S32760超级双相不锈钢中σ相的析出规律Precipitation behavior of σ phase in UNS S32760 super duplex stainless steel
罗照银,李静媛
摘要(Abstract):
利用光学显微镜、纳米力学探针、扫描电镜、能谱仪和透射电镜等方法,研究了S32760超级双相不锈钢热轧板材经1100℃固溶60 min,并在760~1040℃保温30 min过程中σ相的析出规律,分析了W元素对σ相析出行为的影响。结果表明,σ相中富集大量Cr、Mo和W元素,贫Ni且不含N。W提高了σ相在高温区间的稳定性,使σ相在760~1020℃的范围内均能析出。在析出鼻尖温度880℃时效30 min后,钢板硬度达最大值37.1 HRC,α相体积分数降至5.3%。随着时效温度的升高,σ相的形貌变化规律为:粒状→粒状+短棒状→片层状→块状。在鼻尖温度(880℃)附近,σ相和γ2相以片层共析形貌析出,而在高温阶段(如960℃)则呈现出γ2相被大块σ相包围的形貌。
关键词(KeyWords): S32760超级双相不锈钢;时效;σ相;二次奥氏体γ2;相变
基金项目(Foundation): 国家自然科学基金(51174026);; 十二五国家科技支撑计划(2012BAE04B02)
作者(Author): 罗照银,李静媛
DOI: 10.13289/j.issn.1009-6264.2015.04.019
参考文献(References):
- [1]吴玖,姜世振,韩俊媛,等.双相不锈钢[M].北京:冶金工业出版社,1999.
- [2]Calliari I,Zanesco M,Ramous E,et al.Effects of isothermal ageing and continuous cooling after solubilization in a duplex stainless steel[J].Journal of Materials Engineering and Performance,2007,16(1):109-112.
- [3]陈玲玲,索慧波,梁晓慧.时效制度对2205双相不锈钢耐蚀性能的影响[J].金属热处理,2014,39(8):105-108.CHEN Ling-ling,SUO Hui-bo,LIANG Xiao-hui.Effect of aging process on corrosion resistance of 2205 duplex stainless steel[J].Heat Treatment of Metals,2014,39(8):105-108.
- [4]宾远红,李培芬,李志铮,等.不同固溶温度对双相不锈钢σ相析出及冲击韧性的影响[J].材料热处理学报,2013,34(8):136-141.BIN Yuan-hong,LI Pei-fen,LI Zhi-zheng,et al.Precipitation ofσ-phase and its effect on impact toughness of a duplex stainless steel solution-treated at different temperatures[J].Transactions of Materials and Heat Treatment,2013,2013,34(8):136-141.
- [5]黄伟林,向红亮,陈彤,等.时效时间对2906超级双相不锈钢组织及性能的影响[J].材料热处理学报,2013,34(12):120-124.HUANG Wei-lin,XIANG Hong-liang,CHEN Tong,et al.Effects of aging time on microstructure and properties of 2906 super duplex stainless steel[J].Transactions of Materials and Heat Treatment,2013,34(12):120-124.
- [6]Wang X F,Chen W Q.Influence of isothermal aging on the embrittlement of 00Cr25Ni7Mo4N super duplex stainless steel[J].Materials Technology,2009,80(10):779-784.
- [7]向红亮,何福善,刘东.时效温度对铸造超级双相不锈钢析出相的影响[J].金属学报,2009,45(12):1456-1460.XIANG Hong-liang,HE Fu-shan,LIU Dong.Effects of aging temperature on precipitation phase of a cast super duplex stainless steel[J].Acta Metallurgica Sinica,2009,45(12):1456-1460.
- [8]邹德宁,韩英,张威,等.高温时效对2507超级双相不锈钢组织和性能的影响[J].材料热处理学报,2010,31(6):73-76.ZOU De-ning,HAN Ying,ZHANG Wei,et al.Influence of high temperature aging on microstructure and properties of 2507 super-duplex stainless steel[J].Transactions of Materials and Heat Treatment,2010,31(6):73-76.
- [9]王国华.σ相的析出对双相不锈钢组织性能的影响[J].中国冶金,2011,21(6):15-18.WANG Guo-hua.Influence of the sigma phase precipitation on the microstructure and properties in duplex stainless steel[J].China Metallurgy,2011,21(6):15-18.
- [10]赵志毅,徐林,李国平,等.超级双相不锈钢σ相析出及对组织性能的影响[J].材料热处理学报,2010,31(10):75-79.ZHAO Zhi-yi,XU Lin,LI Guo-ping,et al.Precipitation behavior ofσ-phase and its effect on microstructure and properties of a super duplex stainless steel[J].Transactions of Materials and Heat Treatment,2010,31(10):75-79.
- [11]李骥,宋志刚,郑文杰,等.W含量对00Cr25Ni7Mo3.5WCu N钢力学性能的影响[J].金属热处理,2014,39(11):64-67.LI Ji,SONG Zhi-gang,ZHENG Wen-jie,et al.Effect of tungsten on mechanical properties of 00Cr25Ni7Mo3.5WCu N super duplex stainless steel[J].Heat Treatment of Metals,2014,39(11):64-67.
- [12]Zucato I,Moreira M C,Machado I F,et al.Microstructural characterization and the effect of phase transformations on toughness of the UNS S31803duplex stainless steel aged treated at 850℃[J].Materials Research,2002,5(3):385-389.
- [13]杨银辉,严彪,郑鑫.双相不锈钢高温时效σ相析出行为研究进展[J].材料导报,2011,25(10):105-109.YANG Yin-hui,YAN Biao,ZHENG Xin.Research development ofσphase precipitation in high temperature aging on duplex stainless steel[J].Materials Review,2011,25(10):105-109.
- [14]Fargas G,Anglada M,Mateo A.Effect of the annealing temperature on the mechanical properties,formability and corrosion resistance of hot-rolled duplex stainless steel[J].Journal of Materials Processing Technology,2009,209:1770-1782.
- [15]姚瑶,周灿栋,史弼,等.超级双相不锈钢中σ相力学性能的纳米压痕表征[J].机械工程材料,2011,35(7):1-3+7.YAO Yao,ZHOU Can-dong,SHI Bi,et al.Nanoindentation characterization of mechanical properties ofσphase in super duplex stainless steel[J].Materials for Mechanical Engineering,2011,35(7):1-3.
- [16]Nilsson J O,Kangas P,Wilson A,et al.Mechanical properties,microstructural stability and kinetics ofσ-phase formation in 29Cr-6Ni-2Mo-0.38N super duplex stainless steel[J].Metallurgical and Materials Transactions A,2000,31:35-45.
- [17]Chen T H,Weng K L,Yang J R.The effect of high-temperature exposure on the microstructural stability and toughness property in a 2205 duplex stainless steel[J].Materials Science and Engineering A,2002,338:259-270.
- [18]Sieurin H,Sandstrm R.Sigma phase precipitation in duplex stainless steel 2205[J].Materials Science and Engineering A,2007,444:271-276.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||