陆恒昌,董瀚

• 1:钢铁研究总院
• 2:上海大学材料科学与工程学院

摘要(Abstract)：

总结了钢中块状相变的组织特征、内部亚结构及动力学条件。超低碳钢或中低碳钢均可发生块状相变,其组织形貌可呈不规则的块状或条片状,内部亚结构主要是位错与亚晶粒。在现有块状相变定义的基础上,综合块状相变的特征,从便于组织甄别的角度提出新定义:块状相变是热激活原子非协同地跨过相界长大过程,新相可穿越母相晶界、与母相成分相同且不具特定晶体学位向关系的相变。

关键词(KeyWords)： 块状相变;超低碳钢;亚结构;动力学

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(51474076);; 国家重点研发计划(2016YFB0101605)

作者(Author): 陆恒昌,董瀚

DOI: 10.13289/j.issn.1009-6264.2017-0445

参考文献(References)：

• [1]Massalski T B.Massive transformations revisited[J].Metallurgical&Materials Transactions A,2002,33(8):2277-2283.
• [2]Massalski T B.The mode and morphology of massive transformations in Cu-Ga,Cu-Zn,Cu-Zn-Ga and Cu-Ga-Ge alloys[J].Acta Metallurgica,1958,6(4):243-253.
• [3]Imandoust A,Zarei-Hanzaki A,Abedi H R.Low-temperature strain-induced ferrite transformation in twinning-induced plasticity steel[J].Scripta Materialia,2012,67(12):995-998.
• [4]Odqvist J.On the transition to massive growth during theγ→αtransformation in Fe-Ni alloys[J].Scripta Materialia,2005,52(3):193-197.
• [5]Wits J J,Kop T A,Leeuwen Y V,et al.A study on the austenite-to-ferrite phase transformation in binary substitutional iron alloys[J].Materials Science&Engineering A,2000,283(1-2):234-241.
• [6]Virkar A V,Su P,Fung K Z.Massive transformation in bismuth oxide-based ceramics[J].Metallurgical&Materials Transactions A,2002,33(8):2433-2443.
• [7]Griesser S,Bernhard C,Dippenaar R.Effect of nucleation undercooling on the kinetics and mechanism of the peritectic phase transition in steel[J].Acta Materialia,2014,62(81):111-120.
• [8]Jacot A,Sumida M,Kurz W.Solute trapping-free massive transformation at absolute stability[J].Acta Materialia,2011,59(4):1716-1724.
• [9]Inoue H,Koseki T,Ohkita S,et al.Effect of solidification on subsequent ferrite-to-austenite massive transformation in an austenitic stainless steel weld metal[J].ISIJ International,1995,35(10):1248-1257.
• [10]Krishanu B,Gandham P,Dieter M H,et al.Non-equilibrium solidification of concentrated Fe-Ge alloys[J].Materials Science&Engineering A,2007,449-451(12):12-17.
• [11]Hsieh C C,Lin D Y,Chen M C,et al.Precipitation and strengthening behavior of massiveδ-ferrite in dissimilar stainless steels during massive phase transformation[J].Materials Science&Engineering A,2008,477(1):328-333.
• [12]Bos C,Sommer F,Mittemeijer E J.A kinetic monte carlo method for the simulation of massive phase transformations[J].Acta Materialia,2004,52(12):3545-3554.
• [13]Bos C,Sommer F,Mittemeijer E J.An atomistic analysis of the interface mobility in a massive transformation[J].Acta Materialia,2005,53(20):5333-5341.
• [14]Loginova I,Odqvist J,Amberg G,et al.The phase-field approach and solute drag modeling of the transition to massiveγ→αtransformation in binary Fe-C alloys[J].Acta Materialia,2003,51(5):1327-1339.
• [15]Krielaart G P,Sietsma J,Zwaag S V D.Ferrite formation in Fe-C alloys during austenite decomposition under non-equilibrium interface conditions[J].Materials Science&Engineering A,1997,237(2):216-223.
• [16]Jr M B,Mittemeijer E J.Simulation of the massive austenite-ferrite transformation under uniaxial loading[J].Computational Materials Science,2013,77(77):214-223.
• [17]Gamsjger E,Liu Y,Rester M,et al.Diffusive and massive phase transformations in Ti-Al-Nb alloys-modelling and experiments[J].Intermetallics,2013,38(4):126-138.
• [18]Lima M,Kurz W.Massive transformation and absolute stability[J].Metallurgical&Materials Transactions A,2002,33(8):2337-2345.
• [19]Plichta M R,Clark W A T,Aaronson H I.The nucleation kinetics,crystallography,and mechanism of the massive transformation[J].Metallurgical Transactions A,1984,15(3):427-435.
