高温时效对低活化钢微观组织及力学性能的影响Effect of high temperature aging on microstructure and mechanical properties of reduced activation steel
邱国兴,张红钊,杨永坤,李小明,彭雷朕,曹磊
摘要(Abstract):
采用光学显微镜、扫描电镜(SEM)、透射电镜(TEM)和力学性能测试等研究了经中间热处理的含钇和钛的低活化钢在550℃时效500、1250、2500、4000和5000 h后的组织和性能变化规律,并分析了微观组织变化对力学性能的影响。结果表明:时效过程中实验钢的组织保持为稳定的马氏体,晶粒发生粗化,M_(23)C_6和MX相的长大速率、屈服强度、抗拉强度和冲击性能逐渐降低并趋于稳定。时效时间增加至4000 h后,Laves相的粗化速度有所降低。当时效时间达到5000 h时,实验钢的晶粒尺寸为9.1μm, M_(23)C_6的长大速率为0.0072 nm/h, MX的长大速率为0.0004 nm/h,实验钢的室温屈服强度和抗拉强度分别为632和755 MPa,室温冲击吸收能量为307 J,韧脆转变温度为-64℃,实验钢在650℃时屈服强度和抗拉强度分别为313和337 MPa。晶粒粗化是实验钢冲击韧性降低的主要原因。
关键词(KeyWords): 低活化钢;高温时效;Laves相;M_(23)C_6;MX;力学性能
基金项目(Foundation): 河北省自然基金(E2021417001);; 中国博士后科学基金(2022M720982);; 陕西省自然基金(2021JQ-502)
作者(Author): 邱国兴,张红钊,杨永坤,李小明,彭雷朕,曹磊
DOI: 10.13289/j.issn.1009-6264.2023-0028
参考文献(References):
- [1] Qiu G X,Zhan D P,Cao L,et al.Review on development of reduced activated ferritic/martensitic steel for fusion reactor[J].Journal of Iron and Steel Research International,2022,29(9):1343-1356.
- [2] Blomm E E,Conn R W,Davis J W,et al.Low activation materials for fusion applications[J].Journal of Nuclear Materials,1984,122(1/3):17-26.
- [3] 邱国兴,白冲,蔡明冲,等.RAFM钢应变补偿本构关系及热加工图[J].钢铁,2022,57(11):157-166.QIU Guo-xing,BAI Chong,CAI Ming-chong,et al.Strain compensation constitutive equation and hot processing map of RAFM steel[J].Iron and Steel,2022,57(11):157-166.
- [4] 李靖,金鹏,崔明焕,等.高He通量注入条件下F/M和ODS钢中纳米微结构对He泡形核和长大的影响(英文)[J].原子核物理评论,2022,39(1):101-107.LI Jing,JIN Peng,CUI Ming-huan,et al.Effect of nanostructure on nucleation and growth of He bubbles in F/M and ODS steels under high He flux Injection[J].Nuclear Physics Review,2022,39(1):101-107.
- [5] 王宝安.氧化物弥散强化低碳钢的组织与力学性能[D].秦皇岛:燕山大学,2017.WANG Bao-an.Microstructure and mechanical properties of oxide dispersion strengthened low carbon steels[D].Qinhuangdao:Yanshan University,2017.
- [6] 张家榕,李艳芬,芮祥,等.粉末热锻制备9Cr-ODS钢的微观组织和力学性能研究[J].钢铁研究学报,2021,33(11):1171-1178.ZHANG Jia-rong,LI Yan-fen,RUI Xiang,et al.Study on microstructure and mechanical properties of 9Cr-ODS steel prepared by a powder hot forging process[J].Journal of Iron and Steel Research,2021,33(11):1171-1178.
- [7] 单以银,严伟,杨柯.钇对9Cr-2WVTa低活化马氏体钢力学性能的影响[C]//2007中国钢铁年会论文集,中国四川成都:冶金工业出版社,2007:901-902.SHAN Yi-yin,YAN Wei,YANG Ke,et al.Effect of yttrium on mechanical properties of 9Cr-2WVTa low active martensite steel[C]//Proceedings of 2007 China Steel Annual Conference,Chengdu:Metallurgical Industry Press,2007:901-902.
