Al、Zn元素添加对Mg-Cu合金微观组织和力学性能的影响Effect of Al and Zn element addition on microstructure and mechanical properties of Mg-Cu alloy
贾澳,魏珂正,徐媛媛,黄卓,王子健,丁汉林,项重辰
摘要(Abstract):
采用扫描电镜、能谱仪、X射线衍射仪、硬度试验和拉伸试验等研究了Al、Zn元素单独或同时添加对Mg-Cu合金微观组织和力学性能的影响。结果表明:与铸态相比,T6处理后3种合金的力学性能都有明显地提高;其中Mg-1Cu-1Zn合金的力学性能提升得最多,其热处理后的屈服强度为176.6 MPa、抗拉强度为267.9 MPa、伸长率为14.1%,比铸态分别提高了58.1%、41.6%和40.7%。仅添加Zn元素的Mg-1Cu-1Zn合金,T6处理后晶界上的大部分第二相已成功固溶进基体中,并在晶粒内生成了圆球状析出相,经分析确认这两种相为MgZnCu和Mg(Zn, Cu)_2;合金力学性能提高的原因是固溶强化和时效强化等多种因素的综合作用。
关键词(KeyWords): Mg-Cu合金;热处理;力学性能
基金项目(Foundation):
作者(Author): 贾澳,魏珂正,徐媛媛,黄卓,王子健,丁汉林,项重辰
DOI: 10.13289/j.issn.1009-6264.2023-0503
参考文献(References):
- [1] 胡长平.推动有色工业迈入新发展阶段——《“十四五”原材料工业发展规划》(有色金属部分)解读[J].中国有色金属,2022(3):33-35.HU Chang-ping.Promote the non-ferrous industry into a new stage of development — “14th Five-Year Plan” raw materials industry development plan (non-ferrous metal part) interpretation[J].China Nonferrous Metals,2022(3):33-35.
- [2] 孙宝德,疏达,付华栋,等.高端新材料智能制造的发展机遇与方向[J].中国工程科学,2023,25(3):152-160.SUN Bao-de,SHU Da,FU Hua-dong,et al.Development opportunities and directions for intelligent manufacturing of high-end new materials[J].Strategic Study of CAE,2023,25(3):152-160.
- [3] Pan F S,Yang M B,Chen X H.A review on casting magnesium alloys:Modification of commercial alloys and development of new alloys[J].Journal of Materials Science and Technology,2016,32(12):1211-1221.
- [4] Trang T T T,Zhang J H,Kim J H,et al.Designing a magnesium alloy with high strength and high formability[J].Nature Communications,2018,9(1):2522.
- [5] Joost W J,Krajewski P E.Towards magnesium alloys for high-volume automotive applications[J].Scripta Materialia,2017,128:107-112.
- [6] 曾小勤,朱庆春,李扬欣,等.镁合金中的第二相颗粒强化[J].中国材料进展,2019,38(3):193-204.ZENG Xiao-qin,ZHU Qing-chun,LI Yang-xin,et al.Second-phase particle strengthening in magnesium alloys[J].Materials China,2019,38(3):193-204.
- [7] 王征远,秦守益,王先飞,等.热处理对WE43镁合金显微组织和力学性能的影响[J].特种铸造及有色合金,2021,41(3):364-367.WANG Zheng-yuan,QIN Shou-yi,WANG Xian-fei,et al.Effect of heat treatment on microstructure and mechanical properties of WE43 magnesium alloy[J].Special Casting & Nonferrous Alloys,2021,41(3):364-367.
- [8] 刘楚明,朱秀荣,周海涛.镁合金相图集[M].长沙:中南大学出版社,2006.LIU Chu-ming,ZHU Xiu-rong,ZHOU Hai-tao.Magnesium Alloy Phase Atlas[M].Changsha:Central South University Press,2006.
- [9] 兴春梅.Mg-Zn-Cu合金的变形与热处理研究[D].沈阳:沈阳理工大学,2009.XING Chun-mei.Study on deformation and heat treatment of Mg-Zn-Cu alloys[D].Shenyang:Shenyang Ligong University,2009.
- [10] Bao J X,Li L H,Sha J C,et al.Effects of trace amounts of Sn,Ca,and Cu on the electrochemical properties and discharge performance of Mg-2Zn-1Gd-0.5Zr as an anode for Mg-air battery[J].Electrochimica Acta,2023,465:143014.
- [11] Zhang Z Y,Peng L M,Zeng X Q,et al.Effects of Cu and Mn on mechanical properties and damping capacity of Mg-Cu-Mn alloy[J].Transactions of Nonferrous Metals Society of China,2008,18(S1):55-58.
- [12] 伍华怡.Cu元素对AZ80镁合金组织和性能的影响[D].重庆:重庆大学,2019.WU Hua-yi.Effect of Cu element on the organization and properties of AZ80 magnesium alloy[D].Chongqing:Chongqing University,2019.
