A S M A,et al.A review to the laser cladding of self-lubricating composite coatings[J].Lasers in Manufacturing and Materials Processing,2016,3(2):67-99.
• [15] Xu J S,Zhang X C,Xuan F Z,et al.Tensile properties and fracture behavior of laser cladded WC/Ni composite coatings with different contents of WC particle studied by in-situ tensile testing[J].Materials Science and Engineering A,2013,560:744-751.
• [16] Wang D S,Liang E J,Chao M J,et al.Investigation on the microstructure and cracking susceptibility of laser-clad V2O5/NiCrBSiC alloy coatings[J].Surface and Coatings Technology,2008,202(8):1371-1378.
• [17] Wang L M,Lin Q,Yue L J,et al.Study of application of rare earth elements in advanced low alloy steels[J].Journal of Alloys and Compounds,2008,451(1/2):534-537.
• [18] Zhang K M,Zou J X,Jun L,et al.Synthesis of Y2O3 particle enhanced Ni/TiC composite on TC4 Ti alloy by laser cladding[J].Transactions of Nonferrous Metals Society of China,2012,22(8):1817-1823.
• [19] Li M X,Zhang S H,Li H S,et al.Effect of nano-CeO2 on cobalt-based alloy laser coatings[J].Journal of Materials Processing Technology,2008,202(1/3):107-111.
• [20] Tian Y S,Chen C Z,Chen L X,et al.Effect of RE oxides on the microstructure of the coatings fabricated on titanium alloys by laser alloying technique[J].Scripta Materialia,2006,54(5):847-852.
• [21] Zhang H,Zou Y,Zou Z D,et al.Effects of CeO2 on microstructure and corrosion resistance of TiC-VC reinforced Fe-based laser cladding layers[J].Journal of Rare Earths,2014,32(11):1095-1100.
• [22] Stetsovych V,Pagliuca F,Dvo■,et al.Epitaxial cubic Ce2O3 films via Ce-CeO2 interfacial reaction[J].The Journal of Physical Chemistry Letters,2013,4(6):866-871.
• [23] Zhang S H,Li M X,Yoon J H,et al.Microstructure and corrosion resistance of Ni-based alloy laser coatings with nanosize CeO2 addition[J].Science and Technology of Advanced Materials,2008,9(3):035002.
• [24] Ye X,Cao H,Qi F,et al.Effect of Y addition on the microstructure and mechanical properties of ZM31 alloy[J].Materials,2020,13(3):583.
• [25] Dong J T,Luo Z,Zhou L S,et al.Effects of rare earth elements on the quality of nugget in aluminum alloy spot welding[J].Advanced Materials Research,2011,160-162:796-801.
• [26] Shewmon P.Diffusion in Solids[M].Switzerland:Springer Cham,2016.
• [27] Knyazeva A G.The theory of reactive diffusion for the description of oxide phase growth in a coating[J].AIP Conference Proceedings,2015,1683(1):020084.
• [28] Vehkam?ki H.Classical Nucleation Theory in Multicomponent Systems[M].Berlin Heidelberg:Springer-Verlag,2006.
• [29] Liang C J,Wang C L,Zhang K X,et al.Nucleation and strengthening mechanism of laser cladding aluminum alloy by Ni-Cr-B-Si alloy powder based on rare earth control[J].Journal of Materials Processing Technology,2021,294:117145.
• [30] Gong Y L,Wu M P,Miao X J,et al.Effect of CeO2 on crack sensitivity and tribological properties of Ni60A coatings prepared by laser cladding[J].Advances in Mechanical Engineering,2021,13(4):1-12.
• [31] Deng X C,Wang K F,Zhang G H.Effects of oxide addition on structure and properties of WC-10Co cemented carbide obtained by in situ synthesized powder[J].International Journal of Applied Ceramic Technology,2022,19(4):1916-1928.
• [32] Qian S Y,Xu Z H,Xie H N,et al.Effect of rare metal element interfacial modulation in graphene/Cu composite with high strength,high ductility and good electrical conductivity[J].Applied Surface Science,2020,533:147489.
• [33] Zeng Z Y B,Liu Y Z,Zhang Y X,et al.Ferroelastic domain switching toughening in Ce-Y-La co-stabilized zirconia ceramics obtained from coated starting powders[J].Journal of Alloys and Compounds,2020,820:153177.
• [34] Zhang Z,Yang Q,Yang F,et al.Comparative investigation on wear properties of composite coatings with varying CeO2 contents[J].Coatings,2022,12(7):906.
