X100管线钢中马奥岛精细结构表征及逆转变TEM原位分析Fine structure characterization and TEM in situ analysis of reversed transformation of martensite-austenite islands in X100 pipeline steel
张继明,喻春明
摘要(Abstract):
采用透射电镜(TEM)对X100高钢级管线钢中马奥岛(MA)组织的精细结构进行了分析,并采用原位观察的方法研究了加热过程中MA岛的逆转变行为。结果表明,X100管线钢中MA组织中的马氏体(M)由块状马氏体和孪晶马氏体组成,而残留奥氏体则由块状奥氏体和沿MA晶界分布的薄膜状奥氏体组成,两种组织在MA中交叉弥散分布。MA岛在加热过程中具有较高的稳定性,在400℃以下仅发生孪晶马氏体向马氏体的转变和MA内部碳元素的扩散。当加热温度在A_(c1)以上时,MA中的马氏体开始向奥氏体转变,在低于A_(c3)温度约30℃附近,MA岛完全转变为逆转变奥氏体组织。
关键词(KeyWords): 管线钢;MA岛;孪晶马氏体;残留奥氏体;逆转变奥氏体
基金项目(Foundation):
作者(Author): 张继明,喻春明
DOI: 10.13289/j.issn.1009-6264.2020-0260
参考文献(References):
- [1] 冯耀荣,柴惠芬,郭生武,等.低碳超低碳微合金化管线钢显微组织的研究进展[J].材料导报,2006,16(6):9-12.FENG Yao-rong,CHAI Hui-fen,GUO Sheng-wu,et al.Progress in research on microstructure of low-carbon and ultralow-carbon microalloyed of pipeline steels[J].Materials Review,2006,16(6):9-12.
- [2] 唐丽,尹立孟,王金钊.X80管线钢二次热循环的连续冷却转变行为及贝氏体相变动力学[J].材料导报,2019,33(9):3119-3124.TANG Li,YIN Li-meng,WANG Jin-zhao.Continuous cooling transformation behaviors and bainite transformation kinetics of X80 pipeline steel during the second thermal cycle[J].Materials Reports,2019,33(9):3119-3124.
- [3] 边育智,刘洋,王新华,等.X65、X70 管线钢高温延塑性的对比分析[J].钢铁研究学报,2007,19(11):51-54.BIAN Yu-zhi,LIU Yang,WANG Xin-hua,et al.Comparison and analysis on high temperature ductility of X65 and X70 pipeline steel[J].Journal of Iron and Steel Research,2007,19(11):51-54.
- [4] 毕宗岳,刘海璋,牛辉.西气东输二线用X80 管材及其焊接工艺[J].焊接,2011,11:47-51.BI Zong-yue,LIU Hai-zhang,NIU Hui.Welding process of X80 steel pipe for second west to east gas pipeline project[J].Welding and Joining,2011,11:47-51.
- [5] 朱丽霞,何晓东,仝珂,等.一种抗大变形管线钢的显微组织与拉伸性能的相关性研究[J].材料导报,2010,24(16):556-559.ZHU Li-xia,HE Xiao-dong,TONG Ke,et al.Relationship between tensile properties and microstructure of a high deformation pipeline steel[J].Materials Review,2010,24(16):556-559.
- [6] Zhang J M,Huo C Y,Ma Q R,et al.Nbc-tin co-precipitation behavior and mechanical properties of X90 pipeline steels by critical-temperature rolling process[J].International Journal of Pressure Vessels and Piping,2018,165:29-33.
- [7] Zhang J M,Luo T X,Wang X Q,et al.Formation mechanism of nanoscale transformation twinning in ultra-low-carbon high-strength pipeline steels[J].Journal of Materials Science,2019,54:14950-14960.
- [8] Zhang J M,Sun W H,Sun H.Mechanical properties and microstructure of X120 grade high strength pipeline steel[J].Journal of Iron and Steel Research,International,2010,17(10):63-67.
- [9] Ji L K,Li H L,Wang H T,et al.Influence of dual-phase microstructures on the properties of high strength grade line pipes[J].Journal of Materials Engineering and Performance,2014,23:3867-3874.
- [10] 张继明,喻春明.时效对含Nb低合金高强钢显微组织和力学性能的影响[J].材料热处理学报,2019,40(6):123-129.ZHANG Ji-ming,YU Chun-ming.Effect of aging on microstructure and mechanical properties of low alloy high strength steel containing Nb[J].Transactions of Materials and Heat Treatment,2019,40(6):123-129.
- [11] 马璇,王慧,刘刚伟,等.MA形成过程和分布对高强度管线钢力学性能的影响[J].焊管,2016,39(5):64-68.MA Xuan,WANG Hui,LIU Gang-wei,et al.Effects of distribution and the formation process of MA on deformation and toughness of high strength linepipe steel[J].Welded Pipe and Tube,2016,39(5):64-68.
