可热处理铝锂合金专利技术分析Analysis of heat-treatable Al-Li alloy patents
王姝婷,杨兴海,王俊升,薛程鹏,王硕,苗以升
摘要(Abstract):
可热处理强化铝锂合金密度低、强度高、刚度好,作为航空航天结构材料而备受关注。但是,其生产制备技术难度大、良品率低、成本高,使其工业化大规模生产工艺要求比传统铝合金更高,需大量的技术积淀。在世界范围内,可热处理强化铝锂合金申报专利数量和质量,显示了一个国家的制造水平。因此,本文综述了铝锂合金专利技术的发展,比较了我国专利与欧美国家专利技术的差异,分析了各自的发展特色。发现,我国近10年在铝锂合金领域的专利申请数量已经处于世界领先,但在原型合金成分、专利转化等方面依然有待进一步的提升。
关键词(KeyWords): 铝锂合金;专利创新;合金设计;热处理
基金项目(Foundation): 国家自然科学基金面上项目(52073030);; 国家自然科学基金区域创新联合基金重点项目(U20A20276)
作者(Author): 王姝婷,杨兴海,王俊升,薛程鹏,王硕,苗以升
DOI: 10.13289/j.issn.1009-6264.2023-zt06
参考文献(References):
- [1] 李红萍,叶凌英,邓运来,等.航空铝锂合金研究进展[J].中国材料进展,2016,35(11):856-862.LI Hong-ping,YE Ling-ying,DENG Yun-lai,et al.Progress of aerocraft Al-Li alloys[J].Materials China,2016,35(11):856-862.
- [2] Rioja R J,Liu J.The evolution of Al-Li base products for aerospace and space applications[J].Metallurgical and Materials Transactions A,2012,43(9):3325-3337.
- [3] Rioja R J.Fabrication methods to manufacture isotropic Al-Li alloys and products for space and aerospace applications[J].Materials Science and Engineering A,1998,257(1):100-107.
- [4] Decreus B,Deschamps A,Geuser F D,et al.The influence of Cu/Li ratio on precipitation in Al-Cu-Li-x alloys[J].Acta Materialia,2013,61(6):2207-2218.
- [5] Gumbmann E,Lefebvre W,Geuser F D,et al.The effect of minor solute additions on the precipitation path of an Al-Cu-Li alloy[J].Acta Materialia,2016,115:104-114.
- [6] 赵云鹏,曾福明,周志勇,等.新型铝合金的发展及其在密封舱结构上的工程应用[J].载人航天,2016,22(3):302-307.ZHAO Yun-peng,ZENG Fu-ming,ZHOU Zhi-yong,et al.Development and potential applications of advanced aluminum alloy in spacecraft pressurized cabin[J].Manned Spaceflight,2016,22(3):302-307.
- [7] Wang S,Xue C P,Yang X H,et al.Structural ordering governs stiffness and ductile-to-brittle transition in Al-Li alloys[J].The Journal of Chemical Physics,2023,158(10):104303.
- [8] Wang S,Xue C P,Yang X,et al.Solute clustering governed elastic properties in aluminum[J].Calphad,2022,79:102494.
- [9] Wang S,Wang J S,Zhang C,et al.Continuous precipitate modes of the δ′-Al3Li phase in Al-Li alloys[J].Journal of Alloys and Compounds,2022,904:163800.
- [10] Wang S,Xue C,Yang X,et al.Heterogeneous nucleation of T1 precipitates in solid solution of Al-Cu-Li alloys from Ag-rich structures:An ab initio study[J].Scripta Materialia,2023,225:115191.
- [11] Wang S,Yang X H,Wang J S,et al.Identifying the crystal structure of T1 precipitates in Al-Li-Cu alloys by ab initio calculations and HAADF-STEM imaging[J].Journal of Materials Science & Technology,2023,133:41-57.
- [12] Williams J C,Starke Jr E A.Progress in structural materials for aerospace systems[J].Acta Materialia,2003,51(19):5775-5799.
- [13] 杜康,王军强,曹海龙,等.航空航天用铝锂合金研究进展及发展趋势[J].铝加工,2022(2):3-9.DU Kang,WANG Jun-qiang,CAO Hai-long,et al.Research progress and development trend of Al-Li alloys for aerospace applications[J].Aluminium Fabrication,2022(2):3-9.
- [14] 王俊升,杨兴海,田光元,等.一种低密度高强高弹性模量的铝锂合金及制备方法:CN113981280B[P].2022-05-17.WANG Jun-sheng,YANG Xing-hai,TIAN Guang-yuan,et al.Aluminum-lithium alloy with low density,high strength and high elastic modulus and preparation method:CN113981280B[P].2022-05-17.
- [15] Yang X H,Wang J S,Zhang M S,et al.Achieving high strength and ductility of Al-Cu-Li alloy via creep aging treatment with different pre-strain levels[J].Materials Today Communications,2021,29:102898.
- [16] Yang X H,Wang J S,Xue C P,et al.Accelerating the precipitation kinetics of nano-sized T1 and S′ phases in Al-Cu-Li alloys by hot-deformation and creep-aging[J].Philosophical Magazine,2023,103:1-41.
- [17] 雷正龙,付伟杰,张新瑞,等.一种消除铝锂合金T型接头激光焊接气孔的方法:CN112475602 B[P].2022-06-28.LEI Zheng-long,FU Wei-jie,ZHANG Xin-rui,et al.A method for eliminating air holes in laser welding of Al-Li alloy T-joints:CN112475602 B[P].2022-06-28.
- [18] 张琪,张庆东,叶鹏程,等.基于专利分析的中国铝锂合金创新态势研究[J].铝加工,2021(1):3-7.ZHANG Qi,ZHANG Qing-dong,YE Peng-cheng,et al.Patent-based analysis of China’s Al-Li alloy innovation situation[J].Aluminium Fabrication,2021(1):3-7.
