热处理对Mg-Zn-Zr-Y合金组织及性能的影响Effect of heat treatment on microstructure and properties of Mg-Zn-Zr-Y alloy
郑浩然,张志璇,谷亚楠,陈其嘉
摘要(Abstract):
为解决因残余应力、组织不均匀性、成分偏析所造成的铸态Mg-3Zn-0.8Zr-1Y(mass%)合金性能不佳的问题,对其进行了固溶和时效处理,研究了热处理工艺对其显微组织、力学性能及耐腐蚀性能的影响。结果表明:Mg-3Zn-0.8Zr-1Y合金的最优热处理工艺是480℃均匀化退火12 h后520℃固溶处理12 h,最后在170℃时效24 h。均匀化退火处理缓解了铸态合金中的偏析现象,固溶处理使铸态合金中的W(Mg_3Y_2Zn_3)相基本融入α-Mg基体中形成过饱和固溶体,时效后组织中析出细小且弥散分布的纳米级短杆状Mg_2Zn_3和颗粒状Mg_4Zn_7第二相。与铸态合金相比,经最优工艺处理后合金的硬度、极限抗拉强度、屈服强度和伸长率分别提升到83.4 HV、204 MPa、139 MPa和12.5%,自腐蚀电位提高到-1.793 V(vs.SCE)、腐蚀电流密度降低到59.64μA/cm~2,腐蚀速率降低到1.36 mm/y,表明这种多步热处理工艺可以使Mg-3Zn-0.8Zr-1Y合金的强度、塑性和耐蚀性显著提高。
关键词(KeyWords): Mg-Zn-Zr-Y合金;热处理;微观组织;力学性能;腐蚀性能
基金项目(Foundation): 滨州学院科研基金项目(2021Y38)
作者(Author): 郑浩然,张志璇,谷亚楠,陈其嘉
DOI: 10.13289/j.issn.1009-6264.2022-0647
参考文献(References):
- [1] 贾红敏,常剑秀.定向凝固镁合金的研究进展及应用前景[J].材料导报,2022,36(6):139-145.JIA Hong-min,CHANG Jian-xiu.Research progress and application prospect of directionally solidified Mg alloys[J].Materials Reports,2022,36(6):139-145.
- [2] Alaneme K K,Kareem S A,Olajide J L,et al.Computational biomechanical and biodegradation integrity assessment of Mg-based biomedical devices for cardiovascular and orthopedic applications:A review[J].International Journal of Lightweight Materials and Manufacture,2022,5(2):251-266.
- [3] Cho D H,Avey T,Nam K H,et al.In vitro and in vivo assessment of squeeze-cast Mg-Zn-Ca-Mn alloys for biomedical applications[J].Acta Biomaterialia,2022,150:442-455.
- [4] Wu C L,Xie W J,Ma H C.Laser additive manufacturing of biodegradable Mg-based alloys for biomedical applications:A review[J].Journal of Magnesium and Alloys,2022,10(4):915-937.
- [5] Putra N E,Mirzaali M J,Apachitei I,et al.Multi-material additive manufacturing technologies for Ti-,Mg-,and Fe-based biomaterials for bone substitution[J].Acta Biomaterialia,2020,109:1-20.
- [6] 刘天翼,谭丽丽,赵红阳,等.轧制及热处理对医用Mg-2Zn-0.5Nd-0.5Zr合金板材力学性能和耐蚀性能的影响[J].材料热处理学报,2021,42(11):28-36.LIU Tian-yi,TAN Li-li,ZHAO Hong-yang,et al.Effect of rolling and heat treatment on mechanical properties and corrosion resistance ofbiomedical Mg-2Zn-0.5Nd-0.5Zr alloy sheet[J].Transactions of Materials and Heat Treatment,2021,42(11):28-36.
- [7] Li G,Shen E,Liang L,et al.Microstructure and corrosion resistance of powder metallurgical Ti-Nb-Zr-Mg alloys with low modulus for biomedical application[J].Materials Characterization,2022,192:112223.
- [8] 孙文君,张金玲,于彦冲,等.T4和T6热处理对Mg-2.5Zn-1.5Ca-0.22Zr合金组织和硬度的影响[J].材料热处理学报,2020,41(2):23-29.SUN Wen-jun,ZHANG Jin-ling,YU Yan-chong,etal.Effect of T4 and T6 treatment on microstructure and microhardness of Mg-2.5Zn-1.5Ca-0.22Zr alloy[J].Transactions of Materials and Heat Treatment,2020,41(2):23-29.
