何玉龙,赵毅红,沈国华,陈荣发,周晓进,王自力,王锴,史敏杰

• 1:扬州大学机械工程学院
• 2:江苏省水利勘测设计研究院有限公司
• 3:扬州攀峰网络科技有限公司

摘要(Abstract)：

采用多弧离子镀在SLD钢表面制备CrTiAlN涂层。利用扫描电镜(SEM)、原子力显微镜(AFM)、X射线衍射仪(XRD)、划痕仪和摩擦磨损试验机等研究渗氮处理对SLD钢表面CrTiAlN涂层的组织结构、力学性能和摩擦磨损性能的影响。结果表明,未经渗氮处理的SLD钢表面CrTiAlN涂层的微凸体较多,CrN相以(200)晶面生长,涂层显微硬度为2423 HV0.01。渗氮后,CrN相以(111)晶面择优生长且晶粒更加细小,涂层显微硬度提升24%,磨损机理以磨粒磨损、黏着磨损为主,磨损率下降。

关键词(KeyWords)： SLD钢;渗氮处理;CrTiAlN涂层;摩擦磨损

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(51872254);; 扬州市校合作专项(YZ2019129);; 扬州市邗江区科技计划项目(HJM2019006)

作者(Author): 何玉龙,赵毅红,沈国华,陈荣发,周晓进,王自力,王锴,史敏杰

DOI: 10.13289/j.issn.1009-6264.2021-0027

参考文献(References)：

• [1] 何莹，雷普军，张京，等.粉末冶金模压制成型中硬质合金模体非断裂失效研究[J].模具工业，2019,45(11):72-74.HE Ying,LEI Pu-jun,ZHANG Jing,et al.Study on non fracture failure of cemented carbide mold in powder metallurgy molding[J].Die and Mould Industry,2019,45(11):72-74.
• [2] 孙国栋，刘长华.弧离子镀TiAlN涂层与模具钢基材的结合力的优化[J].热加工工艺，2011,40(2):125-127.SUN Guo-dong,LIU Chang-hua.Optimization of adhesion between arc ion plating TiAlN coating and die steel substrate[J].Hot Working Technology,2011,40(2):125-127.
• [3] 田正磊.H13模具钢表面磁控溅射CrNiTiA1N涂层的性能研究[D].杭州：浙江工业大学，2012.TIAN Zheng-lei.Study on properties of CrNiTiA1N coating on H13 die steel by magnetron sputtering[D].Hangzhou:Zhejiang University of Technology,2012.
• [4] 岑爱.PVD和渗氮处理对高碳高铬冷作模具寿命影响的研究[D].广州：华南理工大学，2017.CEN Ai.Study on the effect of PVD and nitriding treatment on the life of high carbon and high chromium cold working die[D].Guangzhou:South China University of Technology,2017.
• [5] Ma S,Li Y,Xu K.The composite of nitrided steel of H13 and TiN coatings by plasma duplex treatment and the effect of pre-nitriding[J].Surface and Coatings Technology,2001,137(2):116-121.
• [6] Gredic T,Zlatanovic M,Popovic N,et al.Effect of plasma nitriding on the properties of (Ti,Al)N coatings deposited onto hot work steel substrates[J].Thin Solid Films,1993,228(1/2):261-266.
• [7] Ezura H,Ichijo K,Hasegawa H,et al.Micro-hardness,microstructures and thermal stability of (Ti,Cr,Al,Si)N films deposited by cathodic arc method[J].Vacuum,2008,82(5):476-481.
• [8] 楼白杨，娄文雅，徐建龙，等.预渗氮对复合CrTiAlN涂层组织和摩擦性能的影响[J].真空科学与技术学报，2017,37(6):628-632.LOU Bai-yang,LOU Wen-ya,XU Jian-long,et al.Effect of pre nitriding on microstructure and friction properties of composite CrTiAlN films[J].Chinese Journal of Vacuum Science and Technology,2017,37(6):628-632.
• [9] Huang R X,Qi Z B,Sun P,et al.Influence of substrate roughness on structure and mechanical property of TiAlN coating fabricated by cathodic arc evaporation[J].Physics Procedia,2011,18:160-167.
• [10] Shan L,Wang Y X,Li J L,et al.Structure and mechanical properties of thick Cr/Cr2N/CrN multilayer coating deposited by multi-arc ion plating[J].Transactions of Nonferrous Metals Society of China,2015,25(4):1135-1143.
• [11] Kuo Y C,Wang C J,Lee J W.The microstructure and mechanical properties evaluation of CrTiAlSiN coatings:Effects of silicon content[J].Thin Solid Films,2017,638:220-229.
• [12] 贺甜甜，邵若男，刘建，等.不同载荷下GCr15钢的滑动摩擦磨损性能[J].材料热处理学报，2020,41(7):105-110.HE Tian-tian,SHAO Ruo-nan,LIU Jian,et al.Sliding friction and wear properties of GCr15 steel under different loads[J].Transactions of Materials and Heat Treatment,2020,41(7):105-110.
• [13] Khurshudov A,Kato K,Sawada D.Tribological and mechanical properties of carbon nitride thin coating prepared by ion-beam-assisted deposition[J].Tribology Letters,1996,2(1):13-21.
• [14] 王淑庆，王成彪，朱丽娜，等.Si3N4和52100钢对磨副材料对CrN涂层干摩擦学行为的影响[J].材料导报，2017,31(4):41-46.WANG Shu-qing,WANG Cheng-biao,ZHU Li-na,et al.Effect of Si3N4 and 52100 steel on dry tribological behavior of CrN film[J].Materials Review,2017,31(4):41-46.
• [15] 许莎莎，梁文萍，缪强，等.TA19钛合金TiAlN涂层的摩擦磨损特性研究[J].热处理，2019,34(2):7-11.XU Sha-sha,LIANG Wen-ping,MIAO Qiang,et al.Friction and wear properties of TiAlN film on TA19 titanium alloy[J].Heat Treatment,2019,34(2):7-11.
• [16] 徐克刚.渗氮铬渗氮复合工艺研究[D].苏州：苏州大学，2013.XU Ke-gang.Research on chromium nitride nitriding composite process[D].Suzhou:Suzhou University,2013.

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