质子交换膜燃料电池不锈钢双极板表面CrNx薄膜的制备及性能Preparation and performance of CrNx thin films on surface of stainless steel bipolar plates for proton exchange membrane fuel cells
李帅,翟志华,孙海东,邵明昊,姜金龙
摘要(Abstract):
采用多弧离子镀技术,在316L不锈钢基底上制备了CrNx薄膜。通过正交试验法分析了工艺参数对薄膜微观结构和性能的影响。结果表明:各工艺因素影响CrNx薄膜的表面液滴数量、耐腐蚀性和界面接触电阻的重要性分别为:靶电流>基体偏压>沉积气压;基体偏压>靶电流>沉积气压;靶电流>沉积气压>基体偏压。综合考虑,靶电流为80A、基体偏压为50V、沉积气压为3.5Pa的参数组合为最优工艺。经最优工艺制备的CrNx薄膜由Cr、Cr_2N与CrN相组成,其表面液滴粒径较小,表现出优良的耐腐蚀性,腐蚀电流密度仅为0.574μA·cm~(-2),同时具有较低的界面接触电阻,为9.68mΩ·cm~2。
关键词(KeyWords): 金属双极板;CrNx;金属液滴;耐腐蚀性能;导电性
基金项目(Foundation): 山东省重点研发计划(SYS202203)
作者(Author): 李帅,翟志华,孙海东,邵明昊,姜金龙
DOI: 10.13289/j.issn.1009-6264.2024-0125
参考文献(References):
- [1] Debe M K. Electrocatalyst approaches and challenges for automotive fuel cells[J]. Nature,2012,486(7401):43-51.
- [2] Gao X,Chen J,Xu R,et al. Research progress and prospect of the materials of bipolar plates for proton exchange membrane fuel cells(PEMFC)[J]. International Journal of Hydrogen Energy,2024,50:711-743.
- [3] Lee F C,Ismail M S,Ingham D B,et al. Alternative architectures and materials for PEMFC gas diffusion layers:A review and outlook[J]. Renewable and Sustainable Energy Reviews,2022,166(321):112-640.
- [4] Yi P,Zhang D,Qiu D,et al. Carbon-based coatings for metallic bipolar plates used in proton exchange membrane fuel cells[J].International Journal of Hydrogen Energy,2019,44(13):6813-6843.
- [5] Wu S,Yang W,Yan H,et al. A review of modified metal bipolar plates for proton exchange membrane fuel cells[J]. International Journal of Hydrogen Energy,2021,46(12):8672-8701.
- [6] Chen J, Fan R, Qin N, et al. Recent advances on materials and technologies of composite bipolar plate for proton exchange membrane fuel cell[J]. Journal of Power Sources,2024,594(378):234009.
- [7]孙贤伟,李希超,赵经香,等.质子交换膜燃料电池双极板防护薄膜研究进展[J].表面技术,2023,52(5):26-36.SUN Xian-wei,LI Xi-chao,ZHAO Jing-xiang,et al. Research progress on protective coatings for bipolar plates of proton exchange membrane fuel cells[J]. Surface Technology,2023,52(5):26-36.
- [8]侯强强,李希超,孙贤伟,等. PEMFC金属双极板氮化物涂层的研究进展[J].材料热处理学报,2024,45(1):11-21.HOU Qiang-qiang,LI Xi-chao,SUN Xian-wei,et al. Research progress of nitride coatings on PEMFC metal bipolar plate[J].Transactions of Materials and Heat Treatment,2024,45(1):11-21.
- [9] Song Y,Zhang C,Ling C Y,et al. Review on current research of materials,fabrication and application for bipolar plate in proton exchange membrane fuel cell[J]. International Journal of Hydrogen Energy,2020,45(54):29832-29847.
- [10] Lee S H,Kakati N,Maiti J,et al. Corrosion and electrical properties of Cr N-and Ti N-coated 316L stainless steel used as bipolar plates for polymer electrolyte membrane fuel cells[J]. Thin Solid Films,2013,529(40):374-379.
- [11]赵时璐.多弧离子镀Ti-Al-Zr-Cr-N系复合硬质膜的制备、微结构与性能[D].沈阳:东北大学,2024:2-20.ZHAO Shi-lu. Preparation,microstructure and properties of Ti-Al-Zr-Cr-N composite hard films deposited by multi-arc ion plating[D]. Shenyang:Northeastern University,2024:2-20.
- [12] Deng Y,Chen W,Li B,et al. Physical vapor deposition technology for coated cutting tools:A review[J]. Ceramics International,2020,46(11):18373-18390.
- [13] Tkadletz M,Mitterer C,Sartory B,et al. The effect of droplets in arc evaporated Ti Al Ta N hard coatings on the wear behavior[J].Surface and Coatings Technology,2014,257(257):95-101.
- [14] Panjan P,ˇCekada M,Panjan M,et al. Growth defects in PVD hard coatings[J]. Vacuum,2009,84(1):209-214.
- [15] Sebastiani M,Piccoli M,Bemporad E. Effect of micro-droplets on the local residual stress field in CAE-PVD thin coatings[J].Surface and Coatings Technology,2013,215(257):407-412.
- [16] Ali M,Hamzah E,Abbas T,et al. Macrodroplet reduction and growth mechanisms in cathodic arc physical vapor deposition of Ti N films[J]. Surface Review and Letters,2008,15(5):653-659.
