Al对Mg-12Gd-3Y-1Sm合金显微组织和耐蚀性的影响Effect of Al on microstructure and corrosion resistance of Mg-12Gd-3Y-1Sm alloy
陈籽佚,李全安,陈晓亚,朱宏喜
摘要(Abstract):
采用静态质量损失法和电化学测试实验等研究了Al元素添加对时效态Mg-12Gd-3Y-1Sm合金耐蚀性的影响。采用光学显微镜、扫描电镜和X射线衍射仪对合金的微观组织及腐蚀产物的物相和形貌进行了观察分析。结果表明:Mg-12Gd-3Y-1Sm时效态合金组织由α-Mg基体和Mg_5Gd、 Mg_(24)Y_5和Mg_(41)Sm_5相组成,添加Al元素后,合金中出现了Al_2RE相。随着Al元素添加量的增加,时效态合金的晶粒先减小后增大,当Al添加量为0.8%时,合金晶粒最细小,第二相最均匀。Al的添加能显著提高合金的耐蚀性,但当Al添加量超过0.8%时合金耐蚀性又开始略有降低,添加0.8%Al的合金具有最佳的耐蚀性,这与电化学测试分析结果相一致,合金腐蚀产物主要为Mg(OH)_2和少量的Al_2RE。
关键词(KeyWords): Mg-Gd-Y-Sm合金;Al;显微组织;耐蚀性
基金项目(Foundation): 国家自然科学基金(51571084)
作者(Author): 陈籽佚,李全安,陈晓亚,朱宏喜
DOI: 10.13289/j.issn.1009-6264.2020-0435
参考文献(References):
- [1] 翟春泉,曾小勤,丁文江,等.镁合金的开发与应用[J].机械工程材料,2001,25(1):6-10.ZHAI Chun-quan,ZENG Xiao-qin,DING Wen-jiang,et al.Development and application of magnesium alloys in China[J].Materials For Mechanical Engineering,2001,25(1):6-10.
- [2] Mordike B L,Ebert T.Magnesium:properties-applications-potential[J].Materials Science and Engineering A,2001,302:37-45.
- [3] 李全安,李克杰,张清.Sm对时效态Mg-12Gd-2Y-0.5Zr合金组织与力学性能的影响[J].材料热处理学报,2011,32(12):84-88.LI Quan-an,LI Ke-jie,ZHANG Qing.Effects of Sm on microstructure and mechanical properties of aged Mg-12Gd-2Y-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2011,32(12):84-88.
- [4] 贵云玮,李全安,周耀,等.热处理对Mg-11Gd-2Y-5Sm-0.5Zr合金组织和力学性能的影响[J].中国稀土学报,2017,35(6):776-781.GUI Yun-wei,LI Quan-an,ZHOU Yao,et al.Effect of heat treatment on microstructure and mechanical properties of Mg-11Gd-2Y-5Sm-0.5Zr alloy[J].Journal of the Chinese Society of Rare Earths,2017,35(6):776-781.
- [5] 付三玲.Mg-Gd(-Y-Sm-Zr)耐热镁合金组织和性能研究[D].西安:西安理工大学,2016.FU San-ling.Study on microstructure and mechanical properties of Mg-Gd(-Y-Sm-Zr) heat resistant magnesium alloys[D].Xi’an:Xi’an University of Technology,2016.
- [6] 张帅,李全安,朱宏喜,等.Ca对Mg-1lGd-3Y-0.5Zr合金显微组织和耐蚀性的影响[J].材料热处理学报,2019,40(8):17-23.ZHANG Shuai,LI Quan-an,ZHU Hong-xi,et al.Effect of Ca on microstructure and corrosion resistance of Mg-11Gd-3Y-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2019,40(8):17-23.
- [7] 王浩,文九巴,贺俊光,等.微量稀土Sm对AZ80镁合金腐蚀性能的影响[J].材料热处理学报,2013,34(4):41-45.WANG Hao,WEN Jiu-ba,HE Jun-guang,et al.Effect of rare earth element Sm on corrosion resistance of AZ80 magnesium alloy[J].Transactions of Materials and Heat Treatment,2013,34(4):41-45.
