含铌H13钢中一次碳氮化物生成机理及热稳定性Formation mechanism and thermal stability of primary carbonitrides in Nb-containing H13 tool steel
郝勇飞,成国光,谢有
摘要(Abstract):
对含铌0.051%的H13钢铸锭中一次碳氮化物成分特征及在1150℃、1250℃下的热稳定性进行了分析,并利用热力学软件Thermo-Calc对其形成机制进行了合理的解释。研究发现含铌0.051%的H13钢铸锭中存在3类一次碳氮化物,富Nb类、富V类以及富Mo-Cr类相。富Nb相热稳定性高,在1150℃及1250℃下保温6 h仍大量存在。富V相在1150℃下保温6 h仍然存在,而在1250℃下保温6 h即可完全固溶。富Mo-Cr相热稳定性低,无论是在1150℃还是1250℃下,均没有发现。这些相是在凝固过程中由于元素富集而在液相中析出。凝固过程中,富V的碳氮化物相首先析出,之后随着Nb含量的富集,富Nb的碳化物相开始析出,当Nb元素消耗到一定程度而同时V元素进一步富集后,富V的碳化物相再次析出,富Mo-Cr相在凝固末期最后析出。
关键词(KeyWords): H13钢;Nb;热稳定性;生成机理;Thermo-Calc
基金项目(Foundation): 高品质特殊钢(863)项目(2012AA03A503)
作者(Author): 郝勇飞,成国光,谢有
DOI: 10.13289/j.issn.1009-6264.2017.04.020
参考文献(References):
- [1]Rawal K,Priya A,Malik A,et al.Improvement of aluminum erosion behavior and corrosion resistance of AISI H13 tool steel by oxidation treatment[J].ISIJ International,2010,50(4):569-573.
- [2]Guimaraes J R C,Branco J R T,Kajita T.Partial substitution of niobium for vanadium in H-13 hot-work tool steel[J].Materials Science and Technology,1986,2(10):1074-1076.
- [3]Branco J R T,Krauss G.Alloy partitioning and grain growth control of H13 steel[C]//Proceeding of the 6th International Congress on Heat Treatment of Materials,Chicago:ASM,1988:195-199.
- [4]Elias C N,Viana C S D C.The effect of partial substitution of Nb for V on austenite grain size and hardness of a tool steel[J].Journal of Materials Engineering and Performance,1992,1(6):751-754.
- [5]Elias C N,Da Costa Viana C S.Effect of ausforming on microstructure and hardness of AISI H-13 tool steel modified with niobium[J].Materials Science and Technology,1992,8(9):785-790.
- [6]Maloney J L,Edwards W P,Rodney M S.Chromium hot work steel:US,5207843[P].1993-05-04.
- [7]Xie Y,Cheng G,Chen L,et al.The degeneration of the heterogeneous nucleation for the large precipitates(Ti,Nb,V)(C,N)in ESR H13+Nb tool steel with low-Mg O slag[J].Metallurgical Research&Technology,2016,113(2):1-12.
- [8]Xie Y,Cheng G G,Chen L,et al.Mechanism of generation of large(Ti,Nb,V)(C,N)-type precipitates in H13+Nb tool steel[J].International Journal of Minerals,Metallurgy and Materials,2016,23(11):1264-1274.
- [9]Xie Y,Cheng G G,Meng X L,et al.Precipitation behavior of primary precipitates in Ti-microalloyed H13 tool steel[J].ISIJ International,2016,56(11):1996-2005.
- [10]Xie Y,Cheng G G,Chen L,et al.Characteristics and generating mechanism of large precipitates in Nb-Ti-microalloyed H13 tool steel[J].ISIJ International,2016,56(6):995-1002.
- [11]谢有,成国光,陈列,等.H13热作模具钢大尺寸析出相特征及生成机理研究[J].中国冶金,2016,26(4):32-37.XIE You,CHENG Guo-guang,CHEN Lie,et al.Characteristics and generating mechanism of large precipitates in H13 tool steel[J].China Metallurgy,2016,26(4):32-37.
- [12]Shao X J,Wang X H,Jiang M,et al.Effect of heat treatment conditions on shape control of large-sized elongated Mn S inclusions in resulfurized freecutting steels[J].ISIJ International 2011,51(12):1995-2001.
- [13]Prikryl M,Kroupa A,Weatherly G C,et al.Precipitation behavior in a medium carbon,Ti-V-N microalloyed steel[J].Metallurgical and Materials Transactions A,1996,27(5):1149-1165.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||