等温热处理对Mg-6Zn-3Cu合金半固态组织演变的影响Effects of isothermal heat treatment on microstructural evolution of Mg-6Zn-3Cu alloy
黄晓锋,张玉,秦牧岚,郝远
摘要(Abstract):
通过半固态等温热处理,研究了重熔温度和保温时间对铸造ZC63镁合金半固态组织演变的影响。结果表明:半固态等温热处理能够将ZC63合金中的枝晶组织转变为球状组织,并可获得更加细小、分布均匀的球状颗粒;重熔温度和保温时间对非枝晶组织演变有着重要的影响,提高保温温度或延长保温时间,可加快原始铸锭重熔进程及组织形态的优化,保温温度过高或保温时间过长,试样会发生严重变形,同时球状颗粒易于粗化和长大;非枝晶组织演变是在熔化和结晶的动态变化中完成,主要的演变机制是在等温热处理过程中晶界处的共晶组织向基体溶解,原始组织的粗化、分离、球化以及球状颗粒的合并与长大。ZC63合金半固态触变成形最适合的等温热处理工艺是600℃×30 min。
关键词(KeyWords): ZC63镁合金;半固态等温热处理;非枝晶组织;演变机理
基金项目(Foundation): 国家自然科学基金(51464032);; 国家973计划(2010CB635106)
作者(Author): 黄晓锋,张玉,秦牧岚,郝远
DOI: 10.13289/j.issn.1009-6264.2016.08.010
参考文献(References):
- [1]Deker R F.The renaissance in magnesium[J].Advanced Materials&Process,1998,98:31-33.
- [2]MORDIKE B L,EBERT T.Magnesium properties applications potential[J].Materials Sciences and Engineering A,2001,302(1):37-45.
- [3]Buha J.Characterisation of precipitates in an aged Mg-Zn-Ti[J].Journal of Alloys and Compounds,2009,472:171-177.
- [4]黄巍,李荻.300℃等温处理时间对AZ91D压铸镁合金组织和性能的影响[J].材料热处理学报,2006,27(2):37-41HUANG Wei,LI Di.Effects of isothermal treatment time on Microstructure and properties of AZ91D die cast magnesium alloy at 300℃[J].Transactions of Materials and Heat Treatment,2006,27(2):37-41.
- [5]Flemings M C.Behavior of metal alloys in the semi-solid state[J].Metallurgical Transactions A,1991,22(5):957-981.
- [6]FAN Z.Semisolid metal processing[J].International Materials Reviews,2002,47(2):49-85.
- [7]Nussbaum A I.Semi-solid forming of aluminum and magnesium[J].Light Metal Age,1996,19(6):6-22.
- [8]毛卫民.半固态金属成形技术[M].北京:机械工业出版社,2004.
- [9]FAN Z,LIU G,WANG Y.Microstructure and mechanical properties of rheo-die cast AZ91D magnesium alloy[J].Journal of Materials Science,2006,41(12):3631-3644.
- [10]路贵民,董杰,崔建忠,等.液相线半连续铸造7075Al合金二次加热与触变成形[J].金属学报,2001,37(11):1185-1188.LU Gui-min,DONG Jie,CUI Jian-zhong,et al.Study on the reheating and thixoforming of 7075 aluminum alloy cast by liquidus semi-continuous casting[J].Acta Metallurgica Sinica,2001,37(11):1185-1188.
- [11]Hardy S C,Voorhees P W.Ostwald ripening in system with high volume fraction of coarsening phase[J].Met Trans A,1988,19(11):2713-2721.
- [12]李元东,郝远,陈体军,等.等温热处理工艺对AZ91D镁合金半固态组织演变和成形性的影响[J].中国有色金属学报,2002,12(6):1143-1148.LI Yuan-dong,HAO Yuan,CHEN Ti-jun,et al.Effects of isothermal heat treatment on microstructure evolution and forming of AZ91D magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2002,12(6):1143-1148.
- [13]麻彦龙,左汝林,汤爱涛,等.ZK60镁合金铸态显微组织分析[J].重庆大学学报,2004,27(8):52-56.MA Yan-long,ZUO Ru-lin,TANG Ai-tao,et al.Analysis of microstructure of as-cast ZK60 magnesium alloy[J].Journal of Chongqing University,2004,27(8):52-56.
- [14]李爱文,刘江文,伍翠兰,等.Cu含量对铸造Mg-3Zn-xC u-0.6Zr镁合金时效析出行为的影响[J].中国有色金属学报,2010,20(8):1487-1494.LI Ai-wen,LIU Jiang-wen,WU Cui-lan,et al.Effects of Cu addition on aging precipitation behavior of cast Mg-3Zn-xC u-0.6Zr magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2010,20(8):1487-1494.
- [15]刘伟,张英波,李彬,等.半固态等温处理Mg-Zn-Y合金微观组织演变[J].稀有金属材料与工程,2015,44(12):3243-3247.LIU Wei,ZHANG Ying-bo,LI Bin,et al.Semi-solid isothermal heat treatment Mg-Zn-Y on alloy microstructural evolution[J].Rare Metal Materials and Engineering,2015,44(12):3243-3247.
- [16]王栋,刘赵铭,张英波,等.半固态热处理工艺对挤压AZ91镁合金微观组织的影响[J].稀有金属材料与工程,2014,43(9):2277-2280.WANG Dong,LIU Zhao-ming,ZHANG Ying-bo,et al.Effects of semi-solid treatment process parameters on microstructure of extruded AZ91magnesium alloy[J].Rare Metal Materials and Engineering,2014,43(9):2277-2280.
- [17]Kang M K,Kim D Y,Nong M,et al.Ostwald ripening kinetics of angular grains dispersed in a liquid phase by two-dimensional nucleation and abnormal grain growth[J].Journal of the Europe an Ceramic Society,2002,22:603-612.
- [18]冯凯,黄晓锋,马颖,等.ZA74镁合金非枝晶组织的演变过程及机理[J].中国有色金属学报,2013,23(3):635-644.FENG Kai,HUANG Xiao-feng,MA Ying,et al.Non-dendritic microstructure evolution process and mechanism of ZA74 magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2013,23(3):635-644.
- [19]杨光昱,郝启堂,介万奇,等.Mg-5Al-1.5Ca-0.4Zn-0.2Mn基镁合金的等温热处理法半固态压铸组织和性能[J].中国有色金属学报,2005,15(4):614-620.YANG Guang-yu,HAO Qi-tang,JIE Wan-qi,et al.Microstructure and properties of Mg-5Al-1.5Ca-0.4Zn based alloy by semi-solid isothermal heattreatment die pressure casting process[J].The Chinese Journal of Nonferrous Metals,2005,15(4):614-620.
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