李强,于景媛,穆柏春,孙旭东,孟秀娟

• 1:辽宁工业大学材料科学与工程学院
• 2:东北大学材料与冶金学院

摘要(Abstract)：

采用溶胶-凝胶技术在低温氧化处理后碳纤维表面涂覆HA涂层,获得复合改性碳纤维增强HA复合材料。研究并测试了碳纤维的改性工艺、改性后碳纤维表面的微观形貌以及不同碳纤维含量下复合材料的抗弯强度和断裂韧性。结果表明,在400℃氧化30 min的碳纤维表面具有较高的活性和较大的比表面积,在HA溶胶中提拉5次后碳纤维表面形成一层与基体结合性能较好的膜层。复合改性碳纤维可显著提高HA材料的力学性能,当碳纤维含量为3%时,复合改性碳纤维/HA复合材料的抗弯强度达到最大值79.8 MPa,比基体提高了3.2倍。当碳纤维含量为4%时,复合改性碳纤维/HA复合材料的断裂韧度达到最大值1.85 MPa·m1/2,比基体提高了2.3倍。

关键词(KeyWords)： HA复合材料;碳纤维;复合改性;力学性能

Abstract:

Keywords:

基金项目(Foundation): 国家“863”计划项目(2011AA060102);; 长江学者和创新团队计划项目(IRT0713);; 辽宁省自然科学基金(201102090,2014020111);; 辽宁省博士启动基金(20111068);; 辽宁省高等学校优秀人才支持计划(LJQ2012056,LJQ2013067)

作者(Author): 李强,于景媛,穆柏春,孙旭东,孟秀娟

DOI: 10.13289/j.issn.1009-6264.2014.08.002

参考文献(References)：

• [1]赵冰,杜荣归,林昌健.羟基磷灰石生物陶瓷材料的制备及其新进展[J].功能材料,2003,34(2):126-132.ZHAO Bing,DU Rong-gui,LIN Chang-jian.New developments in the preparation of hydroxyapatite bioceramic materials[J].Functional Materials,2003,34(2):126-132.
• [2]高亚丽,接勐,张海波.医用镁合金表面激光重熔羟基磷灰石涂层[J].材料热处理学报,2012,33(9):117-121.GAO Ya-li,JIE Meng,ZHANG Hai-bo.Laser remelting hydroxyapatite coating on medical Mg alloy[J].Transactions of Materials and Heat Treatment,2012,33(9):117-121.
• [3]Zafer E,Metin U,Isil K.Improvement in sinterability and phase stability of hydroxyapatite and partially stabilized zirconia composites[J].Journal of the European Ceramic Society,2009,29(4):621-628.
• [4]Juliana M,Carina S D,JoséC B,et al.Cell proliferation of human fibroblasts on alumina and hydroxyapatite-based ceramics with different surface treatments[J].International Journal of Applied Ceramic Technology,2010,7(2):139-147.
• [5]Martín A E R,Salvador A S,Jesús L V,et al.Mechanical and bioactive behavior of hydroxyapatite-wollastonite sintered composites[J].International Journal of Applied Ceramic Technology,2010,7(2):164-177.
• [6]Susmita B,Ashis B,Sudip D,et al Synthesis,processing,mechanical,and biological property characterization of hydroxyapatite whisker-reinforced hydroxyapatite composites[J].Journal of the American Ceramic Society,2009,92(2):323-330.
• [7]万怡灶,王玉林,韩可瑜,等.炭纤维增强聚合物复合材料骨折内固定板的研究进展[J].高分子材料科学与工程,2001,17(1):35-38.WAN Yi-zao,WANG Yu-lin,HAN Ke-yu,et al.Development o f carbon fiber reinforced polymer composite bone plate for fracture fixation[J].Polymer Materials Science and Engineering,2001,17(1):35-38.
• [8]Sumit P,Avinash K A,Rai K N,et al.Development of high strength hydroxyapatite by solid-state-sintering process[J].Ceramics International,2007,33(3):419-426.

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