生物活性稀土梯度涂层在碱液环境中的电极化后处理Electric polarized post treatment of rare earth active bioceramic gradient coating in alkaline solution
汪震,刘其斌,肖明,杨邦成
摘要(Abstract):
为了改善活性生物稀土梯度涂层的质量,在碱液环境中采用电极化处理法(PAS)对宽带激光熔覆生物活性稀土梯度涂层进行后处理。利用XRD和电化学分析仪对涂层的相组成和耐腐蚀性进行了研究,通过模拟体液浸泡试验考察了生物陶瓷涂层的生物活性和涂层表面的电荷分布情况。结果表明,碱液环境中电极化处理法(PAS)能够提高涂层的结晶度,使涂层中的非晶相、杂相向羟基磷灰石转化。PAS对涂层的耐腐蚀性影响不大。与未处理涂层相比,PAS处理后的涂层生物活性更好,且涂层表面产生了更多的负电荷。
关键词(KeyWords): 宽带激光熔覆;梯度涂层;稀土氧化物Nd2O3;电极化;生物活性
基金项目(Foundation): 国家自然科学基金资助项目(50961003);; 贵州大学研究生创新基金资助项目(省研理工2010001);; 贵州省科技创新人才团队建设项目(科合人才团队(2010)4004)
作者(Author): 汪震,刘其斌,肖明,杨邦成
DOI: 10.13289/j.issn.1009-6264.2011.10.019
参考文献(References):
- [1]俞耀庭,张兴栋.生物医用材料[M].天津:天津大学出版社,2000.
- [2]Yang Y C,Chang E,The bonding of plasma-sprayed hydroxyapatite coatings to titanium:effect of processing,porosity and residual stress[J].ThinSolid Films,2003,444(1-2):260-275.
- [3]Stoch A,Jastrzebski W.Sol-gel derived hydroxyapatite coatings on titanium and its alloy Ti6A14V[J].Molecular Structual,2005,22(5):744-747.
- [4]Miguel Manso,Carmen Jimenez.Electrodeposition of hydroxyapatite coatings in basic conditions[J].Biomaterials,2000,21(17):1755-1761.
- [5]王勇,高家诚,张亚平.激光熔覆梯度生物陶瓷涂层的研究[J].中国激光,2004,31(4):487-490.WANG yong,GAO Jia-cheng,ZHANG Ya-ping.Study on graded bioceramic coating cladded by laser beam[J].Chinese Journal of Lasers,2004,31(4):487-490.
- [6]刘其斌,王存山,夏元良.宽带激光熔覆WCp/Ni基合金梯度涂层中WCp的溶解机理[J].材料热处理学报,2001,22(3):33-36.LIU Qi-bing,WANG Chen-shan,XIA Yuan-liang.Study on solution mechanism of cast WCp/Ni base alloy gradient coating by wide-band lasercladding.[J].Transactions of Materials and Heat Treatment,2001,22(3):33-36.
- [7]刘其斌,陈江,王丽,等.高温合金激光表面熔铸涂层组织与性能的研究[J].金属热处理学报,1997,18(2):52-54.LIU Qi-bing,CHEN Jiang,WANG Li.Study on microstructure and properties of coating on high temperature alloy by laser surface melt-coating[J].Transactions of Mater Heat Treatment,1997,18(2):52-54.
- [8]刘其斌,郑敏,朱维东,等.宽带激光熔覆梯度生物活性陶瓷复合涂层组织与性能[J].应用激光,2004,24(6):350-354.LIU Qi-bing,ZHENG Min,ZHU Wei-dong,et al.Microstructure and properties on gradient bioceremics composite coating produced by wide-band lasercladding on surface of Ti alloy[J].Applied Laser,2004,24(6):350-354.
- [9]刘其斌,郑敏,朱维东,等.钛合金表面宽带激光熔覆梯度梯度生物陶瓷复合涂层[J].功能材料,2005,36(1):50-53.LIU Qi-bing,ZHENG Min,ZHU Wei-dong,et al.Gradient bioceremics composite coating produced by wide-band laser cladding on surface of Ti alloy[J].Function Material,2005,36(1):50-53.
- [10]黄毅,杨邦成,张兴栋,等.碱液环境中等离子喷涂羟基磷灰石涂层的电极化后处理研究[J].稀有金属材料与工程,2007,36(8):1377-1381.HUANG Yi,YANG Bang-cheng,ZHANG Xing-dong,et al.Electric polarized post treatment of plasma sprayed hydroxyapatite coating in alkalinesolution.[J].Rare Materials and Engineering,2007,36(8):1377-1381.
- [11]Kokubo T,Takadama H.How useful is SBF in predieting in vivo bonebioactivity[J].Biomaterials,2006,27(15):2907-2915.
- [12]Lin F H,Hsu Y S,Lin S H,et al.The effect of Ca/P concentration and temperature of simulated body fluid on the growth of hydroxyapatite coatingonalkali-treated 316L stainless steel[J].Biomaterials,2002,23(19):4029-4038.
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