- [9] Zheng Y F,Gu X N,Witte F.Biodegradable metals[J].Materials Science and Engineering R,2014,77(2):1-34.
- [10] 姜婷,郭学锋,马光,等.时效处理对变形镁合金伸长率的影响[J].钛工业进展,2008,25(6):28-30.JIANG Ting,GUO Xue-feng,MA Guang,et al.Aging effect on elongation of wrought magnesium alloys[J].Titanium Industry Progress,2008,25(6):28-30.
- [11] 王耀贵,李全安,张清,等.Mg-Zn-Zr合金的热处理工艺优化[J].特种铸造及有色合金,2012,32(9):856-858.WANG Yao-gui,LI Quan-an,ZHANG Qing,et al.Processing optimization of heat treatment Mg-Zn-Zr magnesium alloy[J].Special Casting and Nonferrous Alloys,2012,32(9):856-858.
- [12] Yan B,Dong X,Ma R,et al.Effects of heat treatment on microstructure,mechanical properties and damping capacity of Mg-Zn-Y-Zr alloy[J].Materials Science and Engineering A,2014,594:168-177.
- [13] 焦迪,王萍.热处理工艺对Mg-Gd-Y合金组织及耐腐蚀性能的影响[J].材料热处理学报,2020,41(9):59-66.JIAO Di,WANG Ping.Effect of heat treatment process on microstructure and corrosion resistance of Mg-Gd-Y alloy[J].Transactions of Materials and Heat Treatment,2020,41(9):59-66.
- [14] Wang S D,Xu D K,Chen X B,et al.Effect of heat treatment on the corrosion resistance and mechanical properties of an as-forged Mg-Zn-Y-Zr alloy[J].Corrosion Science,2015,92:228-236.
- [15] Jiang B,Xiang Q,Atrens A,et al.Influence of crystallographic texture and grain size on the corrosion behaviour of as-extruded Mg alloy AZ31 sheets[J].Corrosion Science,2017,126:374-380.
- [16] Atrens A,Song G L,Cao F,et al.Advances in Mg corrosion and research suggestions[J].Journal of Magnesium and Alloys,2013,1:177-200.
- [17] Abidin N,Rolfe B,Owen H,et al.The in vivo and in vitro corrosion of high-purity magnesium and magnesium alloys WZ21 and AZ91[J].Corrosion Science,2013,75:354-366.
- [18] Cao F,Shi Z,Hofstetter J,et al.Corrosion of ultra-high-purity Mg in 3.5% NaCl solution saturated with Mg(OH)2[J].Corrosion Science,2013,75:78-99.
- [19] Cooper L F,Zhou Y,Takebe J,et al.Fluoride modification effects on osteoblast behavior and bone formation at TiO2 grit-blasted c.p.titanium endosseous implants[J].Biomaterials,2006,27(6):926-936.
- [20] Luo S Q,Tang A T,Pan F S,et al.Effect of mole ratio of Y to Zn on phase constituent of Mg-Zn-Zr-Y alloys[J].Transactions of Nonferrous Metals Society of China,2011,21(4):795-800.
- [21] Huang Z H,Liang S M,Chen R S,et al.Solidification pathways and constituent phases of Mg-Zn-Y-Zr alloys[J].Journal of Alloys and Compounds,2009,468(1/2):170-178.
- [22] 叶新羽.生物可降解骨固定用Mg-Zn-Zr合金研究[D].天津:天津理工大学,2010.YE Xin-yu.The study on the biodegradable Mg-Zn-Zr alloys used for bone fixation[D].Tianjin:Tianjin University of Technology,2010.
- [23] Bakhsheshi-Rad H R,Abdul-Kadir M R,Farahany S,et al.Relationship between the corrosion behavior and the thermal characteristics and microstructure of Mg-0.5Ca-xZn alloys[J].Corrosion Science,2012,64(6):184-197.
- [24] 宋光铃.镁合金腐蚀与防护[M].北京:化学工业出版社,2006.SONG Guang-ling.Corrosion and Protection of Magnesium Alloys[M].Beijing:Chemical Industry Press,2006.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||