CrCoNi与(CrCoNi)96Cu4中熵合金在H2SO4溶液中的腐蚀行为Corrosion behavior of CrCoNi and (CrCoNi)96Cu4 medium entropy alloys in H2SO4 solution
陈今良
摘要(Abstract):
采用真空电弧熔炼制备了CrCoNi与(CrCoNi)_(96)Cu_4中熵合金,首先对合金进行了变形量为67%的轧制变形,随后在800℃下进行退火30 min的处理,比较退火态CrCoNi与(CrCoNi)_(96)Cu_4中熵合金在0.5 mol/L H_2SO_4溶液中的腐蚀行为。通过X射线衍射(XRD)、扫描电镜(SEM)、原子力显微镜(AFM)对合金的相结构及腐蚀后的微观组织进行表征,利用动电位极化曲线与交流阻抗(EIS)对合金在0.5 mol/L H_2SO_4溶液中的腐蚀性能进行测试。结果表明:在0.5 mol/L H_2SO_4溶液中,(CrCoNi)_(96)Cu_4合金的自腐蚀电流密度与腐蚀速率均小于CrCoNi合金;EIS数据表明(CrCoNi)_(96)Cu_4合金的钝化膜电阻大于CrCoNi合金的钝化膜电阻,即(CrCoNi)_(96)Cu_4合金比CrCoNi合金具有更为优异的耐腐蚀性能。
关键词(KeyWords): 中熵合金;耐腐蚀性;钝化膜;极化曲线;交流阻抗
基金项目(Foundation): 钒钛资源综合利用四川省重点实验室项目(2021FTSZ13);; 攀枝花市科技项目(2022ZD-G-14)
作者(Author): 陈今良
DOI: 10.13289/j.issn.1009-6264.2024-0342
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