医用镁合金等离子喷涂羟基磷灰石涂层研究Study on plasma sprayed hydroxyapatite coating on magnesium alloy
高亚丽,熊党生
摘要(Abstract):
为了提高医用镁合金的表面耐蚀性和生物相容性,采用等离子喷涂技术在镁合金表面制备羟基磷灰石(HA)涂层。研究结果表明,镁合金表面所制备的HA涂层与基体结合牢固,界面无裂纹、气孔等缺陷。相组成为生物相容性较好的HA和少量的Ca3(PO4)2(TCP),显微组织具有层状特征,涂层表面存在一些有利于骨长入的孔隙。涂层的弹性模量约为19.825 GPa,接近骨的弹性模量,涂层表面硬度为300~350 HV。腐蚀试验和钙磷沉积试验结果表明HA涂层具有较好的耐蚀性和骨诱导性。
关键词(KeyWords): 镁合金;等离子喷涂;羟基磷灰石;耐蚀性;生物相容性
基金项目(Foundation): 中国博士后科学基金资助项目(20070421011);; 江苏省博士后科学基金资助项目(0702029B)
作者(Author): 高亚丽,熊党生
DOI: 10.13289/j.issn.1009-6264.2011.01.021
参考文献(References):
- [1]李世普.生物医用材料导论[M].武汉工业大学出版社,2005.
- [2]郭学峰,魏建峰,张忠明.镁合金与超高强度镁合金[J].铸造技术,2002,23:133-136.GUO Xue-feng,WEI Jian-feng,ZHANG Zhong-ming.Review on magnesium alloys and super-high strength magnesium alloys[J].FoundryTechnology,2002,23:133-136.
- [3]郭磊,刘魁,张世亮,等.CA-P/AZ31B镁合金的生物相溶性研究[J].稀有金属材料与工程,2009,38(1):99-103.GUO Lei,LIU Kui,ZHANG liang,et al.Biocompatibility of CA-P/AZ31B magnesium alloy[J].Rare Metal Materials and Engineering,2009,38(1):99-103.
- [4]Heublein B.,Rohde R,Kaese V et al.Biocorrosion of magnesium alloys:a new principle in cardiovascular implant technology[J].Heart,2003,89:651-656.
- [5]肖秀兰,陈志刚.羟基磷灰石涂层制备技术的可行性研究[J].材料导报,2003,17(4):32-34.XIAO Xiu-lan,CHEN Zhi-gang.Study of commercialization of hydroxyapatite coating material[J].Materials Review,2003,17(4):32-34.
- [6]吕宇鹏,陈艳梅,朱瑞富,等.等离子喷涂羟基磷灰石涂层的相组成及其结构[J].材料科学与工艺,2007,15(4):492-499.LU Yu-peng,CHEN Yan-mei,ZHU Run-fu,et al.Phase composition and microstructure of plasma sprayed hydroxyapatite coating[J].MaterialsScience and Technology,2007,15(4):492-499.
- [7]赵秋颖,贺定勇,李晓延,等.微束等离子喷涂制备羟基磷灰石涂层[J].焊接学报,2008,29(3):137-140.ZHAO Qiu-ying,HE Ding-yong,LI Xiao-yan,et al.Microplasma arc sprayed hydroxyapatite coatings[J].Transactions of the China WeldingInstitution,2008,29(3):137-140.
- [8]贺定勇,孙旭峰,栗卓新,等.等离子喷涂羟基磷灰石涂层结晶度的分析[J].北京工业大学学报,2006,32(12):1130-1133.HE Ding-yong,SUN Xu-feng,LI Zhuo-xin,et al.Crystallinity analysis of plasma sprayed HA coating[J].Journal of Beijing University of Technology.2006,32(12):1130-1133.
- [9]Legeros R Z.Biodegradation and bioresorption of calciumphosphate ceramics[J].Clin Mater,1993,14:65-88.
- [10]Legeros R Z,Legeros J P.Kim Y et al.Calcium phosphates in plasma-sprayed HA coatings[J].Ceram Trans,1995,48:173-189.
- [11]郑扣松.HA生物活性梯度涂层的制备和性能研究[D].硕士.华中科技大学,2006,34-35.
- [12]Mcpherson R.The relationship between the mechanism of formation,microstructure and properties of plasma-sprayed coatings[J].Thin Solid Films,1981,83:297-310.
- [13]Ohmori A,Li C J.Thermal Spaying-Theory and Applications[M].London:World Scientific Publishing Co,1993:179-200.
- [14]Safai S,Herman H.Microstructural investigation of plasma-sprayed aluminum coatings[J].Thin Solid Films,1977,45:295-307.
- [15]刘其斌.宽带激光熔覆梯度生物陶瓷复合涂层及其生物相容性[D].大连:大连理工大学,2005.
- [16]ZHANG Qi-yi,CHEN Ji-yong,FENG Jia-ming.Dissolution and mineralization behaviors of HA coatings[J].Biomaterials,2003,24:4741-4748.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||