Al含量对Mg-2.0Zn-0.4Mn合金组织、力学性能及耐腐蚀性能的影响Effect of Al content on microstructure, mechanical properties and corrosion resistance of Mg-2.0Zn-0.4Mn alloy
焦琰珂,熊毅,姚怀
摘要(Abstract):
采用X射线衍射仪、光学显微镜、扫描电镜和透射电镜等研究了铸态Mg-2.0Zn-0.4Mn-xAl (x=0, 2.0, 3.0, 4.0, 5.0, 6.0 mass%)合金的物相和显微组织,采用拉伸实验测试了合金的力学性能,采用静态质量损失法和电化学测试实验研究了合金的耐腐蚀性能。结果表明:含Al合金的组织主要由α-Mg基体及不同形貌的Mg_2(Zn, Al)_(11)和MgZn_2第二相组成。随着Al含量的增加,合金的晶粒尺寸逐渐减小,其力学性能和耐腐蚀性能先升高后降低。当Al含量为4.0 mass%时,合金具有较好的力学性能及耐腐蚀性能,其极限抗拉强度、屈服强度及伸长率分别为(158.4±4.2) MPa、(119.2±5.8) MPa及(15.6±0.5)%,在3.5%NaCl溶液中浸泡72 h后,其平均静态腐蚀速率和析氢腐蚀速率分别为(0.958±0.057)和(0.933±0.051) mm/y。
关键词(KeyWords): 镁合金;显微组织;力学性能;耐腐蚀性
基金项目(Foundation): 河南省高等学校重点科研项目(20A430010);; 国家自然科学基金(U1804146)
作者(Author): 焦琰珂,熊毅,姚怀
DOI: 10.13289/j.issn.1009-6264.2022-0146
参考文献(References):
- [1] Schumann S,Friedrich H.Current and future use of magnesium in the automobile industry[C]//Materials Science Forum,Switzerland,2003,419-422:51-56.
- [2] 彭喜良.镁合金电镀在汽车上的应用[J].汽车实用技术,2017,23:87-88.PENG Xi-liang.Application of magnesium alloy electroplating on automobiles[J].Automobile Applied Technology,2017,23:87-88.
- [3] 陈军.镁合金在汽车工业中的应用分析[J].材料研究与应用,2010,4(2):81-84.CHEN Jun.Application analysis of magnesium alloy in automotive industry[J].Materials Research and Application,2010,4(2):81-84.
- [4] 程仁山,潘虎成,谢东升,等.新型高强度低合金化镁合金研究进展[J].中国材料进展,2020,39(1):31-38.CHENG Ren-shan,PAN Hu-cheng,XIE Dong-sheng,et al.Research progress of newly developed high-strength and low-alloyed magnesium alloy[J].Materials China,2020,39(1):31-38.
- [5] Zhang Y,Li X P,Sun S P,et al.Microstructure evolution and mechanical properties of rheo-squeeze casting AZ91-Ca alloy during heat treatment[J].China Foundry,2017,14(6):485-491.
- [6] Sasaki T T,Oh-ishi K,Ohkubo T,et al.Enhanced age hardening response by the addition of Zn in Mg-Sn alloys[J].Scripta Materialia,2006,55(3):251-254.
- [7] 肖璐,潘复生.Mg-Mn系合金的研究进展[J].有色金属工程,2019,9(9):1-9.XIAO Lu,PAN Fu-sheng.Research progress of Mg-Mn alloys[J].Nonferrous Metal Engineering,2019,9(9):1-9.
- [8] Agarwal S,Curtin J,Duffy B,et al.Biodegradable magnesium alloys for orthopaedic applications:A review on corrosion,biocompatibility and surface modifications[J].Materials Science and Engineering C,2016,68:948-963.
- [9] Yin D S,Zhang E L,Zeng S Y.Effect of Zn on mechanical property and corrosion property of extruded Mg-Zn-Mn alloy[J].Transactions of Nonferrous Metals Society of China,2008,18(4):763-768.
- [10] Kim S H,Lee J U,Kim Y J,et al.Controlling the microstructure and improving the tensile properties of extruded Mg-Sn-Zn alloy through Al addition[J].Journal of Alloys and Compounds,2018,751:1-11.
- [11] Pourbahari B,Mirzadeh H,Emamy M,et al.Enhanced ductility of a fine-grained Mg-Gd-Al-Zn magnesium alloy by hot extrusion[J].Advanced Engineering Materials,2018,20:1701171.
- [12] Mirzadeh H.Constitutive analysis of Mg-Al-Zn magnesium alloys during hot deformation[J].Mechanics of Materials,2014,77:80-85.