• [35] Xu Z Z,He Z J,Wang Z Y,et al.Effects of CeO2 on the microstructure and properties of laser cladding 316L coating[J].Journal of Materials Engineering and Performance,2019,28(8):4983-4990.
• [36] Han B,Lin J,Han X R,et al.Effect of CeO2 on high-temperature wear resistance of WC/Fe-based coatings[J].Surface Engineering,2021,37(8):982-990.
• [37] Kumar S,Kumar D.Role of CeO2 doping on tribological behavior of Al2O3 coated AZ91 alloy[J].Surface and Coatings Technology,2018,349:462-469.
• [38] Chen Y,Chao Y,Luo Z,et al.Microstructure and wear resistance of Co-based/Cr3C2 coatings with CeO2[J].Surface Engineering,2018,34(8):588-595.
• [39] Fan Y,Jin G,Cui X F,et al.Effect of Nb and CeO2 on the mechanical and tribology properties of Co-based cladding coatings[J].Surface and Coatings Technology,2016,288:25-29.
• [40] Sun S,Fu H,Ping X L,et al.Effect of CeO2 addition on microstructure and mechanical properties of in-situ (Ti,Nb) C/Ni coating[J].Surface and Coatings Technology,2019,359:300-313.
• [41] Weng F,Yu H J,Chew Y X,et al.Microstructure and mechanical behavior of the laser synthesized composites modified by micro/nano scale rare earth oxides[J].Journal of Alloys and Compounds,2022,895:162641.
• [42] Chen Y H,Yang C L,Fan C L,et al.Grain refinement of additive manufactured Ti-6.5 Al-3.5 Mo-1.5 Zr-0.3 Si titanium alloy by the addition of La2O3[J].Materials Letters,2020,275:128170.
• [43] Kang X Y,Lin N,He Y H,et al.Improvement of microstructure,mechanical properties and cutting performance of Ti (C,N)-based cermets by ultrafine La2O3 additions[J].Ceramics International,2021,47(14):19934-19944.
• [44] Wang C,Gao Y,Wang R,et al.Microstructure of laser-clad Ni60 cladding layers added with different amounts of rare-earth oxides on 6063 Al alloys[J].Journal of Alloys and Compounds,2018,740:1099-1107.
• [45] Ding L,Hu S.Effect of nano-CeO2 on microstructure and wear resistance of Co-based coatings[J].Surface and Coatings Technology,2015,276:565-572.
• [46] Majd A M,Farzinfar M,Pashakhanlou M,et al.Effect of RE elements on the microstructural and mechanical properties of as-cast and age hardening processed Mg-4Al-2Sn alloy[J].Journal of Magnesium and Alloys,2018,6(3):309-317.
• [47] Li W S,Lu Y,Yuan K X,et al.Effects of cerium on microstructure and bonding strength of Cu-14Al-4.5 Fe bronze plasma sprayed coating[J].Journal of Rare Earths,2011,29(4):363-369.
• [48] Nayyeri M J,Khomamizadeh F.Effect of RE elements on the microstructural evolution of as cast and SIMA processed Mg-4Al alloy[J].Journal of Alloys and Compounds,2011,509(5):1567-1572.
• [49] Dong W L,Yang X F,Song F,et al.Anti-friction and wear resistance analysis of cemented carbide coatings[J].The International Journal of Advanced Manufacturing Technology,2022,122(7/8):2795-2821.
• [50] Yousefi E,Irannejad A,Sharafi S.Electrodeposition and characterization of nanocrystalline Fe-Ni-Cr alloy coatings synthesized via pulse current method[J].Transactions of Nonferrous Metals Society of China,2019,29(12):2591-2603.
• [51]Ayyagari A,Scharf T W,Mukherjee S.Dry reciprocating sliding wear behavior and mechanisms of bulk metallic glass composites[J].Wear,2016,350-351:56-62.
• [52]Stankovi■M,Marinkovi ■A,Grbovi c'A,et al.Determination of Archard’s wear coefficient and wear simulation of sliding bearings[J].Industrial lubrication and Tribology,2018,71(1):119-125.
• [53] Liu Y N,Yang L J,Yang X J,et al.Optimization of microstructure and properties of composite coatings by laser cladding on titanium alloy[J].Ceramics International,2021,47(2):2230-2243.
• [54] Li J L,Xiong D S,Huang Z J,et al.Effect of Ag and CeO2 on friction and wear properties of Ni-base composite at high temperature[J].Wear,2009,267(1/4):576-584.
