热处理对低铜含量再生黄铜合金性能的影响Effect of heat treatment on properties of low-copper content recycled brass alloy
刘伟,胡丹丹,王法超,黄腾,沈守稳,马帅,柴胜利
摘要(Abstract):
近年来铜价持续飙升,为降低黄铜合金的生产成本,低铜含量黄铜产品的市场需求呈现出蓬勃增长的态势。采用废杂铜直接利用法生产了Cu50-52Zn48-50黄铜合金棒线材,即通过废杂铜原料成分设计→合金熔铸→挤压→热处理→加工成型的工艺路线,得到了质量稳定合格的低铜含量合金棒线材。结果表明:在热处理温度为450~600℃范围内,随着温度的升高和保温时间的延长,合金的抗拉强度和伸长率均显著提高,同时发生再结晶软化及时效强化;挤压坯在550℃保温4 h后,可制造出抗拉强度≥650 MPa、伸长率≥3%、直线度≤0.5 mm/m的高精密棒线材;在低铜含量合金棒线材的生产过程中,通过发挥热处理作用改善材料加工性能,开发出了一条质量稳定的工艺路线,降低了黄铜合金的使用成本。
关键词(KeyWords): 废杂铜;热处理;微观组织;抗拉强度
基金项目(Foundation):
作者(Author): 刘伟,胡丹丹,王法超,黄腾,沈守稳,马帅,柴胜利
DOI: 10.13289/j.issn.1009-6264.2024-0523
参考文献(References):
- [1] Tang J X,Yang H H,Chen H J,et al.Potential and future direction for copper resource exploration in China[J].Green and Smart Mining Engineering,2024,1(2):127-131.
- [2] 苏兴才,王浩.中国铜矿资源的现状及潜力分析[J].世界有色金属,2023(4):92-94.SU Xing-cai,WANG Hao.Analysis of the current situation and potential of copper resources in China[J].World Nonferrous Metals,2023(4):92-94.
- [3] 朱永光,张伍丰,王迪,等.中国铜资源产业链供应链韧性评价[J].资源科学,2023,45(9):1761-1777.ZHU Yong-guang,ZHANG Wu-feng,WANG Di,et al.Resilience evaluation of China’s copper resources industrial chain and supply chain[J].Resources Science,2023,45(9):1761-1777.
- [4] Wang J,Zheng S,Liu W,et al.Prediction,evaluation and optimization of China’s copper resource supply system under carbon constraints[J].Sustainable Production and Consumption,2023,39:285-300.
- [5] 成金华,帅竞,赵雨佳,等.关键矿产供应风险评估与预测—以铜资源为例[J].资源科学,2023,45(9):1778-1788.CHENG Jin-hua,SHUAI Jing,ZHAO Yu-jia,et al.Risk assessment and prediction of critical mineral resources supply for China[J].Resources Science,2023,45(9):1778-1788.
- [6] 王俊博.碳约束下中国铜资源供给系统的结构优化研究[D].成都:成都理工大学,2022.WANG Jun-bo.Research on structural optimization of China’s copper resource supply system under carbon constraints[D].Chengdu:Chengdu University of Technology,2022.
- [7] Yin J,Liu L,Ji H,et al.Sustain China’s copper resources with domestic mining,trading,and recycling[J].Resources,Conservation and Recycling,2024,202:107396.
- [8] 刘伟.废杂铜再生制备高品质黄铜合金基础研究[D].北京:北京科技大学,2023.LIU Wei.Basic research and application of high-quality brass alloy by recycling scrap copper[D].Beijing:University of Science and Technology Beijing,2023.
- [9] 黄敏,邵龙彬.再生铜资源的利用状况与发展趋势[J].有色冶金设计与研究,2021,42(1):7-9.HUANG Min,SHAO Long-bin.Utilization status and development trend of reclaimed copper resources[J].Non-ferrous Metallurgical Design and Research,2021,42(1):7-9.
- [10] 娄永刚,张楠,段绍甫.中国铜工业转型升级的方向[J].中国有色金属,2015(9):44-45.LOU Yong-gang,ZHANG Nan,DUAN Shao-fu.The direction of transformation and upgrading of China’s copper industry[J].China Nonferrous Metals,2015(9):44-45.
- [11] Liu S,Zhang Y,Su Z,et al.Recycling the domestic copper scrap to address the China’s copper sustainability[J].Journal of Materials Research and Technology,2020,9(3):2846-2855.
- [12] 邱定蕃,王成彦,王春.中国废杂铜回收与利用[J].有色金属,2003,55(4):94-97.QIU Ding-fan,WANG Cheng-yan,WANG Chun.Recycling of scrap copper in China[J].Nonferrous Metals,2003,55(4):94-97.
- [13] 王冲,杨坤彬,华宏全.废杂铜回收利用工艺技术现状及展望[J].再生资源与循环经济,2011,4(8):28-32.WANG Chong,YANG Kun-bin,HUA Hong-quan.Current status and prospect of recovery and utilization process for copper scrap[J].Renewable Resources and Circular Economy,2011,4(8):28-32.
- [14] 魏绪钧,徐秀芝,冯法伦,等.稀土在铅黄铜合金中的应用[J].稀有金属与硬质合金,1992(2):5-10.WEI Xu-jun,XU Xiu-zhi,FENG Fa-lun,et al.Application of rare earth in lead brass alloys[J].Rare Metals and Cemented Carbides,1992(2):5-10.
