纳米多孔NiFeCoTi高熵合金电极的析氢反应性能Hydrogen evolution reaction performance of nanoporous NiFeCoTi high-entropy alloy electrode
孙新滢,时航,郎兴友,蒋青
摘要(Abstract):
开发高效、稳定的电催化剂用于电化学水分解制氢至关重要。通过合金化和脱合金化法制备了纳米多孔NiFeCoTi高熵合金电极,并对其碱性析氢反应性能进行了研究。结果表明:该电极具有柱状纳米多孔结构,能够促进电催化反应过程中的电子传递和质量运输,表面的NiFeCoTi高熵合金可以提供双功能的电催化活性位点,促进水的解离和氢中间体的吸附/结合。在1 M KOH电解液中,纳米多孔NiFeCoTi电极在~111 mV的过电位下就能够达到400 mA/cm~2的电流密度,具有较低的Tafel斜率和优异的长期稳定性。
关键词(KeyWords): 高熵合金;电催化剂;纳米多孔金属;析氢反应
基金项目(Foundation): 国家自然科学基金(52201217,52271217,52130101)
作者(Author): 孙新滢,时航,郎兴友,蒋青
DOI: 10.13289/j.issn.1009-6264.2023-0510
参考文献(References):
- [1] Stamenkovic V R,Strmcnik D,Lopes P P,et al.Energy and fuels from electrochemical interfaces[J].Nature Materials,2017,16(1):57-69.
- [2] Tiwari J N,Dang N K,Sultan S,et al.Multi-heteroatom-doped carbon from waste-yeast biomass for sustained water splitting[J].Nature Sustainability,2020,3(7):556-563.
- [3] 贾飞宏,郭宇晨,邹祥宇,等.Ni3S2@NiCe-LDH/NF电极的电催化析氧行为[J].材料热处理学报,2023,44(10):78-86.JIA Fei-hong,GUO Yu-chen,ZOU Xiang-yu,et al.Electrocatalytic oxygen evolution behavior of Ni3S2@NiCeLDH/NF electrode[J].Transactions of Materials and Heat Treatment,2023,44(10):78-86.
- [4] Zhu J,Hu L S,Zhao P X,et al.Recent advances in electrocatalytic hydrogen evolution using nanoparticles[J].Chemical Reviews,2020,120(2):851-918.
- [5] Li L G,Wang P T,Shao Q,et al.Metallic nanostructures with low dimensionality for electrochemical water splitting[J].Chemical Society Reviews,2020,49(10):3072-3106.
- [6] Chatenet M,Pollet B G,Dekel D R,et al.Water electrolysis:from textbook knowledge to the latest scientific strategies and industrial developments[J].Chemical Society Reviews,2022,51(11):4583-4762.
- [7] Jiao S L,Fu X W,Wang S Y,et al.Perfecting electrocatalysts via imperfections:towards the large-scale deployment of water electrolysis technology[J].Energy & Environmental Science,2021,14(4):1722-1770.
- [8] Yu Z Y,Duan Y,Feng X Y,et al.Clean and affordable hydrogen fuel from alkaline water splitting:past,recent progress,and future prospects[J].Advanced Materials,2021,33(31):2007100.
- [9] Wang J,Gao Y,Kong H,et al.Non-precious-metal catalysts for alkaline water electrolysis:Operando characterizations,theoretical calculations,and recent advances[J].Chemical Society Reviews,2020,49(24):9154-9196.
- [10] Li P,Jiang Y L,Hu Y C,et al.Hydrogen bond network connectivity in the electric double layer dominates the kinetic pH effect in hydrogen electrocatalysis on Pt[J].Nature Catalysis,2022,5(10):900-911.
- [11] Ma Y J,Ma Y,Wang Q,et al.High-entropy energy materials:challenges and new opportunities[J].Energy & Environmental Science,2021,14(5):2883-2905.
- [12] Li H,Zhu H,Zhang S G,et al.Nano high-entropy materials:Synthesis strategies and catalytic applications[J].Small Structures,2020,1(2):2000033.
- [13] Hao J C,Zhuang Z C,Cao K C,et al.Unraveling the electronegativity-dominated intermediate adsorption on high-entropy alloy electrocatalysts[J].Nature Communication,2022,13(1):2662.
- [14] Sun Y F,Dai S.High-entropy materials for catalysis:A new frontier[J].Science Advances,2021,7(20):1600.
- [15] Jia Z,Yang T,Sun L G,et al.A novel multinary intermetallic as an active electrocatalyst for hydrogen evolution[J].Advanced Materials,2020,32(21):2000385.
- [16] Zhai Y Y,Ren X R,Wang B L,et al.High-entropy catalyst-A novel platform for electrochemical water splitting[J].Advanced Function Materials,2022,32(47):2207536.
- [17] Li H D,Lai J P,Li Z J,et al.Multi-sites electrocatalysis in high-entropy alloys[J].Advanced Function Materials,2021,31(47):2106715.
- [18] Shi H,Zhou Y T,Yao R Q,et al.Spontaneously separated intermetallic Co3Mo from nanoporous copper as versatile electrocatalysts for highly efficient water splitting[J].Nature Communication,2020,11(1):2940.
- [19] Yao R Q,Zhou Y T,Shi H,et al.Nanoporous surface high-entropy alloys as highly efficient multisite electrocatalysts for nonacidic hydrogen evolution reaction[J].Advanced Functional Materials,2020,31(10):2009613.
- [20] Nakaya Y,Hayashida E,Asakura H,et al.High-entropy intermetallics serve ultrastable single-atom Pt for propane dehydrogenation[J].Journal of the American Chemical Society,2022,144(35):15944-15953.
- [21] He Z Y,Zhang J,Gong Z H,et al.Activating lattice oxygen in NiFe-based (oxy) hydroxide for water electrolysis[J].Nature Communication,2022,13(1):2191.
- [22] Ge Y Z,Qin X T,Li A W,et al.Maximizing the synergistic effect of CoNi catalyst on α-MoC for robust hydrogen production[J].Journal of the American Chemical Society,2021,143(2):628-633.
- [23] Zang W J,Sun T,Yang T,et al.Efficient hydrogen evolution of oxidized Ni-N3 defective sites for alkaline freshwater and seawater electrolysis[J].Advanced Materials,2021,33(8):2003846.
- [24] Huang C Q,Zhou Q C,Duan D S,et al.The rapid self-reconstruction of Fe-modified Ni hydroxysulfide for efficient and stable large-current-density water/seawater oxidation[J].Energy & Environmental Science,2022,15(11):4647-4658.
- [25] Lu Q,Hutchings G S,Yu W T,et al.Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution[J].Nature Communication,2015,6:6567.
- [26] Geng B,Yan F,Zhang X,et al.Conductive CuCo-based bimetal organic framework for efficient hydrogen Evolution[J].Advanced Materials,2021,33(49):2106781.
- [27] Jiang H,Sun M Z,Wu S L,et al.Oxygen-incorporated NiMoP nanotube arrays as efficient bifunctional electrocatalysts for urea-assisted energy-saving hydrogen production in alkaline electrolyte[J].Advanced Function Materials,2021,31(43):2104951.
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