- [17] Wang H,Stack M,Lyon S,et al. The corrosion behaviour of macroparticle defects in arc bond-sputtered Cr N/Nb N superlattice coatings[J]. Surface and Coatings Technology,2000,126(2/3):279-287.
- [18] Cede?o-Vente M L, Manríquez J, Mondragón-Rodríguez G C, et al. Application of a transmission line model to evaluate the influence of structural defects on the corrosion behavior of arc-PVD Cr N coatings[J]. Ceramics International,2021,47(15):20885-20899.
- [19]吕树国,刘常升,张罡,等.氮离子束辅助电弧离子镀对Ti N膜层中金属“大颗粒”影响的研究[J].钢铁研究学报,2010(1):22-25.LüShu-guo,LIU Chang-sheng,ZHANG Gang,et al. Effect of ion beam bombardment assisted arc ion plating on metal ‘large particles’ in tin coatings[J]. Journal of Iron&Steel Research,2010,22(1):22-25.
- [20] Liu R,Jia Q,Zhang B,et al. Protective coatings for metal bipolar plates of fuel cells:A review[J]. International Journal of Hydrogen Energy,2022,47(54):22915-22937.
- [21] Zhang H,Lin G,Hou M,et al. Cr N/Cr multilayer coating on 316L stainless steel as bipolar plates for proton exchange membrane fuel cells[J]. Journal of Power Sources,2012,198:176-181.
- [22] Lee W,Yun E,Hong S,et al. Ultrathin effective Ti N protective films prepared by plasma-enhanced atomic layer deposition for high performance metallic bipolar plates of polymer electrolyte membrane fuel cells[J]. Applied Surface Science,2020,519:146215.
- [23]段佳妮,李文正,赵春蕾,等.多弧离子镀制备Ti Al CN和Ti Al N薄膜的结构和摩擦磨损性能[J].表面技术,2022,51(4):10.DUAN Jia-ni,LI Wen-zheng,ZHAO Chun-lei,et al. Structure and tribological property of Ti Al CN and Ti Al N coatings prepared by multi-arc ion plating[J]. Surface Technology,2022,51(4):139-148.
- [24] Zhang M,Lin G,Wu B,et al. Composition optimization of arc ion plated Cr Nx films on 316L stainless steel as bipolar plates for polymer electrolyte membrane fuel cells[J]. Journal of Power Sources,2012,205:318-323.
- [25] Zhang D,Guo L,Duan L,et al. Preparation of Cr-based multilayer coating on stainless steel as bipolar plate for PEMFC by magnetron sputtering[J]. International Journal of Hydrogen Energy,2011,36(3):2184-2189.
- [26] Heo H S,Kim S J. Effects of PVD deposition method on electrochemical properties and interfacial contact resistance of Cr N coated titanium as PEMFC bipolar plate[J]. Transactions of the IMF,2023,101(5):1-8.
- [27] Wang Y,Tan Q, Huang B. Synthesis and properties of novel N/Ta-co-doped Ti O2 coating on titanium in simulated PEMFC environment[J]. Journal of Alloys and Compounds,2021,879:160470.
- [28] Wang H,Sweikart M A,Turner J A. Stainless steel as bipolar plate material for polymer electrolyte membrane fuel cells[J]. Journal of Power Sources,2003,115(2):243-251.
- [29] Du H,Zhao H,Xiong J,et al. Effect of interlayers on the structure and properties of Ti Al N based coatings on WC-Co cemented carbide substrate[J]. International Journal of Refractory Metals and Hard Materials,2013,37:60-66.
- [30] Zhirkov I,Petruhins A,Rosén J. Effect of cathode composition and nitrogen pressure on macroparticle generation and type of arc discharge in a DC arc source with Ti-Al compound cathodes[J]. Surface and Coatings Technology,2015,281:20-26.
- [31]宋鑫.基于减少大颗粒的弧斑可控电弧源蒸发过程工艺优化研究[D].沈阳:东北大学,2018.SONG Xin. Study on optimization of the evaporation process of cathode-spots-controlled arc source based on reducing macroparticles[D]. Shenyang:Northeastern University,2018.
- [32] Bi F,Yi P,Zhou T,et al. Effects of Al incorporation on the interfacial conductivity and corrosion resistance of Cr N film on SS316L as bipolar plates for proton exchange membrane fuel cells[J]. International Journal of Hydrogen Energy,2015,40(31):9790-9802.
- [33] Li M,Feng C,Wang F. Effect of partial pressure of reactive gas on chromium nitride and chromium oxide deposited by arc ion plating[J]. Transactions of Nonferrous Metals Society of China,2006,16(1):s276-s279.
- [34] Gui B,Zhou H,Liu X,et al. Influence of N2 flow rate on microstructure and properties of Cr Nx ceramic films prepared by MPP technique at low temperature[J]. Ceramics International,2021,47(15):20875-20884.
- [35] Sugumaran A A, Purandare Y, Ehiasarian A P, et al. Corrosion behavior of post-deposition polished droplet-embedded arc evaporated and droplet-free high power impulse magnetron sputtering/direct current magnetron sputtering coatings[J]. Corrosion,2017,73(6):685-693.
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