- [8] 张靖.Al/(Ca+Nd)比对Mg-Al合金组织和性能的影响[D].哈尔滨:哈尔滨理工大学,2017.ZHANG Jing.Effect of Al/(Ca+Nd) on microstructure and properties of Mg-Al alloy[D].Harbin:Harbin University of Science and Technology,2017.
- [9] Liu M,Uggowitzer P J,Nagasekhar A V,et al.Calculated phase diagrams and the corrosion of die-cast Mg-Al alloys[J].Corrosion Science,2009,51(3):602-619.
- [10] Li K J,Li Q A,Jing X T,et al.Effects of Sm addition on microstructure and mechanical properties of Mg-6Al-0.6Zn alloy[J].Scripta Materialia,2009,60(12):1101-1104.
- [11] 李振亮,贾国栋,张婧,等.Al对挤压态稀土镁合金耐蚀性的影响[J].铸造,2014,63(6):56-559.LI Zhen-liang,JIA Guo-dong,ZHANG Jing,et al.Effects of Al on corrosion resistant property of as-extruded magnesium alloys containing rare earth[J].Foundry,2014,63(6):556-559.
- [12] Dai J,Zhu S,Easton M A,et al.Heat treatment,microstructure and mechanical properties of a Mg-Gd-Y alloy grain-refined by Al additions[J].Materials Science and Engineering A,2013,576:298-305.
- [13] Makar G L,Kruger J.Corrosion of magnesium[J].International Materials Review,1993,38(3):138-153.
- [14] Gui Y W,Li Q A,Chen J,et al.Corrosion behaviour and electrochemistry of Mg-5Y-2Nd-0.5Zr-xSm(x=0,1,3 and 5) alloys in 3.5 wt.% NaCI[J].International Journal of Electrochemical Science,2018,13(12):11502-11515.
- [15] StJohn D H,Cao P,Qian M,et al.A new analytical approach to reveal the mechanisms of grain refinement[J].Advanced Engineering Materials,2007,9(9):739-746.
- [16] Hu X Y,Fu P H,StJohn D,et al.On grain coarsening and refining of the Mg-3Al alloy by Sm[J].Journal of Alloys and Compounds,2016,663:387-394.
- [17] 张志.Al2Sm和Al2Ca对Mg-6A1合金组织及热稳定性能的影响[D].哈尔滨:哈尔滨理工大学,2019.ZHANG Zhi.Effect of Al2Sm and Al2Ca on microstructure and thermal stability properties of Mg-6Al alloy[D].Harbin:Harbin University of Science and Technology,2019.
- [18] 李萧,胡水平,韩天棋.Nd、Y对AZ31镁合金热轧退火薄板耐蚀性的影响[J].材料导报,2020,34(10):10088-10092.LI Xiao,HU Shui-ping,HAN Tian-qi.Effects of Nd,Y on corosion resistibility of hot-rolled and annealed AZ31 magnesium alloy thin sheets[J].Materials Reports,2020,34(10):10088-10092.
- [19] 张诗昌,段汉桥,蔡启舟,等.主要合金元素对镁合金组织和性能的影响[J].铸造,2001,50(6):310-316.ZHANG Shi-chang,DUAN Han-qiao,CAI Qi-zhou,et al.Effects of the main alloying elements on microstructure and properties of magnesium alloys[J].Foundry,2001,50(6):310-316.
- [20] 刘瞿,陈高强,曾申波,等.组织细化对AZ9ID镁合金腐蚀性能的影响[J].清华大学学报(自然科学版),2019,59(9):765-771.LIU Qu,CHEN Gao-qiang,ZENG Shen-bo,et al.Effect of microstructure refinement on the corrosion of AZ9ID magnesium alloys[J].Jourmal of Tsinghua University(Science and Technology),2019,59(9):765-771.
- [21] Aung N N,Zhou W.Effect of grain size and twins on corrosion behaviour of AZ31B magnesium alloy[J].Corrosion Science,2010,52(2):589-594.
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