Gd含量对Mg-0.5Zn-0.4Zr-xGd生物镁合金性能的影响Effects of Gd content on properties of Mg-0.5Zn-0.4Zr-x Gd biodegradable magnesium alloys
单玉郎,文九巴,姚怀,贺俊光,雷少帆
摘要(Abstract):
研究了稀土元素Gd含量对铸态Mg-0.5Zn-0.4Zr-x Gd合金微观组织、力学性能及其腐蚀性能的影响。结果表明:当Gd含量小于5%时,随着Gd含量的提高,第二相沿着晶界析出并且逐渐增多,晶粒明显细化,力学性能和耐蚀性逐渐提高;Gd含量为5%时,合金的力学性能及耐蚀性最好,抗拉强度为174.76 MPa,伸长率为11.25%,平均腐蚀速率仅为0.845 mm/a。Gd含量继续增加,合金力学性能和耐蚀性均呈现劣化趋势。
关键词(KeyWords): 生物镁合金;稀土;耐蚀性
基金项目(Foundation): 河南省“新型有色金属材料”高校科技创新团队支持计划(2012IRTSTHN008);; 河南省教育厅重点项目(15A430024)
作者(Author): 单玉郎,文九巴,姚怀,贺俊光,雷少帆
DOI: 10.13289/j.issn.1009-6264.2016.06.004
参考文献(References):
- [1]Sayuri Yoshizawa,Amy Chaya,Kostas Verdelis,et al.An in vivo model to assess magnesium alloys and their biological effect on human bone marrow stromal cells[J].Acta Biomaterialia,2015,28(2):234-239.
- [2]Hort N,Huang Y,Fechner D,et al.Magnesium alloys as implant materials-principles of property design for Mg-RE alloys[J].Acta Biomaterialia,2010,6(5):1714-1725.
- [3]Kaabi S,Falanhieh Asl,Nemeth S,et al.Electrophoretic deposition of hydroxyapatite coatings on AZ31 magnesium substrate for biodegradable implant applications[J].Progress in Crystal Growth and Characterization of Materials,2014,60(3):74-79.
- [4]Anja C Hanzi,Petra Gunde,Michael Schinhammer,et al.On the biodegradation performance of an Mg-Y-RE alloy with various surface conditions in simulated body fluid[J].Acta Biomaterialia,2009,5(1):162-171.
- [5]HE Zong-ling,FU Peng-huai,WU Yu-juan,et al.High cycle fatigue behavior of as-cast Mg96.34Gd2.5Zn1Zr0.16 alloy fabricated by semi-continuous casting[J].Materials Science and Engineering A,2013,587(2):72-78.
- [6]ZHANG Xiao-bo,YUAN Guang-yin,MAO Lin,et al.Biocorrosion properties of as-extruded Mg-Nd-Zn-Zr alloy compared with commercial AZ31 and WE43 alloys[J].Materials Letters,2012,66(1):209-211.
- [7]ZHANG Xiao-bo,WU Yu-juan,XUE Ya-jun,et al.Biocorrosion behavior and cytotoxicity of a Mg-Gd-Zn-Zr alloy with long period stacking ordered structure[J].Materials Letters,2012,86(1):42-45.
- [8]WEN Li-hua,JI Ze-sheng,LI Xiao-liang,et al.Effect of extrusion ratio on microstructure and mechanical properties of Mg-Nd-Zn-Zr alloys prepared by a solid recycling process[J].Materials Characterization,2008,59(11):1655-1660.
- [9]Apps P J,Karimzadeh H,King J F,et al.Precipitation reactions in magnesium-rare earth alloys containing yttrium,gadolinium or dysprosium[J].Scripta Mater 2003,48(8):1023-1028.
- [10]章晓波,袁广银,王章忠.铸造镁合金Mg-Nd-Zn-Zr的生物腐蚀性能[J].中国有色金属学报,2013(4):905-911.ZHANG Xiao-bo,YUAN Guang-yin,WANG Zhang-zhong.Biocorrosion properties of as-cast Mg-Nd-Zn-Zr magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2013(4):905-911.
- [11]袁广银,章晓波,牛佳林,等.新型可降解生物医用镁合金JDBM的研究进展[J].中国有色金属学报,2011,21(10):2476-2489.YUAN Guang-yin,ZHANG Xiao-bo,NIU Jia-lin,et al.Research progress of new type of degradable biomedical magnesium alloys JDBM[J].The Chinese Journal of Nonferrous Metals,2011,21(10):2476-2489.
- [12]Srinivasan A,Blawert C,Huang Y,et al.Corrosion behavior of Mg-Gd-Zn based alloys in aqueous Na Cl solution[J].Journal of Magnesium and Alloys,2014,2(3):245-256.
- [13]Ng W F,Chiu K Y,Cheng F T.Effect of p H on the vitro corrosion rate of magnesium degradable implant material[J].Materials Science and Engineering C,2010,30(6):898-903.
- [14]Peng Q,Wang J,Wu Y,et al.Microstructures and tensile properties of Mg-8Gd-0.6Zr-x Nd-y A(x+y=3,mass%)alloys[J].Marerials Science and Engineering A,2006,433:133-138.
- [15]Jitka Pelcova,Bohumil Smola,Ivana Stulikova.Influence of processing technology on phase transformations in a rare-earth-containning Mg-Zn-Zr alloy[J].Marerials Science and Engineering A,2007,462:334-338.
- [16]SONG Guang-ling.Control of biodegradation of biocompatible magnesium alloys[J].Corrosion Science,2007(49):1696-1701.
- [17]Lu F M,Ma A B,Jiang J H,et al.Formation of profuse long period stacking ordered microcells in Mg-Gd-Zn-Zr alloy during multipass ECAP process[J].Journal of Alloys and Compounds,2014,601(7):140-145.
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