Cr-Bi对Mg-8Zn-4Al合金铸态组织及时效沉淀相演变的影响Effect of addition of Cr-Bi on microstructure of Mg-8Zn-4Al alloys
董允,林小娉,叶杰,唐莉
摘要(Abstract):
利用扫描电子显微镜(SEM)和X射线衍射(XRD)等分析手段研究了Bi、Cr-Bi复合添加对Mg-8Al-4Zn合金铸态组织及时效沉淀相演变的影响。结果表明:Cr-Bi复合添加能有效改善合金的铸态组织,使连续网状相断开呈短杆或颗粒状。Bi、Cr-Bi复合添加的合金经350℃×12 h+160℃时效,其沉淀硬化曲线呈现典型的温时效。Cr-Bi复合添加的合金时效初期硬化速率较高,20 h就达到峰值硬度的97%,时效48 h达到峰值硬度92.44 HV,过时效阶段硬度下降速度比较缓慢。Mg-8Zn-4Al-0.5Bi合金经350℃×12 h+160℃×120 h时效后主要有MgZn2、Mg3Bi2和单Bi相,呈短杆或细小颗粒状弥散分布在基体上;Cr-Bi复合添加的合金经350℃×12 h+160℃×144 h时效后,除短杆或细小颗粒状的MgZn2相外还有Cr、Al12Cr3等沉淀相,没有发现粗大的MgZn相,且沉淀相与单独添加Bi经120 h时效的合金相比更加细小、致密、弥散均匀分布。
关键词(KeyWords): 镁合金;沉淀强化;微观组织;时效硬化;Cr-Bi
基金项目(Foundation): 国家自然科学基金(51141007);; 河北省自然科学基金(E2010001398)
作者(Author): 董允,林小娉,叶杰,唐莉
DOI: 10.13289/j.issn.1009-6264.2012.03.011
参考文献(References):
- [1]丁文江.镁合金科学与技术[M].北京:科学出版社,2007.
- [2]Buha J.The effect of micro-alloying addition of Cr on age hardening of an Mg-Zn alloy[J].Materials Science and Engineering A,2008,492:293-299.
- [3]Buha J.The effect of Ba on the microstructure and age hardening of an Mg-Zn alloy[J].Materials Science and Engineering A,2008,491:70-79.
- [4]Buha J.Characterisation of precipitates in an aged Mg-Zn-Ti alloy[J].Journal of Alloys and Compounds,2009,472:171-177.
- [5]马志新,张家振,李德富,等.铸态Mg-Gd-Y-Zr镁合金均匀化工艺研究[J].特种铸造及有色合金,2007,27(9):659-662.MA Zhi-xin,ZHANG Jia-zhen,LI De-fu,et al.Homogenizing process for as-cast Mg-Gd-Y-Zr Magnesium alloy[J].Special Casting and NonferrousAlloys,2007,27(9):659-662.
- [6]LIU Yong,YUAN Guang-yin.Deformation behavior of Mg-Zn-Gd-based alloys reinforced with quasicrystal and laves phases at elevated temperatures[J].Journal of Alloys and Compounds,2007,427:160-165.
- [7]YANG Jie,WANG Li-dong,WANG Li-min,et al.Microstructures and mechanical properties of the Mg-4.5Zn-xGd(x=0,2,3,5)alloys[J].Journalof Alloys and Compounds,2008,459:274-280.
- [8]Joachim Grbner,Artem Kozlov,et al.Thermodynamic analysis of as-cast and heat-treated microstructures of Mg-Ce-Nd alloys[J].Acta Materialia,2011,59:613-622.
- [9]LIANG Shu-quan,GUAN Di-kai,CHEN Liang,et al.Precipitation and its effect on age-hardening behavior of as-cast Mg-Gd-Y alloy[J].Materialsand Design,2011,32:361-364.
- [10]曾小勤,丁文江,姚正裔,等.Mg-Zn-A1系合金组织和力学性能[J].上海交通大学学报,2005,39(1):46-51.ZENG Xiao-qin,DING wen-jiang,YAO Zheng-yi,et al.The microstructure and mechanical properties of Mg-Zn-Al alloys[J].Journal of ShanghaiJiaotong University,2005,39(1):46-51.
- [11]袁广银,张为民,孙扬善.Mg-Al基合金加铋合金化对其力学性能的改善作用[J].东南大学学报,1999,29(3):115-119.YUAN Guang-yin,ZHANG Wei-min,SUN Yang-shan.Effect of bismuth addition on the mechanical properties of Mg-Al based alloys[J].Journal ofSoutheast University,1999,29(3):115-119.
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