Al2O3掺杂对烧结钕铁硼磁体电阻率和磁性能的影响Effect of Al2O3 doping on resistivity and magnetic properties of sintered NdFeB magnets
张梦成,冯泉妤,刘友好,刘家琴,吴玉程
摘要(Abstract):
采用晶间掺杂法在钕铁硼合金粉体中掺入Al_2O_3,制备了Al_2O_3掺杂的烧结钕铁硼磁体,研究了Al_2O_3掺杂对钕铁硼磁体的电阻率、磁性能和微观结构的影响。结果表明:磁体电阻率随着Al_2O_3掺杂量的增加逐步提高,由未掺杂时的125.2μΩ·cm提高到Al_2O_3掺杂量为0.5 mass%时的144.4μΩ·cm,提高了15.3%;磁体矫顽力随着Al_2O_3掺杂量的增加呈先增大后减小的趋势,未掺杂磁体的矫顽力为13.28 kOe,当Al_2O_3掺杂量为0.3 mass%时,矫顽力达到最大值14.97 kOe,继续增加Al_2O_3掺杂量,磁体矫顽力开始下降;剩磁随着Al_2O_3掺杂量的增加逐步降低,由未掺杂时的13.97 kGs下降到Al_2O_3掺杂量为0.5 mass%时的12.69 kGs。掺杂适量的Al_2O_3有利于抑制磁体在烧结过程中的晶粒长大,从而起到细化晶粒的作用,提高磁体矫顽力,同时对温度稳定性也起到一定改善作用。
关键词(KeyWords): 烧结钕铁硼;Al_2O_3;电阻率;晶间掺杂;矫顽力
基金项目(Foundation): 安徽省“特支计划”创新领军人才项目(Z2023TP0002);; 国家重点研发计划(2021YFB3502803);; 安徽省自然科学基金(2108085ME141);; 安徽省重点研究与开发计划项目(202104a05020019)
作者(Author): 张梦成,冯泉妤,刘友好,刘家琴,吴玉程
DOI: 10.13289/j.issn.1009-6264.2023-0359
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