- [13] Yang M B,Li H L,Cheng R J.Comparison of as-cast microstructures and solidification behaviours of Mg-Zn-Al ternary magnesium alloys with different Zn/Al mass ratios[J].Advanced Materials Research,2012,548:321-327.
- [14] Kabir H,Munir K,Wen C,et al.Recent research and progress of biodegradable zinc alloys and composites for biomedical applications:Biomechanical and biocorrosion perspectives[J].Bioactive Materials,2021,6(3):836-879.
- [15] Shi Z,Liu M,Atrens A.Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation[J].Corrosion Science,2010,52(2):579-588.
- [16] 佟立丰,张帆,于海生,等.Al,Ca元素对镁合金显微组织及蠕变性能的影响[J].佳木斯大学学报(自然科学版),2007,25(1):56-58.TONG Li-feng,ZHANG Fan,YU Hai-sheng,et al.Effects of Al and Ca additions on microstructure and creep properties of magnesium alloys[J].Journal of Jiamusi University(JCR-SCI),2007,25(1):56-58.
- [17] Zhang Z,Tremblay R,Dube D,et al.Solidification microstructure of ZA102,ZA104 and ZA106 magnesium alloys and its effect on creep deformation[J].Canadian Metallurgical Quarterly,2013,39(4):503-512.
- [18] 钟诗宇,张丁非,胥钧耀,等.含Gd的Mg-Al系合金研究现状[J].材料导报,2021,35(9):9016-9027.ZHONG Shi-yu,ZHANG Ding-fei,XU Jun-yao,et al.Research progress of Mg-Al based alloys containing Gd element[J].Materials Reports,2021,35(9):9016-9027.
- [19] 姜东梅.Mg-Zn-Ca-Zr/Nd/Y生物镁合金组织、力学性能和腐蚀行为研究[D].长春:吉林大学,2014.JIANG Dong-Mei.Investigation on microstructure,mechanical properties and corrosion behavior of Mg-Zn-Ca-Zr/Nd/Y biological magnesium alloys[D].Changchun:Jilin University,2014.
- [20] 陈连生,郑亚琪,张源,等.医用可降解镁合金腐蚀疲劳行为研究进展[J].稀有金属材料与工程,2021,50(9):3375-3387.CHEN Lian-sheng,ZHENG Ya-qi,ZHANG Yuan,et al.Research progress on corrosion fatigue behavior of biomedical degradable magnesium-based alloys rare[J].Rare Metal Materials and Engineering,2021,50(9):3375-3387.
- [21] Lin C,Li X G.Role of CO2 in the initial stage of atmospheric corrosion of AZ91 magnesium alloy in the presence of NaCl[J].Rare Metals,2006,25(2):190-196.
- [22] Lu Y,Bradshaw A R,Chiu Y L,et al.Effects of secondary phase and grain size on the corrosion of biodegradable Mg-Zn-Ca alloys[J].Materials Science and Engineering C,2015,48:480-486.
- [23] Shi Z,Liu M,Atrens A.Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation[J].Corrosion Science,2010,52(2):579-588.
- [24] Abidin N,Atrens A D,Martin D,et al.Corrosion of high purity Mg,Mg2Zn0.2Mn,ZE41 and AZ91 in Hank’s solution at 37 ℃[J].Corrosion Science,2011,53(11):3542-3556.
- [25] Fan J,Qiu X,Niu X D,et al.Microstructure,mechanical properties,in vitro degradation and cytotoxicity evaluations of Mg-1.5Y-1.2Zn-0.44Zr alloys for biodegradable metallic implants[J].Materials Science and Engineering C,2013,33(4):2345-2352.
- [26] Cheng Y L,Qin T W,Wang H M,et al.Comparison of corrosion behaviors of AZ31,AZ91,AM60 and ZK60 magnesium alloys[J].Transactions of Nonferrous Metals Society of China,2009,19(3):517-524.
- [27] Warner T J,Thorne N A,Nussbaum G,et al.A cross-sectional TEM study of corrosion initiation in rapidly solidified Mg-based ribbons[J].Surface and Interface Analysis,1992,19(1/12):386-392.
- [28] Cao F F,Deng K K,Nie K B,et al.Microstructure and corrosion properties of Mg-4Zn-2Gd-0.5Ca alloy influenced by multidirectional forging[J].Journal of Alloys and Compounds,2018,770:1208-1220.
- [29] 刘俊,陈明安,马聪聪,等.第二相粒子在Mg-Gd-Y-Nd-Zr合金局部腐蚀中的作用机制[J].中国有色金属学报,2013,23(1):15-21.LIU Jun,CHEN Ming-an,MA Cong-cong,et al.Effect of second phase particles on localized corrosion of Mg-Gd-Y-Nd-Zr alloy[J].The Chinese Journal of Nonferrous Metals,2013,23(1):15-21.
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