• [55] Lian G F,Xiao S H,Zhang Y,et al.Multi-objective optimization of coating properties and cladding efficiency in 316L/WC composite laser cladding based on grey relational analysis[J].The International Journal of Advanced Manufacturing Technology,2021,112(5/6):1449-1459.
• [56] Qi Q,Wang L J,Liu Y,et al.In-situ TiC-Graphite-Ni hybrid composites innovatively fabricated by pressureless reactive infiltration method[J].Journal of Alloys and Compounds,2018,757:273-278.
• [57] Kumar M,Kumar S,Jha K,et al.Composite coating by TIG cladding with different rare earth oxides[J].Surface Engineering,2022,38(3):271-287.
• [58] Pu J,Sun Y B,Wu L,et al.Effect of CeO2 content on microstructure and properties of Ni-based tungsten carbide layer by plasma arc cladding[J].Coatings,2022,12(3):342-349.
• [59] Wang C,Gao Y,Zeng Z C,et al.Effect of rare-earth on friction and wear properties of laser cladding Ni-based coatings on 6063Al [J].Journal of Alloys and Compounds,2017,727:278-285.
• [60] Cai Y C,Luo Z,Chen Y,et al.Influence of CeO2 on tribological behaviour of TiC/Fe-based composite coating[J].Surface Engineering,2017,33(12):936-943.
• [61] Shu D,Cui X X,Li Z G,et al.Effect of the rare earth oxide CeO2 on the microstructure and properties of the nano-WC-reinforced Ni-based composite coating[J].Metals,2020,10(3):383.
• [62] Li D Y,Zhang Z X,Cui X F,et al.Effect of graphite/CeO2 on microstructure and tribological property of plasma cladded Co-based coatings[J].Materials Chemistry and Physics,2022,280:125756.
• [63] Hou X R,Zhao B,Yang J,et al.Fe-0.4 wt.% C-6.5 wt.% Cr hardfacing coating:Microstructures and wear resistance with La2O3 additive[J].Applied Surface Science,2014,317:312-318.
• [64] Kumar S,Dwivedi S P,Sharma S.Friction and adhesive wear study of HVOF sprayed Ni-WC-CO-based powder coating[J].Powder Metallurgy and Metal Ceramics,2018,57:329-335.
• [65] Sun X L,Zhang J K,Pan W G,et al.Research progress in surface strengthening technology of carbide-based coating[J].Journal of Alloys and Compounds,2022,905:164062.
• [66] Yu H,Luo Z A,Wang Y H,et al.Influence of Ni content on the microstructure and reciprocating wear of Fe-based/B4C composite coating by vacuum cladding[J].Surface and Coatings Technology,2021,423:127604.
• [67] Sharma S.Wear study of Ni-WC composite coating modified with CeO2[J].The International Journal of Advanced Manufacturing Technology,2012,61:889-900.
• [68] Shu D,Dai S,Wang G,et al.Influence of CeO2 content on WC morphology and mechanical properties of WC/Ni matrix composites coating prepared by laser in-situ synthesis method[J].Journal of Materials Research and Technology,2020,9(5):11111-11120.
• [69] Yang L,Xue W H,Gao S Y,et al.Study on sliding friction and wear behavior of M50 bearing steel with rare earth addition[J].Tribology International,2022,174:107725.
• [70]Azimi G,Dhiman R,Kwon H M,et al.Hydrophobicity of rare-earth oxide ceramics[J].Nature Materials,2013,12(4):315-320.
• [71]Zem?a M R,■piewak P,Wejrzanowski T,et al.Hydrophobic properties of Al2O3doped with rare-earth metals:Ab initio modeling studies[J].Physica Status Solidi A,2018,215(16):1700895.
• [72] Hao J,Zhang K,Ren P,et al.Tuning the wettability,mechanical and tribological properties of NbN films by doping rare earth cerium[J].Journal of Alloys and Compounds,2020,814:152339.
• [73] Pawlak Z,Urbaniak W,Oloyede A.The relationship between friction and wettability in aqueous environment [J].Wear,2011,271(9/10):1745-1749.
• [74] Huang J Y,Cai L M,Zhang W,et al.Influence of surface structure/wettability on tribological properties of titanium[J].Tribology International,2022,174:107747.
• [75] Zhang L,Tang W,Chen S,et al.Synergetic migration behavior of La and Ce and related microstructure character of Cr-V-RE co-doped WC-Co alloy[J].Journal of Rare Earths,2012,30(5):480-485.

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