超高温淬火对新型Fe-Cr-B-C合金硬度、冲击韧性和耐磨性能的影响Effect of ultra-high temperature quenching on hardness, impact toughness and wear resistance of a new Fe-Cr-B-C alloy
韩思莹,赵广迪,于镇铭,杜磊,王茜雯心,于江铖,王楚今,周艳文
摘要(Abstract):
Fe-Cr-B-C合金是一种低成本的高硼铁基耐磨合金,具有广阔的应用前景。研究了超高温淬火对一种成分优化的(B含量为0.51 mass%)Fe-Cr-B-C合金显微组织、硬度、冲击韧性和耐磨性能的影响。结果表明:当淬火温度为1100℃,合金基体内析出大量二次硼碳化物,降低了马氏体的过饱和度,同时形成了细小的新晶粒,原始网状硼碳化物发生局部断网,这导致其洛氏硬度最低,冲击吸收能量较高,耐磨性能最差;随着淬火温度升高至1160℃,不再析出二次硼碳化物,也不再形成新晶粒,硼碳化物的断网现象更加明显,而马氏体过饱和度不断增大,这导致洛氏硬度增大至(63.2±0.8) HRC,耐磨性能提高;当淬火温度继续升高至1190℃时,重新析出了大量[γ+(Fe, Cr)_2(B, C)]共晶组织并形成网状结构,导致洛氏硬度小幅下降,冲击韧性恶化,耐磨性能明显下降;合金的冲击吸收能量随淬火温度的升高先增大后减小,当淬火温度为1130℃时达到最大,为(4.25±0.25) J;综合来看,经1160℃淬火后Fe-Cr-B-C合金获得了良好的强韧性匹配和优异的耐磨性能,可作为其优选淬火温度。
关键词(KeyWords): Fe-Cr-B-C合金;超高温淬火;硬度;冲击韧性;耐磨性
基金项目(Foundation): 2025年辽宁科技大学大学生创新创业训练计划项目;; 辽宁省教育厅高校基本科研项目-面上项目(JYTMS20230943);; 国家自然科学基金(51904146)
作者(Author): 韩思莹,赵广迪,于镇铭,杜磊,王茜雯心,于江铖,王楚今,周艳文
DOI: 10.13289/j.issn.1009-6264.2025-0054
参考文献(References):
- [1] 王永林,李迎吉.TiN涂层在一般零件表面的摩擦磨损性能[J].装备制造技术,2017,45(12):143-145.WANG Yong-lin,LI Ying-ji.The friction and wear properties of TiN coating on the surface of the general parts[J].Equipment Manufacturing Technology,2017,45(12):143-145.
- [2] 魏世忠,徐流杰.钢铁耐磨材料研究进展[J].金属学报,2020,56(4):523-538.WEI Shi-zhong,XU Liu-jie.Review on research progress of steel and iron wear-resistant materials[J].Acta Metallurgica Sinica,2020,56(4):523-538.
- [3] 王春荣.硼系铁基耐磨铸造合金的组织与性能研究进展[J].热加工工艺,2013,42(12):11-13.WANG Chun-rong.Research progress on microstructure and properties of wear resistance boron cast iron[J].Hot Working Technology,2013,42(12):11-13.
- [4] 符寒光,胡开华.高硼铸造耐磨合金研究的进展[J].现代铸铁,2005,25(3):32-37.FU Han-guang,HU Kai-hua.Progress of research on high boron wear resistant cast alloys[J].Modern Cast Iron,2005,25(3):32-37.
- [5] 王楚今,于镇铭,赵广迪,等.淬火介质对Fe-Cr-B-C耐磨合金显微组织和强韧性的影响[J].辽宁科技大学学报,2024,47(5):321-329.WANG Chu-jin,YU Zhen-ming,ZHAO Guang-di,et al.Effect of quenching medium on the microstructure and strength-toughness of Fe-Cr-B-C wear-resistant alloy[J].Journal of University of Science and Technology Liaoning,2024,47(5):321-329.
- [6] 赵尚丽,张月霞,王守忠.铸造高强韧性 Fe-Cr-B-C 合金的试验研究[J].铸造,2019,68(9):977-981.ZHAO Shang-li,ZHANG Yue-xia,WANG Shou-zhong.Experimental study on high strength and toughness of Fe-Cr-B-C casting alloy[J].Foundry,2019,68(9):977-981.
- [7] 赵广迪,李阳,秦墨周,等.高硼铁基耐磨合金组织性能的研究进展[J].辽宁科技大学学报,2023,46(3):176-180.ZHAO Guang-di,LI Yang,QIN Mo-zhou,et al.Research progress on microstructure and properties of high boron iron-based wear-resistant alloy[J].Journal of University of Science and Technology Liaoning,2023,46(3):176-180.
- [8] 符寒光,宋绪丁,刘海明,等.热处理对Fe-B-C合金显微组织和性能的影响[J].稀有金属材料与工程,2010,39(6):1125-1128.FU Han-guang,SONG Xu-ding,LIU Hai-ming,et al.Effect of heat treatment on microstructures and properties of Fe-B-C alloy[J].Rare Metal Materials and Engineering,2010,39(6):1125-1128.
- [9] 顾建,符寒光,雷永平.热处理对Fe-5Cr-1.4B合金组织和性能的影响[J].现代铸铁,2013,33(4):78-84.GU Jian,FU Han-guang,LEI Yong-ping.Influence of heat treatment on structure and property of Fe-5Cr-1.4B alloy[J].Modern Cast Iron,2013,33(4):78-84.