• [20]侯增寿,赵兴国,侯文义,等.界面过程控制生长≠扩散控制[J].材料热处理学报,2005,26(3):6-9.HOU Zeng-shou,ZHAO Xing-guo,HOU Wen-yi,et al.Inerface process control growth is not equal to diffusion control[J].Transactions of Materials and Heat Treatment,2005,26(3):6-9.
• [21]戚正风.碳钢过冷奥氏体的转变[J].材料热处理学报,2017,38(4):1-14.QI Zheng-feng.Transformation of supercooling austenite in carbon steel[J].Transactions of Materials and Heat Treatment,2017,38(4):1-14.
• [22]刘宗昌,任慧平,王海燕.贝氏体相变机制与块状转变[J].热处理技术与装备,2006,27(4):1-5.LIU Zong-chang,REN Hui-ping,WANG Hai-yan.The Mechanism of bainite transformation and the massive transformation[J].Heat Treatment Technology and Equipment,2006,27(4):1-5.
• [23]侯增寿,赵兴国,侯文义,等.纯铁γ—α转变机制求索[J].材料热处理学报,2001,22(4):1-3.HOU Zeng-shou,ZHAO Xing-guo,HOU Wen-yi,et al.Probe into theγ-αtransformation mechanism of pure iron[J].Transactions of Materials and Heat Treatment,2001,22(4):1-3.
• [24]李峰.纯铁块状转变机制探索[J].材料热处理学报,2007,28(3):44-46.LI Feng.Study on massive transformation mechanism of pure iron[J].Transactions of Materials and Heat Treatment,2007,28(3):44-46.
• [25]Massalski T B.Distinguishing features of massive transformations[J].Metallurgical Transactions A,1984,15(3):421-425.
• [26]Yanar C,Wiezorek J M K,Soffa W A,et al.Massive transformation and the formation of the ferromagnetic L1 0phase in manganesealuminum-based alloys[J].Metallurgical&Materials Transactions A,2002,33(8):2413-2423.
• [27]徐祖耀.块状相变[J].热处理,2003,18(3):1-9.Hsu T Y(XU Zu-yao).Massive transformation[J].Heat Treatment,2003,18(3):1-9.
• [28]董瀚.钢铁材料基础研究的评述[J].钢铁,2008,43(10):1-7.DONG Han.Overview on the fundamental study of steel products[J].Iron and Steel,2008,43(10):1-7.
• [29]Aaronson H I,Vasudevan V K.General discussion session of the symposium on“The mechanisms of the massive transformation”[J].Metallurgical&Materials Transactions A,2002,33(8):2445-2470.
• [30]余永宁.金属学原理[M].北京:冶金工业出版社,2002.
• [31]Wang P,Veeraraghavan D,Kumar M,et al.Massive-parent interphase boundaries and their implications on the mechanisms of theα→γMmassive transformation in Ti-Al alloys[J].Metallurgical&Materials Transactions A,2002,33(8):2353-2371.
• [32]Plichta M R,Clark W A T,Aaronson H I.The nucleation kinetics,crystallography,and mechanism of the massive transformation[J].Metallurgical&Materials Transactions A,1984,15(3):427-435.
• [33]Veeraraghavan D,Wang P,Vasudevan V K.Nucleation kinetics of the→massive transformation in a Ti-47.5 at.%Al alloy[J].Acta Materialia,2003,51(6):1721-1741.
• [34]Wittig J E.The massive transformation in titanium aluminides:initial stages of nucleation and growth[J].Metallurgical&Materials Transactions A,2002,33(8):2373-2379.
• [35]Hillert M.Thermodynamics of the massive transformation[J].Metallurgical Transactions A,1984,15(3):411-419.
• [36]Hillert M.Critical limit for massive transformation[J].Metallurgical&Materials Transactions A,2002,33(8):2299-2308.
• [37]Hillert M,Schalin M.Modeling of solute drag in the massive phase transformation[J].Acta Materialia,2000,48(2):461-468.
• [38]Enomoto M.Simulation of ferrite growth in continuously cooled low-carbon iron alloys[J].Metallurgical&Materials Transactions A,2002,33(8):2309-2316.
• [39]Perepezko J H.Growth kinetics and mechanism of the massive transformation[J].Metallurgical Transactions A,1984,15(3):437-447.
• [40]Borgenstam A,Hillert M.Massive transformation in the Fe-Ni system[J].Acta Materialia,2000,48(11):2765-2775.
• [41]Enomoto M.Phase transformations in steel-massive ferrite transformation controlled by interface mobility[J].Bulletin of the Japan Institute of Metals,2015,54(2):65-71.
