均匀化热处理及冷轧退火对Mg-9Li-2Al-1Y合金组织与耐腐蚀性能的影响Effect of homogenizing heat treatment and cold rolling annealing on microstructure and corrosion resistance of Mg-9Li-2Al-1Y alloy
王思雨,徐维健,杨旭,王斌,王丙兴
摘要(Abstract):
为了改善镁锂合金的耐蚀性,采用均匀化热处理+冷轧退火的工艺对其进行处理,利用扫描电镜和电化学试验研究了不同工艺处理后Mg-9Li-2Al-1Y合金的微观组织和耐蚀性能。结果表明:冷轧退火态Mg-9Li-2Al-1Y合金中的α-Mg相更加细小且分布均匀,腐蚀方式由严重的局部腐蚀转变为均匀腐蚀,耐腐蚀性能明显提升。与铸态相比,冷轧退火态合金组织中高电位Al_2Y粒子沿轧制方向分布更加均匀,延缓了低电位α-Mg相的腐蚀进程。冷轧退火态的合金在3.5%的NaCl溶液中浸泡后产生了一层含Li_2CO_3的腐蚀产物层,提高了致密性,增强了腐蚀产物层对基体的保护作用。
关键词(KeyWords): 镁锂合金;耐腐蚀性能;均匀化热处理;冷轧退火处理
基金项目(Foundation):
作者(Author): 王思雨,徐维健,杨旭,王斌,王丙兴
DOI: 10.13289/j.issn.1009-6264.2021-0575
参考文献(References):
- [1] Shen G J,Duggan B J.Texture development in a cold-rolled and annealed body-centered-cubic Mg-Li alloy[J].Metallurgical and Materials Transactions A,2007,38(10):2593-2601.
- [2] 吴国华,赵炯,刘文才,等.超轻镁锂合金研究应用现状与展望[C]//第十三届全国铸造年会暨2016中国铸造活动周论文集,成都,2016:379-387.WU Guo-hua,ZHAO Jiong,LIU Wen-cai,et al.Situation and prospect of research and application on super light Mg-Li alloys[C]//The 13th National Foundry Annual Conference and 2016 China Foundry Activity Week Proceedings,Chengdu,2016:379-387.
- [3] Lin M C,Tsai C Y,Uan J Y.Electrochemical behaviour and corrosion performance of Mg-Li-Al-Zn anodes with high Al composition[J].Corrosion Science,2009,51(10):2463-2472.
- [4] Pan F,Yang M,Chen X.A review on casting magnesium alloys:modification of commercial alloys and development of new alloys[J].Journal of Materials Science and Technology,2016,32(12):1211-1221.
- [5] Xu T C,Peng X D,Jiang J W,et al.Microstructure and mechanical properties of superlight Mg-Li-Al-Zn wrought alloy[J].Rare Metal Materials and Engineering,2014,43(8):1815-1820.
- [6] Song Y,Shan D,Chen R,et al.Corrosion characterization of Mg-8Li alloy in NaCl solution[J].Corrosion Science,2009,51(5):1087-1094.
- [7] Zhou W R,Zheng Y F,Leeflang M A,et al.Mechanical property,biocorrosion and in vitro biocompatibility evaluations of Mg-Li-(Al)-(RE) alloys for future cardiovascular stent application[J].Acta Biomaterialia,2013,9(10):8488-8498.
- [8] Guo J,Chang L L,Zhao Y R,et al.Effect of Sn and Y addition on the microstructural evolution and mechanical properties of hot-extruded Mg-9Li-3Al alloy[J].Materials Characterization,2019,148:35-42.
- [9] Gu M,Wei G,Zhao J,et al.Influence of yttrium addition on the corrosion behaviour of as-cast Mg-8Li-3Al-2Zn alloy[J].Materials Science and Technology,2017,33(7):864-869.