- [10] 吴宪吉,宋元元,杨志荣,等.淬火温度对Fe-Cr-B-C合金涂层组织及硬度的影响[J].金属热处理,2022,47(10):224-227.WU Xian-ji,SONG Yuan-yuan,YANG Zhi-rong,et al.Influence of quenching temperature on microstructure and hardness of Fe-Cr-B-C alloy coating[J].Heat Treatment of Metals,2022,47(10):224-227.
- [11] 赵广迪,李阳,姚晓雨,等.B对Fe-Cr-B-C合金凝固行为、强韧性及耐磨性的影响[J].金属学报,2025,61(5):699-716.ZHAO Guang-di,LI Yang,YAO Xiao-yu,et al.Effect of boron on solidification behavior,strength-toughness,and wear resistance of Fe-Cr-B-C alloy[J].Acta Metallurgica Sinica,2025,61(5):699-716.
- [12] 李阳,赵广迪,臧喜民,等.B对Fe-Cr-B-C合金热处理后显微组织和强韧性的影响[J].特殊钢,2024,45(5):25-33.LI Yang,ZHAO Guang-di,ZANG Xi-min,et al.Effect of boron on the microstructure and strength toughness of Fe-Cr-B-C alloy after heat treatment[J].Special Steel,2024,45(5):25-33.
- [13] Elgallad E,Zhang Z,Chen X G.Effect of quenching rate on precipitation kinetics in AA2219 DC cast alloy[J].Physica B:Condensed Matter,2017,514:70-77.
- [14] 赵广迪,臧喜民,刘志超,等.淬火工艺对 A514CrQ 齿条钢显微组织演变及硬度的影响[J].特殊钢,2024,45(6):73-82.ZHAO Guang-di,ZANG Xi-min,LIU Zhi-chao,et al.Influence of quenching process on the microstructure evolution and hardness of A514CrQ rack steel[J].Special Steel,2024,45(6):73-82.
- [15] Dudko V,Belyakov A,Molodov D,et al.Microstructure evolution and pinning of boundaries by precipitates in a 9 pct Cr heat resistant steel during creep[J].Metallurgical and Materials Transactions A,2013,44:162-172.
- [16] Li Y,Liu S,Xue T,et al.Comparison of wear behavior of GCr15 bearing steel prepared by selective laser melting (SLM) and electron beam melting (EBM)[J].Materials Letters,1997,305:130726.
- [17] Huang X,Chaturvedi M,Richards N,et al.The effect of grain boundary segregation of boron in cast alloy 718 on HAZ microfissuring—A SIMS analysis[J].Acta Materialia,1997,45(8):3095-3107.
- [18] Mao M,Guo H,Wang F,et al.Effect of cooling rate on the solidification microstructure and characteristics of primary carbides in H13 steel[J].ISIJ International,2019,59(5):848-857.
- [19] Jackson M,Reed R.Heat treatment of UDIMET 720Li:the effect of microstructure on properties[J].Materials Science and Engineering A,1999,259(1):85-97.
- [20] 张占领,柳永宁,于光,等.超高碳钢中枣核状马氏体形态及亚结构[J].金属学报,2009,45(3):280-284.ZHANG Zan-ling,LIU Yong-guang,YU Guang,et al.Morphology and substructure of jujube-stone-like martensite in ultrahigh carbon steel[J].Acta Metallurgica Sinica,2009,45(3):280-284.
- [21] Zhao G,Yang G,Liu F,et al.Transformation mechanism of (γ + γ′) and the effect of cooling rate on the final solidification of U720Li alloy[J].Acta Metallurgica Sinica (English Letters),2017,30(9):887-894.
- [22] 周强,曹燕光,杨庚蔚,等.回火温度对700 MPa级大梁钢组织和性能的影响[J].钢铁,2023,58(10):102-110.ZHOU Qiang,CAO Yan-guang,YANG Geng-wei,et al.Effect of tempering temperature on microstructure and mechanical properties of 700 MPa grade beam steel[J].Iron & Steel,2023,58(10):102-110.
- [23] Gerold V,Haberkorn H.On the critical resolved shear stress of solid solutions containing coherent precipitates[J].Physica Status Solidi (B),1996,16(2):675-684.
- [24] Gladman T.Precipitation hardening in metals[J].Materials Science and Technology,1999,15(1):30-36.
- [25] 冀宣名,王礼榕,杨明,等.淬火-配分处理对30CrMnSiA钢冲击韧性的影响[J].材料科学与工艺,2024,32(3):18-28.JI Xuan-ming,WANG Li-rong,YANG Ming,et al.Effect of quenching and partitioning on the impact toughness of 30CrMnSiA steel[J].Materials Science and Technology,2024,32(3):18-28.
- [26] 王鑫,索忠源,王文革,等.热处理对ZGCr17Ni2马氏体不锈钢组织及硬度影响[J].特种铸造及有色合金,2019,39(9):940-942.WANG Xin,SUO Zhong-yuan,WANG Wen-ge,et al.Effects of heat treatment process on microstructure and hardness of ZGCr17Ni2 martensitic stainless steel[J].Special Casting & Nonferrous Alloys,2019,39(9):940-942.
- [27] 王智慧,万国力,贺定勇,等.Fe-Cr-B-C堆焊合金的组织与耐磨性[J].材料工程,2014,59(9):57-62.WANG Zhi-hui,WAN Guo-li,HE Ding-yong,et al.Microstructures and wear resistance of Fe-Cr-B-C hardfacing alloys[J].Journal of Materials Engineering,2014,59(9):57-62.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||