高频感应焊接黄铜管在海水中的腐蚀机理分析Analysis of corrosion mechanism of high-frequency induction welded brass pipe in seawater
周雷,蔡琰,张炎雨,吴栅,谢志雄,董仕节,解剑英
摘要(Abstract):
对高频感应焊接H65黄铜管进行海水浸泡实验,测量了不同浸泡时间后黄铜焊管的质量变化率,利用体式显微镜、扫描电镜(SEM)、电子探针(EPMA)、电子背散射衍射(EBSD)技术以及X射线光电子能谱(XPS)对焊缝浸泡腐蚀后的微观形貌和元素分布进行分析,利用电化学工作站对焊接接头进行电化学性能测试。结果表明:随着浸泡时间的延长,含有焊缝试样与母材的质量变化率之差逐渐增大;腐蚀产物主要有CuO、Cu(OH)_2、Cu_2O、CuCl、ZnO和Zn(OH)_2等,H65黄铜在海水中的腐蚀机理为“溶解-再沉积”机制;电化学腐蚀的结果表明,焊接接头的耐蚀性低于母材,这是由于焊缝晶粒产生了严重的塑性变形,导致焊接接头的位错密度和内应力大,能量较高。
关键词(KeyWords): 高频感应焊接;H65黄铜;浸泡腐蚀实验;耐蚀性
基金项目(Foundation): 国家自然科学基金(51771071);; 湖北省国际科技合作项目(2022EHB020);; 湖北隆中实验室自主创新项目(2022ZZ-17)
作者(Author): 周雷,蔡琰,张炎雨,吴栅,谢志雄,董仕节,解剑英
DOI: 10.13289/j.issn.1009-6264.2024-0036
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