- [8] Zhan D P,Qiu G X,Li C S,et al.Effects of Ti addition on the microstructure and tensile properties of China low activation martensitic steel for nuclear fusion reactors[J].Steel Research International,2019,90(9):1-8.
- [9] Qiu G X,Zhan D P,Li C S,et al.Effects of Y and Ti addition on microstructure stability and tensile properties of reduced activation ferritic/martensitic steel[J].Nuclear Engineering and Technology,2019,51(5):1365-1372.
- [10] Qiu G X,Zhan D P,Li C S,et al.Development of nano-structure China low activation martensitic steel for fusion reactors[J].Materials Letters,2019,252(1):248-251.
- [11] Wang W,Liu S J,Xu G,et al.Effect of thermal aging on microstructure and mechanical properties of China low-activation martensitic steel at 550 ℃[J].Nuclear Engineering and Technology,2016,48(2):518-524.
- [12] Wang W,Chen J W,Xu G.Effect of thermal aging on grain structural characteristic and ductile-to-brittle transition temperature of CLAM steel at 550 ℃[J].Fusion Engineering and Design,2016,115:74-79.
- [13] Kim H K,Lee J W,Moon J,et al.Effects of Ti and Ta addition on microstructure stability and tensile properties of reduced activation ferritic/martensitic steel for nuclear fusion reactors[J].Journal of Nuclear Materials,2018,500:327-336.
- [14] Xia Z X,Zhang C,Yang Z G.Control of precipitation behavior in reduced activation steels by intermediate heat treatment[J].Materials Science and Engineering A,2011,528(22/23):6764-6768.
- [15] Li Y F,Hiroaki A,Li F,et al.Grain structural characterization of 9Cr-ODS steel aged at 973 K up to 10,000 h by electron backscatter diffraction[J].Journal of Nuclear Materials,2014,455(1/3):568-572.
- [16] Dimmler G,Weinert P,Kozeschnik E,et al.Quantification of the laves phase in advanced 9~12% Cr steels using a standard SEM[J].Materials Characterization,2004,51(5):341-352.
- [17] 张思雨,王凯,闫超杰,等.强磁场下第二相颗粒Ostwald熟化行为[J].铸造技术,2022,43(9):780-791.ZHANG Si-yu,WANG Kai,YAN Chao-jie,et al.Ostwald ripening behavior of second-phase particles under high magnetic field[J].Foundry Technology,2022,43(9):780-791.
- [18] 王学,于淑敏,任遥遥,等.P92钢时效的Laves相演化行为[J].金属学报,2014,50(10):1195-1202.WANG Xue,YU Shu-min,REN Yao-yao,et al.Laves phase evolution in P92 steel during ageing[J].Acta Metallurgica Sinica,2014,50(10):1195-1202.
- [19] Liu S J,Huang Q Y,Li C J,et al.Influence of non-metal inclusions on mechanical properties of CLAM steel[J].Fusion Engineering and Design,2008,84(7):1214-1218.
- [20] 王伟.中国低活化马氏体钢高温热时效行为与力学性能退化机理研究[D].合肥:中国科学技术大学,2017.WANG Wei.Thermal aging behavior and degradation mechanism of China low activation martensitic steel[D].Hefei:University of Science and Technology of China,2017.
- [21] Zhao M C,Zeng T Y,Li J L,et al.Identification of the effective grain size responsible for the ductile to brittle transition temperature for steel with an ultrafine grain size ferrite/cementite microstructure with a bimodal ferrite grain size distribution[J].Materials Science and Engineering A,2011,528(12):4217-4221.
- [22] Zhan D P,Qiu G X,Li C S,et al.Evolution of microstructures and mechanical properties of Zr-containing Y-clam during thermal aging[J].Acta Metallurgica Sinica (English Letters),2020,33(6):881-891.
- [23] 钟群鹏,赵子华.断口学[M].北京:高等教育出版社,2006.
- [24] 张俊善.材料的高温变形与断裂[M].北京:科学出版社,2006.
- [25] Qiu G X,Du Q,Li X M,et al.Strengthening effect of multiscale second phases in reduced activation ferrite/martensitic steel[J].Steel Research International,2021,93(4):2100430.
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