无取向硅钢中氮化物的析出机理Precipitation mechanism of nitride in non-oriented silicon steel
乔家龙,郭飞虎,胡金文,仇圣桃,张兴中
摘要(Abstract):
采用透射电镜(TEM)观察和第二相析出相关理论对无取向硅钢中氮化物的析出机理及其对晶粒长大的影响进行了研究。结合理论计算和检测分析表明,无取向硅钢中氮化物主要为AlN和TiN。含铝无取向硅钢中AlN和TiN在连铸过程优先在晶界形核,随着温度的降低将以位错形核为主。在均热过程中,高牌号无取向硅钢中AlN和低牌号无取向电工钢中TiN平衡析出量分别达97%和95%以上,但无铝无取向电工钢中AlN和高牌号无取向硅钢中TiN主要在热轧、卷取和退火过程中析出且尺寸较小。薄板坯流程无铝无取向电工钢中[Als]含量达到93×10~(-6)时,钢中AlN的析出将明显抑制晶粒长大。含铝无取向硅钢中的AlN将对退火过程中的晶粒长大起到抑制作用,且对低牌号无取向电工钢影响更大。
关键词(KeyWords): 无取向硅钢;氮化物;析出机制;热力学和动力学;晶粒长大
基金项目(Foundation): 国家重点研发计划(2016YFB0300305)
作者(Author): 乔家龙,郭飞虎,胡金文,仇圣桃,张兴中
DOI: 10.13289/j.issn.1009-6264.2020-0267
参考文献(References):
- [1] 何忠治,赵宇,罗海文.电工钢[M].北京:冶金工业出版社,2012HE Zhong-zhi,ZHAO Yu,LUO Hai-wen.Electrical Steel[M].Beijing:Metallurgical Industry Press,2012.
- [2] Matsumura K,Fukuda B.Recent developments of non-oriented electrical steel sheets[J].IEEE Transactions on Magnetics,1984,20(5):1533-1538.
- [3] 雍岐龙.钢铁材料中的第二相[M].北京:冶金工业出版社,2006.YONG Qi-long.Secondary Phases in Steel[M].Beijing:Metallurgical Industry Press,2006.
- [4] Wilson F G,Gladman T.Aluminium nitride in steel[J].International Materials Reviews,1988,33(1):221-286.
- [5] Petrovic D S,Arh B,Tehovnik F,et al.Magnesium non-metallic inclusions in non-oriented electrical steel sheets[J].ISIJ International,2011,51(12):2069-2075.
- [6] Luo Y,Zhang L F,Li M,et al.A thermodynamic model to estimate the formation of complex nitrides of AlxMg(1-x)N in silicon steel[J].Metallurgical and Materials Transactions B,2018,49(3):894-901.
- [7] Luo Y,Zhang L F,Yang W,et al.Precipitation of nitrides in non-oriented silicon steel[J].Ironmaking and Steelmaking,2019,46(4):359-367.
- [8] Sennour M,Esnouf C.Contribution of advanced microscopy techniques to nano-precipitates characterization:case of AlN precipitation in low-carbon steel[J].Acta Materialia,2003,51(4):943-957.
- [9] Okenko A P,Ivanenkov M I,Kulkova M N.Fine precipitates in the grain boundaries of transformer steel[J].Metal Science and Heat Treatment,1971,13(5):376-379.
- [10] Nakayama T,Takahashi M.Effects of vanadium on magnetic properties of semi-processed non-oriented electrical steel sheets[J].Journal of Materials Science,1995,30(23):5979-5984.
- [11] Taisei,Nakayama T,Takahashi M,et al.Effects of titanium on magnetic properties of semi-processed non-oriented electrical steel sheets[J].Journal of Materials Science,1997,32(4):1055-1059.
- [12] Hou C K,Hu C T,Lee S.The effect of titanium and niobium on degradation of magnetic properties of lamination steels[J].Journal of Magnetism and Magnetic Materials,1990,87(1/2):44-50.
- [13] Hou C K,Hu C T.The effect of aluminium on the magnetic properties of lamination steels[J].IEEE Transactions on Magnetics,1991,27(5):4305-4309.
