自蔓延高温合成法制备金刚石工具材料研究现状Research status of diamond tool materials prepared by self-propagating high-temperature synthesis
武美玲,尹育航,丁冬海,肖国庆,段锋,彭凯,杨潘,张立,敬臣
摘要(Abstract):
金刚石工具多采用热压烧结法制备,但此方法存在能耗高、结合剂对金刚石的把持力弱、石墨模具污染环境等缺点。自蔓延高温合成法(SHS)不仅具有高效、节能的优点,而且反应过程中产生的瞬时高温有助于金刚石表面形成碳化物,能使结合剂与金刚石形成化学冶金结合。因此,SHS制备金刚石工具受到广泛关注。本文首先基于相关体系的热力学参数(绝热温度),分析了SHS制备金刚石工具的可行性;综述了原料配比、稀释剂、金刚石浓度及排布方式、引燃方式及碳化物的形成等因素对Ni-Al、Ti-Al及Fe-Al体系SHS制备金刚石工具材料的影响;然后,对比了所制得的金刚石工具材料的性能。最后,展望了SHS制备金刚石工具材料潜在的研究方向,提出了抑制SHS反应过程中金刚石石墨化的方法。
关键词(KeyWords): 自蔓延高温合成;金属结合剂;金刚石工具;致密化
基金项目(Foundation): 国家自然科学基金(52272027);; 陕西省重点研发计划(2022GY-421);; 陕西省教育厅科研计划项目(20JY039)
作者(Author): 武美玲,尹育航,丁冬海,肖国庆,段锋,彭凯,杨潘,张立,敬臣
DOI: 10.13289/j.issn.1009-6264.2022-0500
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