- [13] Luo A,Pekguleryuz M O.Cast magnesium alloys for elevated temperature applications[J].Journal of Materials Science,1994,29(20):5259-5271.
- [14] Zhang J,Peng P,Yang Q,et al.Bimodal grain structure formation and strengthening mechanisms in Mg-Mn-Al-Ca extrusion alloys[J].Journal of Magnesium and Alloys,2023,11(12):4407-4419.
- [15] Cihova M,Sch?ublin R,Hauser L B,et al.Rational design of a lean magnesium-based alloy with high age-hardening response[J].Acta Materialia,2018,158(5):214-229.
- [16] Zhao J,Jiang B,Yuan Y,et al.Influence of Ca and Zn synergistic alloying on the microstructure,tensile properties and strain hardening of Mg-1Gd alloy[J].Materials Science and Engineering A,2020,785(15):139344.
- [17] Xiang C,Huang Z,Wang Z,et al.Effect of Cu addition on the microstructure,mechanical properties and thermal properties of Mg-Al-Ca-Mn alloy[J].Materials Characterization,2023,202(1):113028.
- [18] Li Z T,Zhang X D,Zheng M Y,et al.Effect of Ca/Al ratio on microstructure and mechanical properties of Mg-Al-Ca-Mn alloys[J].Materials Science and Engineering A,2017,682:423-432.
- [19] 朱小成.复合合金化对Mg-Al-Ca-Mn合金显微组织和力学性能影响的研究[D].马鞍山:安徽工业大学,2019.ZHU Xiao-cheng.Study on the effect of composite alloying on microstructure and mechanical properties of Mg-Al-Ca-Mn alloys[D].Ma’anshan:Anhui University of Technology,2019.
- [20] Zhu S Z,Luo T J,Zhang T A,et al.Effects of Cu addition on the microstructure and mechanical properties of as-cast and heat treated Mg-6Zn-4Al magnesium alloy[J].Materials Science and Engineering A,2017,689:203-211.
- [21] Dehghanian C,Lotfpour M,Emamy M.The microstructure,and mechanical and corrosion properties of as-cast and as-extruded Mg-2%Zn-x%Cu alloys after solution and aging heat treatments[J].Journal of Materials Engineering and Performance,2019,28(4):2305-2315.
- [22] 张玉,李明,杨文龙,等.热处理工艺对Mg-6Zn-2.5Cu镁合金显微组织和力学性能的影响[J].材料热处理学报,2020,41(4):40-46.ZHANG Yu,LI Ming,YANG Wen-long,et al.Effect of heat treatment process on microstructure and mechanical properties of Mg-6Zn-2.5Cu magnesium alloy[J].Transactions of Materials and Heat Treatment,2020,41(4):40-46.
- [23] Pan H C,Pan F S,Wang X,et al.High conductivity and high strength Mg-Zn-Cu alloy[J].Materials Science and Technology,2014,30(7):759-764.
- [24] Golmakaniyoon S,Mahmudi R.Comparison of the effects of La-and Ce-rich rare earth additions on the microstructure,creep resistance,and high-temperature mechanical properties of Mg-6Zn-3Cu cast alloy[J].Materials Science and Engineering A,2011,528(15):5228-5233.
- [25] Tan W,Li T,Li S,et al.High strength-ductility and rapid degradation rate of as-cast Mg-Cu-Al alloys for application in fracturing balls[J].Journal of Materials Science and Technology,2021,94(35):22-31.
- [26] Zhu H,Sha G,Liu J,et al.Microstructure and mechanical properties of Mg-6Zn-xCu-0.6Zr (wt.%) alloys[J].Journal of Alloys and Compounds,2011,509(8):3526-3531.
- [27] 刘军,王晓婉,汪伟,等.铜含量对Mg-Al-Zn-Cu可溶镁合金溶解性能的影响[J].轻金属,2020(11):48-51.LIU Jun,WANG Xiao-wan,WANG Wei,et al.Effect of copper content on the dissolution properties of Mg-Al-Zn-Cu soluble magnesium alloys[J].Light Metals,2020(11):48-51.
- [28] 李旭娇.热处理对Mg-8Zn-1Cu-xAl 镁合金微观组织的影响[D].兰州:兰州理工大学,2021.LI Xu-jiao.Effect of heat treatment on the microstructure of Mg-8Zn-1Cu-xAl magnesium alloys[D].Lanzhou:Lanzhou University of Technology,2021.
- [29] 袁光宇.Cu、Zn对Mg微观组织和性能的影响[D].重庆:重庆大学,2018.YUAN Guang-yu.The influence of Cu and Zn on the microstructure and properties of Mg[D].Chongqing:ChongqingUniversity,2018.
- [30] 刘楚明.铝合金相图集[M].长沙:中南大学出版社,2014.LIU Chu-ming.Aluminum Phase Gallery[M].Changsha:Central South University Press,2014.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||