- [10] Lv Y Z,Liu M,Xu Y,et al.The electrochemical behaviors of Mg-8Li-0.5 Y and Mg-8Li-1Y alloys in sodium chloride solution[J].Journal of Power Sources,2013,239:265-268.
- [11] Morishige T,Obata Y,Goto T,et al.Effect of Al composition on the corrosion resistance of Mg-14 mass% Li system alloy[J].Materials Transactions,2016,57(10):1853-1856.
- [12] Xiang Q,Jiang B,Zhang Y,et al.Effect of rolling-induced microstructure on corrosion behaviour of an as-extruded Mg-5Li-1Al alloy sheet[J].Corrosion Science,2017,119:14-22.
- [13] Nene S S,Kashyap B P,Prabhu N,et al.Microstructure refinement and its effect on specific strength and bio-corrosion resistance in ultralight Mg-4Li-1Ca (LC41) alloy by hot rolling[J].Journal of Alloys and Compounds,2014,615:501-506.
- [14] Wang G,Song D,Li C,et al.Developing improved mechanical property and corrosion resistance of Mg-9Li alloy via solid-solution treatment[J].Metals,2019,9(9):920.
- [15] Xu W,Birbilis N,Sha G,et al.A high-specific-strength and corrosion-resistant magnesium alloy[J].Nature Materials,2015,14(12):1229-1235.
- [16] Atrens A D,Gentle I,Atrens A.Possible dissolution pathways participating in the Mg corrosion reaction[J].Corrosion Science,2015,92:173-181.
- [17] Wang N,Wang R,Peng C,et al.Discharge behaviour of Mg-Al-Pb and Mg-Al-Pb-In alloys as anodes for Mg-air battery[J].Electrochimica Acta,2014,149:193-205.
- [18] Liu X,Xue J,Liu S.Discharge and corrosion behaviors of the α-Mg and β-Li based Mg alloys for Mg-air batteries at different current densities[J].Materials and Design,2018,160:138-146.
- [19] Yuan S,Lu H,Sun Z,et al.Electrochemical performance of Mg-3Al modified with Ga,In and Sn as anodes for Mg-air battery[J].Journal of the Electrochemical Society,2016,163(7):1181-1187.
- [20] Nakatsugawa I,Martin R,Knystautas E J.Improving corrosion resistance of AZ91D magnesium alloy by nitrogen ion implantation[J].Corrosion,1996,52(12):921-926.
- [21] 刘莉,冯艳,王日初,等.均匀化退火及挤压对Mg-Hg-Ga合金显微组织和耐腐蚀性能的影响[J].中国有色金属学报,2017,27(1):32-39.LIU Li,FENG Yan,WANG Ri-chu,et al.Effect of homogenizing annealing and extrusion on microstructure and corrosion resistance of Mg-Hg-Ga alloy[J].The Chinese Journal of Nonferrous Metals,2017,27(1):32-39.
- [22] Frankel G S,Sridhar N.Understanding localized corrosion[J].Materials Today,2008,11(10):38-44.
- [23] Sun Y,Wang R,Peng C,et al.Microstructure and corrosion behavior of as-homogenized Mg-xLi-3Al-2Zn-0.2 Zr alloys (x=5,8,11 wt%)[J].Materials Characterization,2020,159:110031-110039.
- [24] Li C Q,Xu D K,Chen X B,et al.Composition and microstructure dependent corrosion behaviour of Mg-Li alloys[J].Electrochimica Acta,2018,260:55-64.
- [25] Hou L,Raveggi M,Chen X B,et al.Investigating the passivity and dissolution of a corrosion resistant Mg-33at.% Li alloy in aqueous chloride using online ICP-MS[J].Journal of The Electrochemical Society,2016,163(6):324-329.
- [26] Zeng R C,Sun L,Zheng Y F,et al.Corrosion and characterisation of dual phase Mg-Li-Ca alloy in Hank’s solution:The influence of microstructural features[J].Corrosion Science,2014,79:69-82.
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