- [19] 王祝堂.世界铝-锂合金工业概要及中国与它们的差距[J].轻金属,2016(10):1-6.WANG Zhu-tang.Summary on Al-Li alloys industry in the world and difference of Chinese Al-Li alloys industry[J].Light Metals,2016(10):1-6.
- [20] 吴秀亮,刘铭,臧金鑫,等.铝锂合金研究进展和航空航天应用[J].材料导报,2016,30(S2):571-578.WU Xiu-liang,LIU Ming,ZANG Jin-xin,et al.Research progress and aerospace application of aluminum lithium alloys[J].Materials Reports,2016,30(S2):571-578.
- [21] 王浩军,史春玲,贾志强,等.铝锂合金的发展及研究现状[J].热加工工艺,2012,41(14):82-85.WANG Hao-jun,SHI Chun-ling,JIA Zhi-qiang,et al.Development and current status of aluminum-lithium alloy[J].Hot Working Technology,2012,41(14):82-85.
- [22] 吴国华,孙江伟,张亮,等.铝锂合金材料研究应用现状与展望[J].有色金属科学与工程,2019,10(2):31-46.WU Guo-hua,SUN Jiang-wei,ZHANG Liang,et al.Current status and prospects of research and application of aluminum-lithium alloy[J].Nonferrous Metals Science and Engineering,2019,10(2):31-46.
- [23] Arconic Tech Llc.2xxx aluminum lithium alloys:US20210404038(A1)[P].2021-12-30.
- [24] 王俊升,杨兴海,田光元,等.一种微量元素复合强化高强度铝锂合金及制备方法:CN114540679B[P].2022-04-26.WANG Jun-sheng,YANG Xing-hai,TIAN Guang-yuan,et al.A kind of trace element composite strengthening high-strength aluminum-lithium alloy and preparation method thereof:CN114540679B[P].2022-04-26.
- [25] 李晓谦,蒋日鹏,张立华,等.一种超声波辅助铸造装置及制造铝锂合金的方法:CN110284030B[P].2020-08-04.LI Xiao-qian,JIANG Ri-peng,ZHANG Li-hua,et al.Ultrasonic assisted casting device and method for manufacturing aluminum-lithium alloy:CN110284030B[P].2020-08-04.
- [26] 李建宇,吴树森,郭威,等.一种外加纳米颗粒增强铸造铝锂合金的制备方法:CN114672686B[P].2022-10-28.LI Jian-yu,WU Shu-sen,GUO Wei,et al.Preparation method of additional nano-particle reinforced cast aluminum-lithium alloy:CN114672686B[P].2022-10-28.
- [27] 马芳,张捷,张豪,等.一种大规格喷射成形高强铝锂合金的制备方法:CN115418509A[P].2022-12-02.MA Fang,ZHANG Jie,ZHANG Hao,et al.Preparation method of large-size spray-formed high-strength aluminum-lithium alloy:CN115418509A[P].2022-12-02.
- [28] 王俊升,杨兴海,田光元,等.一种高比强度、比刚度铝锂合金厚壁环形件及其制备方法:CN114058912B[P].2022-01-17.WANG Jun-sheng,YANG Xing-hai,TIAN Guang-yuan,et al.High-specific-strength and high-specific-stiffness aluminum-lithium alloy thick-wall annular piece and preparation method thereof:CN114058912B[P].2022-01-17.
- [29] 王俊升,杨兴海,张明山,等.一种应力时效态高强铝锂合金的制备方法:CN112981284B[P].2021-02-09.WANG Jun-sheng,YANG Xing-hai,ZHANG Ming-shan,et al.A kind of preparation method of stress aging state high-strength aluminum-lithium alloy:CN112981284B[P].2021-02-09.
- [30] 李红英,鲍新涵,赵公澍,等.一种铝锂合金及其热处理工艺:CN114561578A[P].2022-05-31.LI Hong-ying,BAO Xin-han,ZHAO Gong-shu,et al.Aluminum-lithium alloy and heat treatment process thereof:CN114561578A[P].2022-05-31.
- [31] 王俊升,薛程鹏,郭跃岭,等.一种电弧增材制造铝锂合金缺陷和组织控制的方法:CN112593169B[P].2020-12-16.WANG Jun-sheng,XUE Cheng-peng,GUO Yue-ling,et al.A method for arc additive manufacturing of aluminum-lithium alloy defect and structure control:CN112593169B[P].2020-12-16.
- [32] Xue C P,Zhang Y X,Mao P C,et al.Improving mechanical properties of wire arc additively manufactured AA2196 Al-Li alloy by controlling solidification defects[J].Additive Manufacturing,2021,43:102019.
- [33] 王少刚,谢美蓉.改善铝锂合金焊缝成形和提高接头质量的电子束焊接工艺:CN110653477A[P].2020-01-07.WANG Shao-gang,XIE Mei-rong.Electron beam welding technology improving aluminum-lithium alloy weld formation and improving joint quality:CN110653477A[P].2020-01-07.
- [34] 刘志鹏,肖阳,马凯杰,等.一种铝锂合金废料废屑再生回收方法:CN111893335B[P].2021-09-28.LIU Zhi-peng,XIAO Yang,MA Kai-jie,et al.Method for recycling aluminum-lithium alloy waste scraps:CN111893335B[P].2021-09-28.
- [35] 于以标,陈乐平,徐勇.高性能铝锂合金的研究进展及其应用[J].铸造技术,2020,41(7):687-692.YU Yi-biao,CHEN Le-ping,XU Yong.Research progress and application of high-performance aluminum-lithium alloy[J].Foundry Technology,2020,41(7):687-692.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||