渗硼对Ti(C,N)基金属陶瓷组织和性能的影响Effect of boronizing on microstructure and properties of Ti(C,N)-based cermet
詹斌,刘宁,李彬彬,刘爱军,唐慧兰
摘要(Abstract):
采用粉末冶金法制备了纳米改性Ti(C,N)基金属陶瓷,并用固体粉末法对其进行了渗硼处理。研究了渗硼处理对Ti(C,N)基金属陶瓷微观组织以及抗弯强度和硬度的影响。结果表明:渗硼处理使Ti(C,N)基金属陶瓷中生成了CoB、TiB2、MoB2和石墨相。金属陶瓷的渗硼层由硼化物层、扩散层和基体区组成,厚度为100~140μm。硼化物层主要由CoB组成,扩散层含有较多孔隙,基体区存在富硼的渗硼影响区,影响区具有与Ti(C,N)基金属陶瓷近似的微观组织,但金属相含量较少。渗硼处理使Ti(C,N)基金属陶瓷的抗弯强度降低,主要是由材料中产生的热应力、组织应力以及组织变化引起的。Ti(C,N)基金属陶瓷的表面硬度提高48.7%。在由渗硼层表面向内部100~140μm范围内,硬度呈下降趋势。
关键词(KeyWords): Ti(C,N)基金属陶瓷;渗硼;组织;力学性能
基金项目(Foundation): 安徽省自然科学基金项目(090414185)
作者(Author): 詹斌,刘宁,李彬彬,刘爱军,唐慧兰
DOI: 10.13289/j.issn.1009-6264.2012.08.028
参考文献(References):
- [1]Ettmayer P,Lengauer W.The story of cermets[J].Powder Metallurgy International,1989,21:37-38.
- [2]Zackrisson J,Thuvander M,Lindahl P,et al.Atom probe analysis of carbonitride grains in(Ti,W,Ta,Mo)(C,N)(Co/Ni)cermets withdifferent carbon content[J].Applied Surface Science,1996,94-95:351-355.
- [3]Ettmayer P,Kolaska H,Lengauer W,et al.Ti(C,N)cermets-metallurgy and properties[J].International Journal of Refractory Metals and HardMaterials,1995,13(6):343-351.
- [4]Liu N,Chao S,Yang H D.Cutting performances,mechanical property and microstructure of ultra-fine grade Ti(C,N)-based cermets[J].International Journal of Refractory Metals and Hard Materials,2006,24(6):445-452.
- [5]Liu N,Han C L,Yang H D,et al.The milling performances of TiC-based cermet tools with TiN nanopowders addition against normalized mediumcarbon steel AISI1045[J].Wear,2005,258(11-12):1688-1695.
- [6]尤显卿,宋雪峰.WC/钢复合材料渗硼中WC颗粒对硼化物生长的影响[J].材料热处理学报,2006,27(3):121-126.YOU Xian-qing,SONG Xue-feng.Effect of WC particles to the growth of borides during boronizing of WC/steel composites[J].Transactions ofMaterials and Heat Treatment,2006,27(3):121-126.
- [7]Mu D,Shen B L,Zhao X.Effects of boronizing on mechanical and dry-sliding wear properties of CoCrMo alloy[J].Materials&Design,2010,31(8):3933-3936.
- [8]Sen S,Sen U,Bindal C.The growth kinetics of borides formed on boronized AISI 4140 steel[J].Vacuum,2005,77(2):195-202.
- [9]Usta M,Ozbek I,Bindal C,et al.A comparative study of borided pure niobium,tungsten and chromium[J].Vacuum,2006,80(11-12):1321-1325.
- [10]Chao S,Liu N,Yuan Y P,et al.Microstructure and mechanical properties of ultrafine Ti(CN)-based cermets fabricated from nano/submicronstarting powders[J].Ceramics International,2005,31(6):851-862.
- [11]Chen H C,Pfender E,Heberlein J.Structural changes in plasma-sprayed ZrO2 coatings after hot isostatic pressing[J].Thin Solid Films,1997,293:227-235.
- [12]袁庆龙,曹晶晶.45钢渗硼工艺对渗层组织与性能的影响[J].热加工工艺,2010,39(2):134-136.YUAN Qing-long,CAO Jing-jing.Effect of boronization technology on microstructure and properties of boronizing layer on 45 steel[J].Hot WorkingTechnology,2010,39(2):134-136.
- [13]胡三媛,徐方超,李长林,等.YG6硬质合金渗硼层厚度对抗弯强度的影响[J].中国农业大学学报,2003,8(6):45-47.HU San-yuan,XU Fang-chao,LI Chang-lin,et al.Effect of the boronizing thickness of YG6 hard alloy on bending strength[J].Journal of ChinaAgricultural University,2003,8(6):45-47.
- [14]张焱,尤显卿,夏学生,等.电冶钢结硬质合金的渗硼研究[J].热处理,2007,22(4):27-31.ZHANG Yan,YOU Xian-qing,XIA Xue-sheng,et al.Boronizing for eleclro-metallurgical steel bonded carbide[J].Heat Treatment,2007,22(4):27-31.
- [15]章为夷.固体渗硼时硼砂型渗剂中活性硼原子输运方式研究[J].材料热处理学报,2003,24(2):29-32.ZHANG Wei-yi.Study on the transfer ways of activated boron atoms in the borax pack boronizing agent during boronizing[J].Transactions of MetalHeat Treatment,2003,24(2):29-32.
- [16]黄拿灿,林福曾,朱海泉,等.钴及钴基合金的渗硼和硼硅共渗强化[J].金属热处理,1987(6):10-16.HUANG Na-can,LIN Fu-zeng,ZHU Hai-quan,et al.Boronization and boron-siliconization of the cobalt and cobalt base alloy[J].Heat Treatmentof Metals,1987(6):10-16.
- [17]饶孝权,刘兆年.YG8硬质合金渗硼层组织和性能的分析[J].金属热处理学报,1994,15(3):55-60.RAO Xiao-quan,LIU Zhao-nian.Analysis on microstructure and property of boronized layer of YG8 hard alloy[J].Transactions of Metal HeatTreatment,1994,15(3):55-60.
- [18]Mu D,Yang C,Shen B L,et al.Oxidation resistance of borided pure cobalt[J].Journal of Alloys and Compounds,2009,479(1-2):629-633.
- [19]尤显卿.WC-钢复合材料渗硼层的组织结构[J].兵器材料科学与工程,1992,15(11):37-42.YOU Xian-qing.Microstructure of boronized layer on WC-steel composite material[J].Ordnance Material Science and Engineering,1992,15(11):37-42.
- [20]黄培云.粉末冶金原理[M].北京:冶金工业出版社,2006.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||