硼脱氧后的残留硼含量对纯铜组织及性能的影响Effect of residual boron content after boron deoxidation on microstructure and properties of pure copper
张凌亮,程楚,宋克兴,刘海涛,周延军,安士忠,宋金涛,华云筱
摘要(Abstract):
针对铜熔炼脱氧工艺,研究了采用硼粉脱氧后残留氧含量及残留硼含量对纯铜微观组织、力学性能和电学性能的影响。结果表明:随着硼加入量的增加,纯铜中氧含量快速降低,残留硼含量升高,纯铜微观组织中枝晶状的氧化亚铜相逐渐消失;随着残留硼含量从0×10~(-6)增加至8.8×10~(-6)时,纯铜的抗拉强度和硬度先升高后降低,伸长率不断升高,导电率升高;当残留硼含量为23×10~(-6)时,纯铜的抗拉强度为135.6 MPa,伸长率为55%,硬度为60.8 HV0.1,导电率为98.12%IACS。
关键词(KeyWords): 纯铜;脱氧;组织;力学性能;导电性能
基金项目(Foundation): 国家自然科学基金面上项目(52071133);; 河南省科技攻关项目(202102210207);; 河南省创新引领专项(191110210400);; 中国博士后科学基金第67批面上资助(2020M672222);; 河南省高等学校重点科研项目(19A430012);; 洛阳市科技重大专项(1901006A);; 河南省杰出人才创新基金(182101510003)
作者(Author): 张凌亮,程楚,宋克兴,刘海涛,周延军,安士忠,宋金涛,华云筱
DOI: 10.13289/j.issn.1009-6264.2021-0143
参考文献(References):
- [1] Zinkle,Steven J.Applicability of copper alloys for demo high heat flux components[J].Physica Scripta,2016,2016:4-14.
- [2] Li Z D,Lin C G,Cui S.Development of research and application of copper alloys with high strength and high conductivity[J].Advanced Materials Research,2014,1053:61-68.
- [3] Laque F L.The behavior of nickel copper alloys in sea water[J].Naval Engineers Journal,2010,53(1):29-64.
- [4] Jang Y H,Kim S S,Han S Z,et al.Effect of trace phosphorous on tensile behavior of accumulative roll bonded oxygen-free copper[J].Scripta Materialia,2005,52(1):21-24.
- [5] Myers M,Blythe E A.Effects of oxygen,sulphur and porosity on mechanical properties of cast high-purity copper at 950 ℃[J].Metal Science Journal,2013,8(1):165-170.
- [6] Nieh T G,Nix W D.Embrittlement of copper due to segregation of oxygen to grain boundaries[J].Metallurgical Transactions A,1981,12(5):893-901.
- [7] 王吉会,姜晓霞,李诗卓.硼在纯铜熔炼中的脱氧作用[J].科学通报,1995(15):1426-1426.WANG Ji-hui,JIANG Xiao-xia,LI Shi-zhuo.Deoxidization of boron in pure copper smelting [J].Science Bulletin,1995 (15):1426-1426
- [8] 罗云,刘莹,钟志强.浅析杂质元素对铜杆质量的影响[J].有色金属加工,2012,41(3):26-30.LUO Yun,LIU Ying,ZHONG Zhi-qiang.Analysis of the influence of impurity elements on the quality of copper rod [J].Processing of Nonferrous Metals,2012,41(3):26-30.
- [9] Sandstrm R,Andersson H.The effect of phosphorus on creep in copper [J].Journal of Nuclear Materials,2008,372(1):66-75.
- [10] 贾延琳,汪明朴,李周.磷脱氧铜管焊接漏气失效分析[J].理化检验-物理分册,2006,42(2):92-94.JIA Yan-lin,WANG Ming-pu,LI Zhou.Cracking analysis of brazed phosphorus deoxidized copper tube [J].Physical Testing and Chemical Analysis part A:Physical Testing,2006,42 (2):92-94.
- [11] Aksoy M,Kuzucu V,Turhan H.A note on the effect of phosphorus on the microstructure and mechanical properties of leaded-tin bronze[J].Journal of Materials Processing Technology,2002,124(1/2):113-119.
- [12] 郝平菊,王振华,刘元铭.退火温度对铜/铝/铜复合板结合性能的影响[J].热加工工艺,2018,47(24):159-162.HAO Ping-ju,WANG Zhen-hua,LIU Yuan-ming.Effect of annealing temperature on bonding properties of copper/aluminum/copper composite plate [J].Hot Working Technology,2018,47 (24):159-162.
- [13] Wang S,Zhang S,Song H,et al.Surface roughness improvement of the bent thin-walled copper tube by controlling the microstructure and texture components[J].Procedia Manufacturing,2020,50:613-617.
