锆和锶对铸态镍铝青铜组织与性能的影响Effects of zirconium and strontium on microstructure and properties of nickel aluminium bronze ingot
张兵,许晓静,陈树东,蒋伟
摘要(Abstract):
借助显微硬度计、光学显微镜、扫描电镜、X射线衍射分析、腐蚀实验和拉伸测试等手段,研究了锆、锶复合微合金化铸态镍铝青铜的硬度、组织、耐蚀性能和力学性能。结果表明:与未微合金化铸态镍铝青铜(Cu-8.87Al-5.22Fe-4.48Ni-1.08Mn-0.53Zn)相比,锆、锶复合微合金化铸态镍铝青铜(Cu-9.86Al-5.84Fe-4.46Ni-1.03Mn-0.6Zn-0.048Zr-0.03Sr)的相组成没有显著变化,都由α相、β相、γ2相和κ相组成。但是微合金化镍铝青铜的α相和κIV相显著细化,共析组织(α相+κIII相)也大幅细化,合金硬度从212.1 HV提高到216 HV。由于腐蚀优先发生在共析区域内,而共析组织的细化降低了其产生连续腐蚀通道的概率,促进了合金的均匀腐蚀性能和电化学腐蚀性能的全面提高(在3.5%Na Cl水溶液中均匀腐蚀速率和电化学腐蚀速率分别降低2.9%和49.6%);晶粒细化和颗粒弥散强化提高了微合金化镍铝青铜的力学性能,其抗拉强度和屈服强度分别提高到676.6 MPa和260.3 MPa(分别提高4.06%和4.07%)。
关键词(KeyWords): 镍铝青铜;微合金化;组织;耐腐蚀性能;力学性能
基金项目(Foundation): 江苏大学优秀学术青年骨干培养对象基金(1211110001);; 校企产学研合作项目(1801110288)
作者(Author): 张兵,许晓静,陈树东,蒋伟
DOI: 10.13289/j.issn.1009-6264.2015.03.012
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