- [12] 仝珂,庄传晶,刘强,等.高钢级管线钢中M/A岛的微观特征及其对力学性能的影响[J].机械工程材料,2011,35(2):4-7.TONG Ke,ZHUANG Chuan-jing,LIU Qiang,et al.Microstructure characteristics of M/A islands in high grade pipeline steel and its effect on mechanical properties[J].Materials for Mechanical Engineering,2011,35 (2):4-7.
- [13] Zhang J M,Chi Q,Ji L K,et al.Microstructure and mechanical properties of twinning M/A islands in a X100 high strength pipeline steel[J].Materials Science Forum,2017,896:182-189.
- [14] Wang C M,Wu X F,Liu J,et al.Transmission electron microscopy of martensite/austenite islands in pipeline steel X70[J].Materials Science and Engineering A,2006,438-440:267-271.
- [15] Shanmugam S,Ramisetti N K,Misra R D K,et al.Microstructure and high strength-toughness combination of a new 700 MPa Nb-microalloyed pipeline steel[J].Materials Science and Engineering A,2008,478:26-37.
- [16] Zhong Y,Xiao F R,Zhang J W,et al.In situ TEM study of the effect of M/A films at grain boundaries on crack propagation in an ultra-fine acicular ferrite pipeline steel[J].Acta Materialia,2006,54:435-443.
- [17] 钱海帆.TMCP工艺生产X100管线钢的微观组织及强化机理[J].钢铁研究学报,2011,23(11):54-58.QIAN Hai-fan.Microstructure and strengthening mechanism of X100 pipeline steel produced by TMCP[J].Journal of Iron and Steel Research,2011,23(11):54-58.
- [18] Huda N,Wang Y Y,Li L J.Effect of martensite-austenite (MA) distribution on mechanical properties of inter-critical reheated coarse grain heat affected zone in X80 linepipe steel.Materials Science and Engineering A,2019,765:1-9.
- [19] Kitade A,Kawabata T,Kimura S,et al.Clarification of micromechanism on brittle fracture initiation condition of TMCP steel with MA as the trigger point[J].Procedia Structural Integrity,2018,13:1845-1854.
- [20] 李学达,尚成嘉,韩昌柴,等.X100管线钢焊接热影响区中链状M-A组元对冲击韧性和断裂机制的影响[J].金属学报,2016,52(9):1023-1035.LI Xue-da,SHANG Cheng-jia,HAN Chang-chai,et al.Influence of necklace-type M-A constituent on impact toughness and fracture mechanism in the heat affected zone of X100 pipeline steel[J].Acta Metallurgical Sinica,2016,52(9):1023-1035.
- [21] Zhang J M,Li H,Yang F,et al.Effect of heat treatment process on mechanical properties and microstructure of a 9%Ni steel for large LNG storage tanks[J].Journal of Materials Engineering and Performance,2013,22:3867-3871.
- [22] Obeid O,Giulio A,Hamid B,et al.Experimental and numerical thermo-mechanical analysis of welding in a lined pipe[J].Journal of Manufacturing Processes,2018,32:857-872.
- [23] Raj B,Saroja S,Laha K,et al.Methods to overcome embrittlement problem in 9Cr-1Mo ferritic steel and its weldment[J].Journal of Materials Science,2009,44:2239-2246.
- [24] Hernandez V H B,Panda S K,Okita Y,et al.A study on heat affected zone softening in resistance spot welded dual phase steel by nanoindentation[J].Journal of Materials Science,2010,45:1638-1647.
- [25] Kurdjumov G,Kaminsky E.X-ray studies of the structure of quenched carbon steel[J].Nature,1928,122:475-476.
- [26] Kurdjumov G,Sachs G.Uber den mechanismus der stahlhrtung[J].Zeitschrift fur Physik,1930,64(5/6):325-343.
- [27] Zhang M X,Kelly P M.Crystallographic features of phase transformations in solids[J].Progress in Materials Science,2009,54:1101-1170.
- [28] Poorhaydari K,Patchett B M,Ivey D G.Transformation twins in the weld HAZ of a low-carbon high-strength microalloyed steel[J].Materials Science and Engineering A,2006,435-436:371-382.
- [29] 康沫狂,管敦惠,郭成道,等.低合金高强度结构钢中的(M-A)组织[J].西北工业大学学报,1972(2):1-19.KANG Mo-kuang,GUAN Dun-hui,GUO Cheng-dao,et al.M-A microstructure of low alloyed composite steels[J].Journal of Northwestern Polytechnical University,1972(2):1-19.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||