• [42]Borgenstam A,Hillert M.Bainite in the light of rapid continuous cooling information[J].Metallurgical and Materials Transactions A,1996,27(7):1501-1512.
• [43]Wilson E A.Theγ→αtransformation in low carbon irons[J].ISIJ International,1994,34(8):615-630.
• [44]Lee J M,Shibata K,Asakura K,et al.Observation ofγ→αtransformation in ultralow-carbon steel under a high temperature optical microscope[J].Transactions of the Iron&Steel Institute of Japan,2002,42(10):1135-1143.
• [45]Wilson E A.γ→αtransformation in Fe,Fe-Ni,and Fe-Cr alloys[J].Metal Science,1984,18(10):471-484.
• [46]刘宗昌,任慧平.含La钢的γ→α块状相变[J].热处理,2007,22(1):34-38.LIU Zong-chang,REN Hui-ping.γ→αmassive transformation of steel containing La[J].Heat Treatment,2007,22(1):34-38.
• [47]李承基.Fe-C-Si及Fe-C-Ni合金中的块型转变[J].金属热处理学报,1984,5(2):1-18.LI Cheng-ji.A massive transformation in Fe-C-Si and Fe-C-Ni alloys[J].Transactions of Metal Heat Treatment,1984,5(2):1-18.
• [48]俞德刚,郑经纮,沈甫法,等.18 Cr Ni WA钢中温转变组织[J].上海交通大学学报,1982,16(2):69-83.YU De-gang,ZHENG Jing-hong,SHEN Fu-fa,et al.The microstructures of intermediate-temperature transformations in 18 Cr Ni WA steel[J].Journal of Shang Hai Jiao Tong University,1982,16(2):69-83.
• [49]俞德刚,郑经纮,梁振峰,等.低中碳合金钢的中温块状铁素体组织[J].金属学报,1983,19(5):5-12.YU De-gang,ZHENG Jing-hong,LIANG Zhen-feng,et al.Middle temperature transformation of massive ferrite in low or medium carbon alloys steels[J].Acta Metallurgica Sinica,1983,19(5):5-12.
• [50]Ok S Y,Park J K.Dynamic austenite-to-ferrite transformation behavior of plain low carbon steel within(γ+α)2-phase field at low strain rate[J].Scripta Materialia,2005,52(11):1111-1116.
• [51]Chung J H,Park J K,Kim T H,et al.Study of deformation-induced phase transformation in plain low carbon steel at low strain rate[J].Materials Science&Engineering A,2010,527(20):5072-5077.
• [52]Park J K,Kim K H,Chung J H,et al.Deformation-induced austenite-to-ferrite massive transformation in medium carbon steel[J].Metallurgical&Materials Transactions Part A,2008,39(2):235-242.
• [53]Wilson E A,Chong S H.Isothermal transformations in an Fe-9 pct Ni alloy[J].Metallurgical&Materials Transactions A,2002,33(8):2425-2431.
• [54]Park J H,Lee Y K.Non-isothermal austenite formation behavior in an interstitial free steel with different ferrite microstructures[J].Scripta Materialia,2008,58(7):602-605.
• [55]Cizek P,Wynne B P,Davies C H J,et al.Effect of composition and austenite deformation on the transformation characteristics of low-carbon and ultralow-carbon microalloyed steels[J].Metallurgical&Materials Transactions A,2002,33(5):1331-1349.
• [56]Roberts M J.Effect of transformation substructure on the strength and toughness of Fe-Mn alloys[J].Metallurgical Transactions,1970,1(12):3287-3294.
• [57]Zhang X D,Godfrey S,Weaver M,et al.The massive transformation in Ti-Al alloys:mechanistic observations[J].Acta Materialia,1996,44(9):3723-3734.
• [58]Veeraraghavan D,Wang P,Vasudevan V K.Kinetics and thermodynamics of theα→γmmassive transformation in a Ti-47.5 at.%Al alloy[J].Acta Materialia,1999,47(11):3313-3330.
• [59]Sargent G A,Delaey L,Massalski T B.Formation of“feathery”structures during massive transformation in Cu-Ga alloys[J].Acta Metallurgica,1968,16(5):723-724.
• [60]Cheng W C,Lin H Y,Liu C F.Observing the massive transformation in an Fe-Mn-Al alloy[J].Materials Science&Engineering A,2002,335(1/2):82-88.
• [61]刘宗昌,李峰,任慧平.含镧高纯钢中的块状相变组织[J].钢铁研究学报,2007,19(5):76-79.LIU Zong-chang,LI Feng,REN Hui-png.Massive structure of purity steel containing La[J].Journal of Iron and Steel Research,2007,19(5):76-79.
• [62]郑梦珠,王海燕,李德超,等.Fe-RE系高纯净钢的γ-α多型性转变[J].稀土,2017,38(4):1-6.ZHENG Meng-zhu,WANG Hai-yan,LI De-chao,et al.Effect of rare earth onγ-αphase transformation in Fe-RE high purity steel[J].Chinese Rare Earths,2017,38(4):1-6.