- [15] 国占玲.黄铜的成分、性能及典型应用[J].黑龙江科技信息,2012(28):66.
- [16] 梅大安.低铜无铅硅黄铜的制备及组织性能研究[D].广州:华南理工大学,2012.MEI Da-an.Preparation,structure and properties of low-copper lead-free silicon brass[D].Guangzhou:South China University of Technology,2012.
- [17] 庞晋山.变质处理对低铜高锌黄铜冲击韧性的影响[J].铸造,2006,55(9):953-955.PANG Jin-shan.The influence of modification on impacted tenacity of low copper-high zinc brass[J].Casting,2006,55(9):953-955.
- [18] 李丹阳,刘平,张柯,等.热处理工艺对无铅硅黄铜组织及性能的影响[J].材料热处理学报,2017,38(4):71-77.LI Dan-yang,LIU Ping,ZHANG Ke,et al.Effect of heat treatment on microstructure and properties of lead-free silicon brass[J].Transactions of Materials and Heat Treatment,2017,38(4):71-77.
- [19] 罗飞翔,段振虎,伍伟玉.热处理工艺对高锰钢组织和硬度的影响[J].铜业工程,2023(6):117-122.LUO Fei-xiang,DUAN Zhen-hu,WU Wei-yu.Effect of heat treatment process on microstructure and hardness of high manganese steel[J].Copper Engineering,2023(6):117-122.
- [20] 孙慧,董晟全,梁艳峰,等.热处理工艺对无铅黄铜腐蚀行为的影响[J].热加工工艺,2012,41(4):153-155.SUN Hui,DONG Sheng-quan,LIANG Yan-feng,et al.Effect of heat treatment on corrosion behavior of lead-free brass[J].Hot Working Technology,2012,41(4):153-155.
- [21] 赵作福,齐锦刚,王家毅,等.电脉冲处理HSi59-2.5硅黄铜热处理后的相组成[J].金属热处理,2014,39(12):126-130.ZHAO Zuo-fu,QI Jin-gang,WANG Jia-yi,et al.Phase composition of electric pulse treated HSi59-2.5 silicon brass after heat treatment[J].Heat Treatment of Metals,2014,39(12):126-130.
- [22] 刘志学,党龙,程巨强.热处理对锻造铅黄铜组织和性能的影响[J].西安工业大学学报,2013,33(10):832-835.LIU Zhi-xue,DANG Long,CHENG Ju-qiang.Influence of heat treatment on microstructure and properties of forging lead brass alloy[J].Journal of Xi’an University of Technology,2013,33(10):832-835.
- [23] 胡垚,程巨强,刘志学.变质处理及热处理对铸造黄铜组织和性能的影响[J].热加工工艺,2008,37(5):29-31.HU Yao,CHENG Ju-qiang,LIU Zhi-xue.Influence of modification and heat treatment on properties and microstructure of casting lead brass[J].Hot Working Technology,2008,37(5):29-31.
- [24] 冯卫,黄绍辉,刘钦雷,等.热处理对CW713R特殊黄铜组织及性能的影响[J].有色金属材料与工程,2016,37(5):219-222.FENG Wei,HUANG Shao-hui,LIU Qin-lei,et al.Effect of heat treatment on the microstructure and properties of CW713R special brass[J].Nonferrous Metal Materials and Engineering,2016,37(5):219-222.
- [25] 王雪松,周兵,戴姣燕,等.Al含量对等值锌当量耐磨黄铜组织及性能的影响[J].材料导报,2021,35(20):20124-20128.WANG Xue-song,ZHOU Bing,DAI Jiao-yan,et al.Effect of Al content on microstructure and properties of equal value zinc equivalent wear-resistant brass[J].Material Reports,2021,35(20):20124-20128.
- [26] 高来弟,张勇,刘新才,等.废杂铜再生铜材的显微组织和性能研究[J].热加工工艺,2015,44(17):36-39.GAO Lai-di,ZHANG Yong,LIU Xin-cai,et al.Research on microstructures and properties of copper from regenerated scraps[J].Hot Working Technology,2015,44 (17):36-39.
- [27] 李航.复杂锰黄铜中[Mn(Fe)]5Si3相形成长大机制及其对性能影响研究[D].大连:大连理工大学,2018.LI Hang.Formation and growth mechanisms of [Mn(Fe)]5Si3 phase and its influence on properties in complex manganese brasses[D].Dalian:Dalian University of Technology,2018.
- [28] 王法超,胡丹丹,沈守稳,等.Cu54-56Zn40-44再生铜合金棒材成形工艺及性能研究[J].精密成形工程,2024,16(9):102-111.WANG Fa-chao,HU Dan-dan,SHEN Shou-wen,et al.Research on the forming process and properties of Cu54-56Zn40-44 regenerated copper alloy rods[J].Journal of Netshape Forming Engineering,2024,16(9):102-111.
- [29] 蔡薇,齐亮,谢水生,等.挤压态H65黄铜的晶粒细化与性能关系研究[J].热加工工艺,2008,37(7):7-9.CAI Wei,QI Liang,XIE Shui-sheng,et al.Effects of grains refinement on characteristics of extruded H65 brass[J].Hot Working Technology,2008,37(7):7-9.
- [30] 陈嘉会.热挤压铝黄铜显微组织研究[D].宁波:宁波大学,2014.CHEN Jia-hui.Microstructure and mechanical properties analysis of aluminum brass produced by hot-working[D].Ningbo:Ningbo University,2014.
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