- [14] Zhang T,Zhang X,Guo Z Y.AlN precipitates and microstructure in non-oriented electrical steels produced by twin-roll casting process[J].Acta Metallurgica Sinica,2013,26(4):483-488.
- [15] Jenkins K,Lindenmo M.Precipitates in electrical steels[J].Journal of Magnetism and Magnetic Materials,2008,320(20):2423-2429.
- [16] Nakayama T,Honjou N.Effect of aluminum and nitrogen on the magnetic properties of non-oriented semi-processed electrical steel sheet[J].Journal of Magnetism and Magnetic Materials,2000,213(1/2):87-94.
- [17] Xiang L,Yue E B,Fan D D,et al.Calculation of AIN and MnS precipitation in non-oriented electrical steel produced by CSP process[J].Journal of Iron and Steel Research (International),2008,15(5):88-94.
- [18] 王海军,付兵,项利,等.AlN在Hi-B钢铁素体相中析出的形核机制[J].钢铁研究学报,2015,27(10):40-45.WANG Hai-jun,FU Bing,XIANG Li,et al.Nucleation mechanism of precipitate of AlN in ferrite phase of Hi-B steel[J].Journal of Iron and Steel Research,2015,27(10):40-45.
- [19] 张可,孙新军,张明亚,等.Ti-V-Mo复合微合金钢中(Ti,V,Mo)C在γ/α中沉淀析出的动力学[J].金属学报,2018(8):1122-1130.ZHANG Ke,SUN Xin-jun,ZHANG Ming-ya,et al.Kinetics of (Ti,V,Mo) C precipitated in γ/α matrix of Ti-V-Mo complex microalloyed steel[M].Acta Metallurgica Sinica,2018(8):1122-1130.
- [20] Chen Y L,Wang Y,Zhao A M.Precipitation of AlN and MnS in low carbon aluminium-killed steel[J].Journal of Iron and Steel Research(International),2012(4):54-59.
- [21] 刘国平,凌晨,樊立峰,等.取向硅钢中AlN析出的动力学[J].钢铁研究学报,2014,26(12):60-64.LIU Guo-ping,LING Chen,FAN Li-feng,et al.Kinetics of precipitation for AlN in grain-oriented silicon steel[J].Journal of Iron and Steel Research,2014,26(12):60-64.
- [22] 樊立峰,许学勇,岳尔斌.高牌号无取向硅钢铸坯夹杂物浅析[J].宽厚板,2007,13(4):21-23.FAN Li-feng,XU Xue-yong,YUE Er-bing.Analysis on the inclusion in continuous casting slab of high-grade non-oriented silicon steel[J].Wide and Heavy Plate,2007,13(4):21-23.
- [23] 郭艳永,蔡开科.冷轧无取向硅钢中微细夹杂物的研究[J].中国稀土学报,2004,22(s1):498-502.GUO Yan-yong,CAI Kai-ke.Study on microinclusoins in cold-rolled non-oriented silicon steel sheet[J].Journal of the Chinese Rare Earth Society,2004,22(S1):498-502
- [24] Boca I,Czirakib A,Grofc T,et al.Analysis of inclusion in cold rolled non-oriented Si-Fe strips[J].Journal of Magnetic Materials,1990,83(13):381.
- [25] 张峰.钙合金处理硅钢中的夹杂物及晶粒成长变化[J].电工材料,2013(2):28-32.ZHANG Feng.Change of inclusions and grain growth of silicon steels by adding Ca alloy during RH refining process[J].Electrical Engineering Materials,2013(2):28-32.
- [26] 王宝明,赵志毅,陈凌峰,等.夹杂物尺寸及数量对无取向硅钢磁性能影响的主成分回归分析[J].冶金分析,2014,34(10):1-6.WANG Bao-ming,ZHAO Zhi-yi,CHEN Ling-feng,et al.Principal component regression analysis on the size and quantity of inclusions affecting magnetic properties of non-oriented silicon steel[J].Metallurgical Analysis,2014,34(10):1-6.
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