- [14] Wang J,Jiang X,Li S.Effect of boron on microstructure and properties of copper-base alloys[J].Chinese Journal of Material Research,1997,11(4):381-386.
- [15] Wang J,Jiang X,Li S.Microalloying effect of boron on copper-base alloys[J].Transactions of Nonferrous Metals Society of China,1996,6(1):89-94.
- [16] Lu D,Wang J,Lu L,et al.Effect of boron and cerium on microstructures and properties of Cu-Fe-P alloy[J].Journal of Rare Earths,2006,24(5):602-606.
- [17] Cao X,Jahazi M.Examination and verification of the filtration mechanism of cake mode during the pressure filtration tests of liquid Al-Si cast alloys[J].Materials Science and Engineering A,2005,403(1):94-100.
- [18] Batra I S,Dey G K,Kulkami U D,et al.Microstructure and properties of Cu-Cr-Zr alloy[J].Journal of Nuclear Materials,2001,299(2):91-100.
- [19] 苏义祥,门志慧.纯铜熔炼及铸件缺陷分析和预防措施[J].铸造,2005(9):89-91.SU Yi-xiang,MEN Zhi-hui.Defect analysis and preventive measures of pure copper smelting and casting[J].Casting,2005(9):89-91.
- [20] Chakrabarti D J,Laughlin D E.The B-Cu (boron-copper) system[J].Bulletin of Alloy Phase Diagrams,1982,3(1):45-48.
- [21] Zou J,Lu L,Lu D P,et al.Effect of boron and cerium on corrosion resistance of Cu-Fe-P alloy[J].Journal of Materials Engineering and Performance,2016,25(3):1062-1067.
- [22] 李刚,肖来荣,赵小军,等.Cu-RE-B-Mg合金在无氧铜制备过程中的净化作用及机理分析[J].热加工工艺,2017(1):49-52.LI Gang,XIAO Lai-rong,ZHAO Xiao-jun,et al.Purification effect and mechanism analysis of Cu-RE-B-Mg alloy in the preparation of oxygen-free copper [J].Hot Working Technology,2017 (1):49-52.
- [23] 董旭刚,金青林,林波,等.微量硼对Cu-15Ni合金显微组织与力学性能的影响[J].铸造,2010(5):502-505.DONG Xu-gang,JIN Qing-lin,LIN Bo,et al.Effect of trace boron on microstructure and mechanical properties of Cu-15Ni alloy [J].Casting,2010(5):502-505
- [24] 陈晋,朱鸣芳,孙国雄.过冷熔体中的树枝晶分枝机制模拟[J].铸造,2005,54(9):895-898.CHEN Jin,ZHU Ming-fang,SUN Guo-xiong.Simulation of dendrite branching mechanism in undercooled melt [J].Casting,2005,54 (9):895-898.
- [25] 张丽萍,钱继锋,赵浩峰.钛硼合金元素对特殊铜合金性能的影响[J].山西机械,2000(3):14-15.ZHANG Li-ping,QIAN Ji-feng,ZHAO Hao-feng.Effect of Ti-B alloy elements on properties of special copper alloys [J].Shanxi Machinery,2000 (3):14-15.
- [26] 刘守法,周兆锋.第二相增强金属基复合材料研究进展[J].热加工工艺,2018,47(4):14-16.LIU Shou-fa,ZHOU Zhao-feng.Research progress of second phase reinforced metal matrix composites [J].Hot Working Technology,2018,47 (4):14-16.
- [27] 龚建森,胡诚立,齐龙浩,等.微量硼添加剂对铸造铜合金金相组织和机械性能的影响[J].湖南大学学报,1984(3):99-111.GONG Jian-sen,HU Cheng-li,QI Long-hao,et al.Effect of trace boron additive on microstructure and mechanical properties of cast copper alloy [J].Journal of Hunan University,1984 (3):99-111.
- [28] 夏承东,汪明朴,张婉,等.热轧淬火Cu-Cr系合金的性能和组织演变[J].中国有色金属学报,2012(8):2230-2237.XIA Cheng-dong,WANG Ming-pu,ZHANG Wan,et al.Properties and microstructure evolution of hot rolled quenched Cu-Cr alloys [J].Chinese Journal of Nonferrous Metals,2012(8):2230-2237.
- [29] 钟群鹏,赵子华,张峥.断口学的发展及微观断裂机理研究[J].机械强度,2005,27(3):358-370.ZHONG Qun-peng,ZHAO Zi-hua,ZHANG Zheng.The development of fractography and the study of micro-fracture mechanism [J].Mechanical Strength,2005,27(3):358-370.
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