时效时间对Al-Zn-In-Mg-Ti牺牲阳极电化学性能的影响Influence of aging time on electrochemical performance of Al-Zn-In-Mg-Ti sacrificial anode
贺俊光,文九巴,孙乐民,高军伟,李登辉
摘要(Abstract):
通过比较时效不同时间的Al-5Zn-0.03In-1Mg-0.05Ti-0.1Si阳极合金的析出相、开路电位、电流效率、腐蚀形貌及电化学阻抗谱等,研究了时效时间对该阳极微观组织和电化学性能的影响。结果表明:该合金中的主要析出相为Mg Zn2相,随时效时间的增加析出相迅速长大且密度逐渐降低。时效30 min试样的电化学性能最好,开路电位约-1.0793 V(SCE),电流效率为94.5%,试样表面腐蚀坑深度很浅、腐蚀形貌非常均匀。随着时效时间延长,合金的开路电位逐渐负移,但电流效率却逐渐降低且腐蚀形貌逐渐恶化。析出相对铝基牺牲阳极的电化学性能影响较大,长时间时效不利于改善铝合金阳极的综合电化学性能。
关键词(KeyWords): 时效;铝合金;牺牲阳极;组织;电化学性能
基金项目(Foundation): 河南省重点攻关项目(132102210119);; 河南省教育厅重点项目(14A430001);; 洛阳市科技攻关(1301001A)
作者(Author): 贺俊光,文九巴,孙乐民,高军伟,李登辉
DOI: 10.13289/j.issn.1009-6264.2015.05.017
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