• [63]Loginova I,gren J,Amberg G.On the formation of widmansttten ferrite in binary Fe-C-phase-field approach[J].Acta Materialia,2004,52(13):4055-4063.
• [64]Suehiro M,Liu Z K,gren J.Effect of niobium on massive transformation in ultra low carbon steels:a solute drag treatment[J].Acta Materialia,1996,44(10):4241-4251.
• [65]Howe J M,Jr W T R,Vasudevan V K.Static and in-situ,high-resolution transmission electron microscopy investigations of the atomic structure and dynamics of massive transformation interfaces in a Ti-Al alloy[J].Metallurgical&Materials Transactions A,2002,33(8):2391-2411.
• [66]Nie J F,Muddle B C.Orientation and structure of planar facets on the massive phaseγmin a near-Ti Al alloy[J].Metallurgical&Materials Transactions A,2002,33(8):2381-2389.
• [67]Howe J M.Comparison of the atomic structure,composition,kinetics and mechanisms of interfacial motion in martensitic,bainitic,massive and precipitation face-centered cubic-hexagonal close-packed phase transformations[J].Materials Science&Engineering A,2006,438-440(15):35-42.
• [68]Aaronson H I,Mahajan S,Purdy G R,et al.Origins of internal structure in massive transformation products[J].Metallurgical&Materials Transactions A,2002,33(8):2347-2351.
• [69]Wilson E A,Shtansky D V,Ohmori Y.A kinetic and electron microscopic study of transformations in continuously cooled Fe-15%Ni alloys[J].ISIJ International,2007,41(8):866-875.
• [70]Cheng W C,Lai C K.Observing massive phase transformation in a Fe-Mn-Al alloy[J].Scripta Materialia,2006,55(9):783-786.
• [71]Aaronson H I.Mechanisms of the massive transformation[J].Metallurgical&Materials Transactions A,2002,33(8):2285-2297.
• [72]Mittemeijer E J.Analysis of the kinetics of phase transformations[J].Journal of Materials Science,1992,27(15):3977-3987.
• [73]Kempen A T W,Sommer F,Mittemeijer E J.Determination and interpretation of isothermal and non-isothermal transformation kinetics;the effective activation energies in terms of nucleation and growth[J].Journal of Materials Science,2002,37(7):1321-1332.
• [74]Kempen A T W,Sommer F,Mittemeijer E J.The kinetics of the austenite-ferrite phase transformation of Fe-Mn:differential thermal analysis during cooling[J].Acta Materialia,2002,50(14):3545-3555.
• [75]Zhu J N,Luo H W,Yang Z G,et al.Determination of the intrinsicα/γinterface mobility during massive transformations in interstitial free Fe-X alloys[J].Acta Materialia,2017,65(133):258-268.
• [76]Liu Y C,Sommer F,Mittemeijer E J.Kinetics of the abnormal austenite-ferrite transformation behaviour in substitutional Fe-based alloys[J].Acta Materialia,2004,52(9):2549-2560.
• [77]Liu Y C,Sommer F,Mittemeijer E J.The austenite-ferrite transformation of ultralow-carbon Fe-C alloy;transition from diffusion-to interface-controlled growth[J].Acta Materialia,2006,54(12):3383-3393.
• [78]Liu Y C,Wang D,Sommer F,et al.Isothermal austenite-ferrite transformation of Fe-0.04 at.%C alloy:dilatometric measurement and kinetic analysis[J].Acta Materialia,2008,56(15):3833-3842.
• [79]Yada H,Li C M,Yamagata H.Dynamicγ→αTransformation during hot deformation in iron-nickel-carbon alloys[J].ISIJ International,2000,40(2):200-206.
• [80]Mohapatra G,Sommer F,Mittemeijer E J.The austenite to ferrite transformation of Fe-Ni under the influenceof a uniaxially applied tensile stress[J].Acta Materialia,2007,55(13):4359-4368.
• [81]Galera G,Borzaga C.Austenite-ferrite transformation kinetics under uniaxial compressive stress in Fe-2.96at.%Ni alloy[J].Acta Materialia,2009,57(9):2858-2868.

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